Sodium penta­fluoro­phenyl­borate

The crystal structure of the title compound, Na[(C(6)F(5))BH(3)], is composed of discrete anions and cations. The sodium cations are surrounded by four anions with three short Na⋯B [2.848 (8), 2.842 (7) and 2.868 (8) Å] and two short Na⋯F contacts [2.348 (5) and 2.392 (5) Å], forming a three-dimensi...

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Detalles Bibliográficos
Autores principales: Vitze, Hannes, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515123/
https://www.ncbi.nlm.nih.gov/pubmed/23284350
http://dx.doi.org/10.1107/S1600536812042584
Descripción
Sumario:The crystal structure of the title compound, Na[(C(6)F(5))BH(3)], is composed of discrete anions and cations. The sodium cations are surrounded by four anions with three short Na⋯B [2.848 (8), 2.842 (7) and 2.868 (8) Å] and two short Na⋯F contacts [2.348 (5) and 2.392 (5) Å], forming a three-dimensional network. The anion is the first structural example of a pentafluorophenyl ring carrying a BH(3) group.

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