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(μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxyl­ato-1:2κN,O:O)-dichlorido(ethanol-κO)bis­[N-hy­droxy-1-(pyridin-2-yl)methan­imine-κ(2) N,N′]dicobalt(II)

The dinuclear title compound, [Co(2)Cl(3)(C(6)H(4)NO(2))(C(6)H(6)N(2)O)(2)(C(2)H(5)OH)], contains two six-coordinate Co(II) atoms with different octa­hedral coordination environments. One Co(II) atom is coordinated by two N atoms from one pyridine-2-carbaldehyde oxime ligand, by one terminal and one...

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Detalles Bibliográficos
Autor principal: Chen, Lei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515119/
https://www.ncbi.nlm.nih.gov/pubmed/23284346
http://dx.doi.org/10.1107/S1600536812041736
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author Chen, Lei
author_facet Chen, Lei
author_sort Chen, Lei
collection PubMed
description The dinuclear title compound, [Co(2)Cl(3)(C(6)H(4)NO(2))(C(6)H(6)N(2)O)(2)(C(2)H(5)OH)], contains two six-coordinate Co(II) atoms with different octa­hedral coordination environments. One Co(II) atom is coordinated by two N atoms from one pyridine-2-carbaldehyde oxime ligand, by one terminal and one bridging Cl(−) ion, by one O atom from an ethanol mol­ecule, and by one O atom from a bridging pyridine-2-carboxyl­ate (picolinate) anion. The second Co(II) atom is coordinated by two N atoms from another pyridine-2-carbaldehyde oxime ligand, one N and one O atom from the bridging picolinate anion, and by one terminal Cl(−) and one bridging Cl(−) anion. The structure displays intra­molecular O—H⋯O and O—H⋯Cl hydrogen bonds. Weak C—H⋯Cl hydrogen-bonding inter­actions connect the mol­ecules into a three-dimensional network.
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spelling pubmed-35151192013-01-02 (μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxyl­ato-1:2κN,O:O)-dichlorido(ethanol-κO)bis­[N-hy­droxy-1-(pyridin-2-yl)methan­imine-κ(2) N,N′]dicobalt(II) Chen, Lei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title compound, [Co(2)Cl(3)(C(6)H(4)NO(2))(C(6)H(6)N(2)O)(2)(C(2)H(5)OH)], contains two six-coordinate Co(II) atoms with different octa­hedral coordination environments. One Co(II) atom is coordinated by two N atoms from one pyridine-2-carbaldehyde oxime ligand, by one terminal and one bridging Cl(−) ion, by one O atom from an ethanol mol­ecule, and by one O atom from a bridging pyridine-2-carboxyl­ate (picolinate) anion. The second Co(II) atom is coordinated by two N atoms from another pyridine-2-carbaldehyde oxime ligand, one N and one O atom from the bridging picolinate anion, and by one terminal Cl(−) and one bridging Cl(−) anion. The structure displays intra­molecular O—H⋯O and O—H⋯Cl hydrogen bonds. Weak C—H⋯Cl hydrogen-bonding inter­actions connect the mol­ecules into a three-dimensional network. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515119/ /pubmed/23284346 http://dx.doi.org/10.1107/S1600536812041736 Text en © Lei Chen 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Lei
(μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxyl­ato-1:2κN,O:O)-dichlorido(ethanol-κO)bis­[N-hy­droxy-1-(pyridin-2-yl)methan­imine-κ(2) N,N′]dicobalt(II)
title (μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxyl­ato-1:2κN,O:O)-dichlorido(ethanol-κO)bis­[N-hy­droxy-1-(pyridin-2-yl)methan­imine-κ(2) N,N′]dicobalt(II)
title_full (μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxyl­ato-1:2κN,O:O)-dichlorido(ethanol-κO)bis­[N-hy­droxy-1-(pyridin-2-yl)methan­imine-κ(2) N,N′]dicobalt(II)
title_fullStr (μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxyl­ato-1:2κN,O:O)-dichlorido(ethanol-κO)bis­[N-hy­droxy-1-(pyridin-2-yl)methan­imine-κ(2) N,N′]dicobalt(II)
title_full_unstemmed (μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxyl­ato-1:2κN,O:O)-dichlorido(ethanol-κO)bis­[N-hy­droxy-1-(pyridin-2-yl)methan­imine-κ(2) N,N′]dicobalt(II)
title_short (μ(2)-Chlorido)-(μ(2)-pyridine-2-carboxyl­ato-1:2κN,O:O)-dichlorido(ethanol-κO)bis­[N-hy­droxy-1-(pyridin-2-yl)methan­imine-κ(2) N,N′]dicobalt(II)
title_sort (μ(2)-chlorido)-(μ(2)-pyridine-2-carboxyl­ato-1:2κn,o:o)-dichlorido(ethanol-κo)bis­[n-hy­droxy-1-(pyridin-2-yl)methan­imine-κ(2) n,n′]dicobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515119/
https://www.ncbi.nlm.nih.gov/pubmed/23284346
http://dx.doi.org/10.1107/S1600536812041736
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