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Poly[di-μ(3)-hy­droxy[μ(4)-5-(4-carb­oxy­phen­yl)pyridine-2-carboxyl­ato-κ(5) N,O (2):O (2′):O (4):O (4′)]dicadmium]

The asymmetric unit of the title polymeric complex, [Cd(2)(C(13)H(7)NO(4))(OH)(2)](n), consists of two independent Cd(II) atoms, one 5-(4-carb­oxy­phen­yl)pyridine-2-carboxyl­ate ligand and two hy­droxy groups. One Cd(II) atom is six-coordinated by two O atoms from two ligand mol­ecules and by four...

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Detalles Bibliográficos
Autores principales: Meng, Fan-Jin, Jia, Heng-Qing, Hu, Ning-Hai, Zhou, Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515118/
https://www.ncbi.nlm.nih.gov/pubmed/23284345
http://dx.doi.org/10.1107/S1600536812042444
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author Meng, Fan-Jin
Jia, Heng-Qing
Hu, Ning-Hai
Zhou, Hua
author_facet Meng, Fan-Jin
Jia, Heng-Qing
Hu, Ning-Hai
Zhou, Hua
author_sort Meng, Fan-Jin
collection PubMed
description The asymmetric unit of the title polymeric complex, [Cd(2)(C(13)H(7)NO(4))(OH)(2)](n), consists of two independent Cd(II) atoms, one 5-(4-carb­oxy­phen­yl)pyridine-2-carboxyl­ate ligand and two hy­droxy groups. One Cd(II) atom is six-coordinated by two O atoms from two ligand mol­ecules and by four μ(3)-OH groups in a distorted trigonal–prismatic geometry. The other is five-coordinated by one N and two O atoms from two ligands and by two μ(3)-OH groups, forming a distorted square-pyramidal geometry. The two independent Cd(II) atoms are connected by the ligand mol­ecules and the OH groups into a three-dimensional framework. O—H⋯O hydrogen bonds between the OH groups and the carboxyl­ate O atoms are observed.
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spelling pubmed-35151182013-01-02 Poly[di-μ(3)-hy­droxy[μ(4)-5-(4-carb­oxy­phen­yl)pyridine-2-carboxyl­ato-κ(5) N,O (2):O (2′):O (4):O (4′)]dicadmium] Meng, Fan-Jin Jia, Heng-Qing Hu, Ning-Hai Zhou, Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title polymeric complex, [Cd(2)(C(13)H(7)NO(4))(OH)(2)](n), consists of two independent Cd(II) atoms, one 5-(4-carb­oxy­phen­yl)pyridine-2-carboxyl­ate ligand and two hy­droxy groups. One Cd(II) atom is six-coordinated by two O atoms from two ligand mol­ecules and by four μ(3)-OH groups in a distorted trigonal–prismatic geometry. The other is five-coordinated by one N and two O atoms from two ligands and by two μ(3)-OH groups, forming a distorted square-pyramidal geometry. The two independent Cd(II) atoms are connected by the ligand mol­ecules and the OH groups into a three-dimensional framework. O—H⋯O hydrogen bonds between the OH groups and the carboxyl­ate O atoms are observed. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515118/ /pubmed/23284345 http://dx.doi.org/10.1107/S1600536812042444 Text en © Meng et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meng, Fan-Jin
Jia, Heng-Qing
Hu, Ning-Hai
Zhou, Hua
Poly[di-μ(3)-hy­droxy[μ(4)-5-(4-carb­oxy­phen­yl)pyridine-2-carboxyl­ato-κ(5) N,O (2):O (2′):O (4):O (4′)]dicadmium]
title Poly[di-μ(3)-hy­droxy[μ(4)-5-(4-carb­oxy­phen­yl)pyridine-2-carboxyl­ato-κ(5) N,O (2):O (2′):O (4):O (4′)]dicadmium]
title_full Poly[di-μ(3)-hy­droxy[μ(4)-5-(4-carb­oxy­phen­yl)pyridine-2-carboxyl­ato-κ(5) N,O (2):O (2′):O (4):O (4′)]dicadmium]
title_fullStr Poly[di-μ(3)-hy­droxy[μ(4)-5-(4-carb­oxy­phen­yl)pyridine-2-carboxyl­ato-κ(5) N,O (2):O (2′):O (4):O (4′)]dicadmium]
title_full_unstemmed Poly[di-μ(3)-hy­droxy[μ(4)-5-(4-carb­oxy­phen­yl)pyridine-2-carboxyl­ato-κ(5) N,O (2):O (2′):O (4):O (4′)]dicadmium]
title_short Poly[di-μ(3)-hy­droxy[μ(4)-5-(4-carb­oxy­phen­yl)pyridine-2-carboxyl­ato-κ(5) N,O (2):O (2′):O (4):O (4′)]dicadmium]
title_sort poly[di-μ(3)-hy­droxy[μ(4)-5-(4-carb­oxy­phen­yl)pyridine-2-carboxyl­ato-κ(5) n,o (2):o (2′):o (4):o (4′)]dicadmium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515118/
https://www.ncbi.nlm.nih.gov/pubmed/23284345
http://dx.doi.org/10.1107/S1600536812042444
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