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(μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxylato-1:2κN,O:O)-dichlorido(ethanol-κO)bis[N-hydroxy-1-(pyridin-2-yl)methanimine-κ(2) N,N′]dicobalt(II)
The dinuclear title compound, [Co(2)Cl(3)(C(6)H(4)NO(2))(C(6)H(6)N(2)O)(2)(C(2)H(5)OH)], contains two six-coordinate Co(II) atoms with different octahedral coordination environments. One Co(II) atom is coordinated by two N atoms from one pyridine-2-carbaldehyde oxime ligand, by one terminal and one...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515119/ https://www.ncbi.nlm.nih.gov/pubmed/23284346 http://dx.doi.org/10.1107/S1600536812041736 |
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author | Chen, Lei |
author_facet | Chen, Lei |
author_sort | Chen, Lei |
collection | PubMed |
description | The dinuclear title compound, [Co(2)Cl(3)(C(6)H(4)NO(2))(C(6)H(6)N(2)O)(2)(C(2)H(5)OH)], contains two six-coordinate Co(II) atoms with different octahedral coordination environments. One Co(II) atom is coordinated by two N atoms from one pyridine-2-carbaldehyde oxime ligand, by one terminal and one bridging Cl(−) ion, by one O atom from an ethanol molecule, and by one O atom from a bridging pyridine-2-carboxylate (picolinate) anion. The second Co(II) atom is coordinated by two N atoms from another pyridine-2-carbaldehyde oxime ligand, one N and one O atom from the bridging picolinate anion, and by one terminal Cl(−) and one bridging Cl(−) anion. The structure displays intramolecular O—H⋯O and O—H⋯Cl hydrogen bonds. Weak C—H⋯Cl hydrogen-bonding interactions connect the molecules into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3515119 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151192013-01-02 (μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxylato-1:2κN,O:O)-dichlorido(ethanol-κO)bis[N-hydroxy-1-(pyridin-2-yl)methanimine-κ(2) N,N′]dicobalt(II) Chen, Lei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title compound, [Co(2)Cl(3)(C(6)H(4)NO(2))(C(6)H(6)N(2)O)(2)(C(2)H(5)OH)], contains two six-coordinate Co(II) atoms with different octahedral coordination environments. One Co(II) atom is coordinated by two N atoms from one pyridine-2-carbaldehyde oxime ligand, by one terminal and one bridging Cl(−) ion, by one O atom from an ethanol molecule, and by one O atom from a bridging pyridine-2-carboxylate (picolinate) anion. The second Co(II) atom is coordinated by two N atoms from another pyridine-2-carbaldehyde oxime ligand, one N and one O atom from the bridging picolinate anion, and by one terminal Cl(−) and one bridging Cl(−) anion. The structure displays intramolecular O—H⋯O and O—H⋯Cl hydrogen bonds. Weak C—H⋯Cl hydrogen-bonding interactions connect the molecules into a three-dimensional network. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515119/ /pubmed/23284346 http://dx.doi.org/10.1107/S1600536812041736 Text en © Lei Chen 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chen, Lei (μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxylato-1:2κN,O:O)-dichlorido(ethanol-κO)bis[N-hydroxy-1-(pyridin-2-yl)methanimine-κ(2) N,N′]dicobalt(II) |
title | (μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxylato-1:2κN,O:O)-dichlorido(ethanol-κO)bis[N-hydroxy-1-(pyridin-2-yl)methanimine-κ(2)
N,N′]dicobalt(II) |
title_full | (μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxylato-1:2κN,O:O)-dichlorido(ethanol-κO)bis[N-hydroxy-1-(pyridin-2-yl)methanimine-κ(2)
N,N′]dicobalt(II) |
title_fullStr | (μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxylato-1:2κN,O:O)-dichlorido(ethanol-κO)bis[N-hydroxy-1-(pyridin-2-yl)methanimine-κ(2)
N,N′]dicobalt(II) |
title_full_unstemmed | (μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxylato-1:2κN,O:O)-dichlorido(ethanol-κO)bis[N-hydroxy-1-(pyridin-2-yl)methanimine-κ(2)
N,N′]dicobalt(II) |
title_short | (μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxylato-1:2κN,O:O)-dichlorido(ethanol-κO)bis[N-hydroxy-1-(pyridin-2-yl)methanimine-κ(2)
N,N′]dicobalt(II) |
title_sort | (μ(2)-chlorido)-(μ(2)-pyridine-2-carboxylato-1:2κn,o:o)-dichlorido(ethanol-κo)bis[n-hydroxy-1-(pyridin-2-yl)methanimine-κ(2)
n,n′]dicobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515119/ https://www.ncbi.nlm.nih.gov/pubmed/23284346 http://dx.doi.org/10.1107/S1600536812041736 |
work_keys_str_mv | AT chenlei m2chloridom2pyridine2carboxylato12knoodichloridoethanolkobisnhydroxy1pyridin2ylmethaniminek2nndicobaltii |