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Potassium N-bromo-2,4-dichloro­benzene­sulfonamidate sesquihydrate

The asymmetric unit of the title salt, K(+)·C(6)H(3)BrCl(2)NO(2)S(−)·1.5H(2)O, contains one K(+) cation, one N-bromo-2,4-dichlorobenzenesulfonamidate anion, one water molecule in general position and one water molecule located on a twofold rotation axis. The K(+) cation is hepta-coordinated by three...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Spandana, H. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515121/
https://www.ncbi.nlm.nih.gov/pubmed/23284348
http://dx.doi.org/10.1107/S1600536812042456
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author Gowda, B. Thimme
Foro, Sabine
Spandana, H. S.
author_facet Gowda, B. Thimme
Foro, Sabine
Spandana, H. S.
author_sort Gowda, B. Thimme
collection PubMed
description The asymmetric unit of the title salt, K(+)·C(6)H(3)BrCl(2)NO(2)S(−)·1.5H(2)O, contains one K(+) cation, one N-bromo-2,4-dichlorobenzenesulfonamidate anion, one water molecule in general position and one water molecule located on a twofold rotation axis. The K(+) cation is hepta-coordinated by three water O atoms and four sulfonyl O atoms from three symmetry-related N-bromo-2,4-dichloro­benzene­sulfonamide anions. The S=N distance of 1.575 (3) Å is consistent with that of a double bond. In the crystal, the anions are linked by O—H⋯Br and O—H⋯N hydrogen bonds into layers parallel to the ac plane.
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spelling pubmed-35151212013-01-02 Potassium N-bromo-2,4-dichloro­benzene­sulfonamidate sesquihydrate Gowda, B. Thimme Foro, Sabine Spandana, H. S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title salt, K(+)·C(6)H(3)BrCl(2)NO(2)S(−)·1.5H(2)O, contains one K(+) cation, one N-bromo-2,4-dichlorobenzenesulfonamidate anion, one water molecule in general position and one water molecule located on a twofold rotation axis. The K(+) cation is hepta-coordinated by three water O atoms and four sulfonyl O atoms from three symmetry-related N-bromo-2,4-dichloro­benzene­sulfonamide anions. The S=N distance of 1.575 (3) Å is consistent with that of a double bond. In the crystal, the anions are linked by O—H⋯Br and O—H⋯N hydrogen bonds into layers parallel to the ac plane. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515121/ /pubmed/23284348 http://dx.doi.org/10.1107/S1600536812042456 Text en © Gowda et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gowda, B. Thimme
Foro, Sabine
Spandana, H. S.
Potassium N-bromo-2,4-dichloro­benzene­sulfonamidate sesquihydrate
title Potassium N-bromo-2,4-dichloro­benzene­sulfonamidate sesquihydrate
title_full Potassium N-bromo-2,4-dichloro­benzene­sulfonamidate sesquihydrate
title_fullStr Potassium N-bromo-2,4-dichloro­benzene­sulfonamidate sesquihydrate
title_full_unstemmed Potassium N-bromo-2,4-dichloro­benzene­sulfonamidate sesquihydrate
title_short Potassium N-bromo-2,4-dichloro­benzene­sulfonamidate sesquihydrate
title_sort potassium n-bromo-2,4-dichloro­benzene­sulfonamidate sesquihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515121/
https://www.ncbi.nlm.nih.gov/pubmed/23284348
http://dx.doi.org/10.1107/S1600536812042456
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