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Potassium N-bromo-2,4-dichloro­benzene­sulfonamidate sesquihydrate

The asymmetric unit of the title salt, K(+)·C(6)H(3)BrCl(2)NO(2)S(−)·1.5H(2)O, contains one K(+) cation, one N-bromo-2,4-dichlorobenzenesulfonamidate anion, one water molecule in general position and one water molecule located on a twofold rotation axis. The K(+) cation is hepta-coordinated by three...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Spandana, H. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515121/
https://www.ncbi.nlm.nih.gov/pubmed/23284348
http://dx.doi.org/10.1107/S1600536812042456
Descripción
Sumario:The asymmetric unit of the title salt, K(+)·C(6)H(3)BrCl(2)NO(2)S(−)·1.5H(2)O, contains one K(+) cation, one N-bromo-2,4-dichlorobenzenesulfonamidate anion, one water molecule in general position and one water molecule located on a twofold rotation axis. The K(+) cation is hepta-coordinated by three water O atoms and four sulfonyl O atoms from three symmetry-related N-bromo-2,4-dichloro­benzene­sulfonamide anions. The S=N distance of 1.575 (3) Å is consistent with that of a double bond. In the crystal, the anions are linked by O—H⋯Br and O—H⋯N hydrogen bonds into layers parallel to the ac plane.