Bis[4-(4-bromophenylimino-κN)pent-2-en-2-olato-κO]copper(II)

In the title compound, [Cu(C(11)H(11)BrNO)(2)], the Cu(II) atom is in a distorted square-planar geometry, with the two bidentate ketimine ligands positioned in a trans geometry. Two inter­molecular C—H⋯O hydrogen bond inter­actions are present which link the mol­ecules in a zigzag manner along the a...

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Detalles Bibliográficos
Autores principales: Bungu, Paul S. E., Schutte, Marietjie, Steyl, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515125/
https://www.ncbi.nlm.nih.gov/pubmed/23284352
http://dx.doi.org/10.1107/S1600536812042420
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author Bungu, Paul S. E.
Schutte, Marietjie
Steyl, G.
author_facet Bungu, Paul S. E.
Schutte, Marietjie
Steyl, G.
author_sort Bungu, Paul S. E.
collection PubMed
description In the title compound, [Cu(C(11)H(11)BrNO)(2)], the Cu(II) atom is in a distorted square-planar geometry, with the two bidentate ketimine ligands positioned in a trans geometry. Two inter­molecular C—H⋯O hydrogen bond inter­actions are present which link the mol­ecules in a zigzag manner along the a axis. The mol­ecules pack in layers along the diagonal of the bc plane.
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spelling pubmed-35151252013-01-02 Bis[4-(4-bromophenylimino-κN)pent-2-en-2-olato-κO]copper(II) Bungu, Paul S. E. Schutte, Marietjie Steyl, G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(11)H(11)BrNO)(2)], the Cu(II) atom is in a distorted square-planar geometry, with the two bidentate ketimine ligands positioned in a trans geometry. Two inter­molecular C—H⋯O hydrogen bond inter­actions are present which link the mol­ecules in a zigzag manner along the a axis. The mol­ecules pack in layers along the diagonal of the bc plane. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515125/ /pubmed/23284352 http://dx.doi.org/10.1107/S1600536812042420 Text en © Bungu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bungu, Paul S. E.
Schutte, Marietjie
Steyl, G.
Bis[4-(4-bromophenylimino-κN)pent-2-en-2-olato-κO]copper(II)
title Bis[4-(4-bromophenylimino-κN)pent-2-en-2-olato-κO]copper(II)
title_full Bis[4-(4-bromophenylimino-κN)pent-2-en-2-olato-κO]copper(II)
title_fullStr Bis[4-(4-bromophenylimino-κN)pent-2-en-2-olato-κO]copper(II)
title_full_unstemmed Bis[4-(4-bromophenylimino-κN)pent-2-en-2-olato-κO]copper(II)
title_short Bis[4-(4-bromophenylimino-κN)pent-2-en-2-olato-κO]copper(II)
title_sort bis[4-(4-bromophenylimino-κn)pent-2-en-2-olato-κo]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515125/
https://www.ncbi.nlm.nih.gov/pubmed/23284352
http://dx.doi.org/10.1107/S1600536812042420
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