[Bis[μ-bis­(diphenyl­phosphino)methane-1:2κ(2) P:P′]-bis­(nitrito-κ(2) O,O′)]disilver(I) acetonitrile disolvate

The title complex, [Ag(2)(NO(2))(2)(C(25)H(22)P(2))(2)]·2CH(3)CN, is a centrosymmetric dimer in which two bis(diphenylphosphino)methane ligands bridge two Ag(+) ions, forming an eight-membered ring with a short Ag⋯Ag separation of 3.1809 (5) Å. The distorted P(2)O(2) coordination of the cation is co...

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Detalles Bibliográficos
Autores principales: Yang, Xue, Huang, Xu, Qiu, Qi-Ming, Jin, Qiong-Hua, Zhang, Cun-Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515120/
https://www.ncbi.nlm.nih.gov/pubmed/23284347
http://dx.doi.org/10.1107/S1600536812041931
Descripción
Sumario:The title complex, [Ag(2)(NO(2))(2)(C(25)H(22)P(2))(2)]·2CH(3)CN, is a centrosymmetric dimer in which two bis(diphenylphosphino)methane ligands bridge two Ag(+) ions, forming an eight-membered ring with a short Ag⋯Ag separation of 3.1809 (5) Å. The distorted P(2)O(2) coordination of the cation is completed by two O-donors from a symmetric bidentate chelate NO(2) (−) anion [Ag—O = 2.550 (3) and 2.567 (3) Å].

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