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Potassium N-bromo-2,4-dichlorobenzenesulfonamidate sesquihydrate
The asymmetric unit of the title salt, K(+)·C(6)H(3)BrCl(2)NO(2)S(−)·1.5H(2)O, contains one K(+) cation, one N-bromo-2,4-dichlorobenzenesulfonamidate anion, one water molecule in general position and one water molecule located on a twofold rotation axis. The K(+) cation is hepta-coordinated by three...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515121/ https://www.ncbi.nlm.nih.gov/pubmed/23284348 http://dx.doi.org/10.1107/S1600536812042456 |
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author | Gowda, B. Thimme Foro, Sabine Spandana, H. S. |
author_facet | Gowda, B. Thimme Foro, Sabine Spandana, H. S. |
author_sort | Gowda, B. Thimme |
collection | PubMed |
description | The asymmetric unit of the title salt, K(+)·C(6)H(3)BrCl(2)NO(2)S(−)·1.5H(2)O, contains one K(+) cation, one N-bromo-2,4-dichlorobenzenesulfonamidate anion, one water molecule in general position and one water molecule located on a twofold rotation axis. The K(+) cation is hepta-coordinated by three water O atoms and four sulfonyl O atoms from three symmetry-related N-bromo-2,4-dichlorobenzenesulfonamide anions. The S=N distance of 1.575 (3) Å is consistent with that of a double bond. In the crystal, the anions are linked by O—H⋯Br and O—H⋯N hydrogen bonds into layers parallel to the ac plane. |
format | Online Article Text |
id | pubmed-3515121 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151212013-01-02 Potassium N-bromo-2,4-dichlorobenzenesulfonamidate sesquihydrate Gowda, B. Thimme Foro, Sabine Spandana, H. S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title salt, K(+)·C(6)H(3)BrCl(2)NO(2)S(−)·1.5H(2)O, contains one K(+) cation, one N-bromo-2,4-dichlorobenzenesulfonamidate anion, one water molecule in general position and one water molecule located on a twofold rotation axis. The K(+) cation is hepta-coordinated by three water O atoms and four sulfonyl O atoms from three symmetry-related N-bromo-2,4-dichlorobenzenesulfonamide anions. The S=N distance of 1.575 (3) Å is consistent with that of a double bond. In the crystal, the anions are linked by O—H⋯Br and O—H⋯N hydrogen bonds into layers parallel to the ac plane. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515121/ /pubmed/23284348 http://dx.doi.org/10.1107/S1600536812042456 Text en © Gowda et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gowda, B. Thimme Foro, Sabine Spandana, H. S. Potassium N-bromo-2,4-dichlorobenzenesulfonamidate sesquihydrate |
title | Potassium N-bromo-2,4-dichlorobenzenesulfonamidate sesquihydrate |
title_full | Potassium N-bromo-2,4-dichlorobenzenesulfonamidate sesquihydrate |
title_fullStr | Potassium N-bromo-2,4-dichlorobenzenesulfonamidate sesquihydrate |
title_full_unstemmed | Potassium N-bromo-2,4-dichlorobenzenesulfonamidate sesquihydrate |
title_short | Potassium N-bromo-2,4-dichlorobenzenesulfonamidate sesquihydrate |
title_sort | potassium n-bromo-2,4-dichlorobenzenesulfonamidate sesquihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515121/ https://www.ncbi.nlm.nih.gov/pubmed/23284348 http://dx.doi.org/10.1107/S1600536812042456 |
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