Sodium penta­fluoro­phenyl­borate

The crystal structure of the title compound, Na[(C(6)F(5))BH(3)], is composed of discrete anions and cations. The sodium cations are surrounded by four anions with three short Na⋯B [2.848 (8), 2.842 (7) and 2.868 (8) Å] and two short Na⋯F contacts [2.348 (5) and 2.392 (5) Å], forming a three-dimensi...

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Detalles Bibliográficos
Autores principales: Vitze, Hannes, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515123/
https://www.ncbi.nlm.nih.gov/pubmed/23284350
http://dx.doi.org/10.1107/S1600536812042584
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author Vitze, Hannes
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Vitze, Hannes
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Vitze, Hannes
collection PubMed
description The crystal structure of the title compound, Na[(C(6)F(5))BH(3)], is composed of discrete anions and cations. The sodium cations are surrounded by four anions with three short Na⋯B [2.848 (8), 2.842 (7) and 2.868 (8) Å] and two short Na⋯F contacts [2.348 (5) and 2.392 (5) Å], forming a three-dimensional network. The anion is the first structural example of a pentafluorophenyl ring carrying a BH(3) group.
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spelling pubmed-35151232013-01-02 Sodium penta­fluoro­phenyl­borate Vitze, Hannes Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, Na[(C(6)F(5))BH(3)], is composed of discrete anions and cations. The sodium cations are surrounded by four anions with three short Na⋯B [2.848 (8), 2.842 (7) and 2.868 (8) Å] and two short Na⋯F contacts [2.348 (5) and 2.392 (5) Å], forming a three-dimensional network. The anion is the first structural example of a pentafluorophenyl ring carrying a BH(3) group. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515123/ /pubmed/23284350 http://dx.doi.org/10.1107/S1600536812042584 Text en © Vitze et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Vitze, Hannes
Lerner, Hans-Wolfram
Bolte, Michael
Sodium penta­fluoro­phenyl­borate
title Sodium penta­fluoro­phenyl­borate
title_full Sodium penta­fluoro­phenyl­borate
title_fullStr Sodium penta­fluoro­phenyl­borate
title_full_unstemmed Sodium penta­fluoro­phenyl­borate
title_short Sodium penta­fluoro­phenyl­borate
title_sort sodium penta­fluoro­phenyl­borate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515123/
https://www.ncbi.nlm.nih.gov/pubmed/23284350
http://dx.doi.org/10.1107/S1600536812042584
work_keys_str_mv AT vitzehannes sodiumpentafluorophenylborate
AT lernerhanswolfram sodiumpentafluorophenylborate
AT boltemichael sodiumpentafluorophenylborate

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