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Poly[di-μ(3)-hydroxy[μ(4)-5-(4-carboxyphenyl)pyridine-2-carboxylato-κ(5) N,O (2):O (2′):O (4):O (4′)]dicadmium]
The asymmetric unit of the title polymeric complex, [Cd(2)(C(13)H(7)NO(4))(OH)(2)](n), consists of two independent Cd(II) atoms, one 5-(4-carboxyphenyl)pyridine-2-carboxylate ligand and two hydroxy groups. One Cd(II) atom is six-coordinated by two O atoms from two ligand molecules and by four...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515118/ https://www.ncbi.nlm.nih.gov/pubmed/23284345 http://dx.doi.org/10.1107/S1600536812042444 |
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author | Meng, Fan-Jin Jia, Heng-Qing Hu, Ning-Hai Zhou, Hua |
author_facet | Meng, Fan-Jin Jia, Heng-Qing Hu, Ning-Hai Zhou, Hua |
author_sort | Meng, Fan-Jin |
collection | PubMed |
description | The asymmetric unit of the title polymeric complex, [Cd(2)(C(13)H(7)NO(4))(OH)(2)](n), consists of two independent Cd(II) atoms, one 5-(4-carboxyphenyl)pyridine-2-carboxylate ligand and two hydroxy groups. One Cd(II) atom is six-coordinated by two O atoms from two ligand molecules and by four μ(3)-OH groups in a distorted trigonal–prismatic geometry. The other is five-coordinated by one N and two O atoms from two ligands and by two μ(3)-OH groups, forming a distorted square-pyramidal geometry. The two independent Cd(II) atoms are connected by the ligand molecules and the OH groups into a three-dimensional framework. O—H⋯O hydrogen bonds between the OH groups and the carboxylate O atoms are observed. |
format | Online Article Text |
id | pubmed-3515118 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151182013-01-02 Poly[di-μ(3)-hydroxy[μ(4)-5-(4-carboxyphenyl)pyridine-2-carboxylato-κ(5) N,O (2):O (2′):O (4):O (4′)]dicadmium] Meng, Fan-Jin Jia, Heng-Qing Hu, Ning-Hai Zhou, Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title polymeric complex, [Cd(2)(C(13)H(7)NO(4))(OH)(2)](n), consists of two independent Cd(II) atoms, one 5-(4-carboxyphenyl)pyridine-2-carboxylate ligand and two hydroxy groups. One Cd(II) atom is six-coordinated by two O atoms from two ligand molecules and by four μ(3)-OH groups in a distorted trigonal–prismatic geometry. The other is five-coordinated by one N and two O atoms from two ligands and by two μ(3)-OH groups, forming a distorted square-pyramidal geometry. The two independent Cd(II) atoms are connected by the ligand molecules and the OH groups into a three-dimensional framework. O—H⋯O hydrogen bonds between the OH groups and the carboxylate O atoms are observed. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515118/ /pubmed/23284345 http://dx.doi.org/10.1107/S1600536812042444 Text en © Meng et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Meng, Fan-Jin Jia, Heng-Qing Hu, Ning-Hai Zhou, Hua Poly[di-μ(3)-hydroxy[μ(4)-5-(4-carboxyphenyl)pyridine-2-carboxylato-κ(5) N,O (2):O (2′):O (4):O (4′)]dicadmium] |
title | Poly[di-μ(3)-hydroxy[μ(4)-5-(4-carboxyphenyl)pyridine-2-carboxylato-κ(5)
N,O
(2):O
(2′):O
(4):O
(4′)]dicadmium] |
title_full | Poly[di-μ(3)-hydroxy[μ(4)-5-(4-carboxyphenyl)pyridine-2-carboxylato-κ(5)
N,O
(2):O
(2′):O
(4):O
(4′)]dicadmium] |
title_fullStr | Poly[di-μ(3)-hydroxy[μ(4)-5-(4-carboxyphenyl)pyridine-2-carboxylato-κ(5)
N,O
(2):O
(2′):O
(4):O
(4′)]dicadmium] |
title_full_unstemmed | Poly[di-μ(3)-hydroxy[μ(4)-5-(4-carboxyphenyl)pyridine-2-carboxylato-κ(5)
N,O
(2):O
(2′):O
(4):O
(4′)]dicadmium] |
title_short | Poly[di-μ(3)-hydroxy[μ(4)-5-(4-carboxyphenyl)pyridine-2-carboxylato-κ(5)
N,O
(2):O
(2′):O
(4):O
(4′)]dicadmium] |
title_sort | poly[di-μ(3)-hydroxy[μ(4)-5-(4-carboxyphenyl)pyridine-2-carboxylato-κ(5)
n,o
(2):o
(2′):o
(4):o
(4′)]dicadmium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515118/ https://www.ncbi.nlm.nih.gov/pubmed/23284345 http://dx.doi.org/10.1107/S1600536812042444 |
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