[Bis[μ-bis­(diphenyl­phosphino)methane-1:2κ(2) P:P′]-bis­(nitrito-κ(2) O,O′)]disilver(I) acetonitrile disolvate

The title complex, [Ag(2)(NO(2))(2)(C(25)H(22)P(2))(2)]·2CH(3)CN, is a centrosymmetric dimer in which two bis(diphenylphosphino)methane ligands bridge two Ag(+) ions, forming an eight-membered ring with a short Ag⋯Ag separation of 3.1809 (5) Å. The distorted P(2)O(2) coordination of the cation is co...

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Autores principales: Yang, Xue, Huang, Xu, Qiu, Qi-Ming, Jin, Qiong-Hua, Zhang, Cun-Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515120/
https://www.ncbi.nlm.nih.gov/pubmed/23284347
http://dx.doi.org/10.1107/S1600536812041931
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author Yang, Xue
Huang, Xu
Qiu, Qi-Ming
Jin, Qiong-Hua
Zhang, Cun-Lin
author_facet Yang, Xue
Huang, Xu
Qiu, Qi-Ming
Jin, Qiong-Hua
Zhang, Cun-Lin
author_sort Yang, Xue
collection PubMed
description The title complex, [Ag(2)(NO(2))(2)(C(25)H(22)P(2))(2)]·2CH(3)CN, is a centrosymmetric dimer in which two bis(diphenylphosphino)methane ligands bridge two Ag(+) ions, forming an eight-membered ring with a short Ag⋯Ag separation of 3.1809 (5) Å. The distorted P(2)O(2) coordination of the cation is completed by two O-donors from a symmetric bidentate chelate NO(2) (−) anion [Ag—O = 2.550 (3) and 2.567 (3) Å].
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spelling pubmed-35151202013-01-02 [Bis[μ-bis­(diphenyl­phosphino)methane-1:2κ(2) P:P′]-bis­(nitrito-κ(2) O,O′)]disilver(I) acetonitrile disolvate Yang, Xue Huang, Xu Qiu, Qi-Ming Jin, Qiong-Hua Zhang, Cun-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ag(2)(NO(2))(2)(C(25)H(22)P(2))(2)]·2CH(3)CN, is a centrosymmetric dimer in which two bis(diphenylphosphino)methane ligands bridge two Ag(+) ions, forming an eight-membered ring with a short Ag⋯Ag separation of 3.1809 (5) Å. The distorted P(2)O(2) coordination of the cation is completed by two O-donors from a symmetric bidentate chelate NO(2) (−) anion [Ag—O = 2.550 (3) and 2.567 (3) Å]. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515120/ /pubmed/23284347 http://dx.doi.org/10.1107/S1600536812041931 Text en © Yang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Xue
Huang, Xu
Qiu, Qi-Ming
Jin, Qiong-Hua
Zhang, Cun-Lin
[Bis[μ-bis­(diphenyl­phosphino)methane-1:2κ(2) P:P′]-bis­(nitrito-κ(2) O,O′)]disilver(I) acetonitrile disolvate
title [Bis[μ-bis­(diphenyl­phosphino)methane-1:2κ(2) P:P′]-bis­(nitrito-κ(2) O,O′)]disilver(I) acetonitrile disolvate
title_full [Bis[μ-bis­(diphenyl­phosphino)methane-1:2κ(2) P:P′]-bis­(nitrito-κ(2) O,O′)]disilver(I) acetonitrile disolvate
title_fullStr [Bis[μ-bis­(diphenyl­phosphino)methane-1:2κ(2) P:P′]-bis­(nitrito-κ(2) O,O′)]disilver(I) acetonitrile disolvate
title_full_unstemmed [Bis[μ-bis­(diphenyl­phosphino)methane-1:2κ(2) P:P′]-bis­(nitrito-κ(2) O,O′)]disilver(I) acetonitrile disolvate
title_short [Bis[μ-bis­(diphenyl­phosphino)methane-1:2κ(2) P:P′]-bis­(nitrito-κ(2) O,O′)]disilver(I) acetonitrile disolvate
title_sort [bis[μ-bis­(diphenyl­phosphino)methane-1:2κ(2) p:p′]-bis­(nitrito-κ(2) o,o′)]disilver(i) acetonitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515120/
https://www.ncbi.nlm.nih.gov/pubmed/23284347
http://dx.doi.org/10.1107/S1600536812041931
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