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μ-(2,2′-Bipyrimidine)-bis­[dichlorido­palladium(II)] dimethyl­formamide monosolvate

In the title compound, [Pd(2)Cl(4)(C(8)H(6)N(4))]·C(3)H(7)NO, the two Pd(2+) cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2′-bipyrimidine ligand. Two terminal chloride anions are also bonded to each of the Pd(2+) cations. The dinuclear complex and t...

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Detalles Bibliográficos
Autores principales: Young, Cyril, Roodt, Andreas, Bezuidenhoudt, Barend C. B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515126/
https://www.ncbi.nlm.nih.gov/pubmed/23284353
http://dx.doi.org/10.1107/S1600536812040779
Descripción
Sumario:In the title compound, [Pd(2)Cl(4)(C(8)H(6)N(4))]·C(3)H(7)NO, the two Pd(2+) cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2′-bipyrimidine ligand. Two terminal chloride anions are also bonded to each of the Pd(2+) cations. The dinuclear complex and the dimethylformamide solvate molecule lie on the inter­section of a twofold rotation axis and a mirror plane, with disorder present in the solvate mol­ecule. There is a slight distortion from the square-planar metal geometry, as indicated by the bite angles of 81.77 (13)° and 91.63 (5)°. The C and O atoms of the solvent mol­ecule are disordered over two sets of sites of equal occupancy.