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Potassium N-bromo-2,4-dichlorobenzenesulfonamidate sesquihydrate
The asymmetric unit of the title salt, K(+)·C(6)H(3)BrCl(2)NO(2)S(−)·1.5H(2)O, contains one K(+) cation, one N-bromo-2,4-dichlorobenzenesulfonamidate anion, one water molecule in general position and one water molecule located on a twofold rotation axis. The K(+) cation is hepta-coordinated by three...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515121/ https://www.ncbi.nlm.nih.gov/pubmed/23284348 http://dx.doi.org/10.1107/S1600536812042456 |
Sumario: | The asymmetric unit of the title salt, K(+)·C(6)H(3)BrCl(2)NO(2)S(−)·1.5H(2)O, contains one K(+) cation, one N-bromo-2,4-dichlorobenzenesulfonamidate anion, one water molecule in general position and one water molecule located on a twofold rotation axis. The K(+) cation is hepta-coordinated by three water O atoms and four sulfonyl O atoms from three symmetry-related N-bromo-2,4-dichlorobenzenesulfonamide anions. The S=N distance of 1.575 (3) Å is consistent with that of a double bond. In the crystal, the anions are linked by O—H⋯Br and O—H⋯N hydrogen bonds into layers parallel to the ac plane. |
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