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μ-(2,2′-Bipyrimidine)-bis[dichloridopalladium(II)] dimethylformamide monosolvate
In the title compound, [Pd(2)Cl(4)(C(8)H(6)N(4))]·C(3)H(7)NO, the two Pd(2+) cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2′-bipyrimidine ligand. Two terminal chloride anions are also bonded to each of the Pd(2+) cations. The dinuclear complex and t...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515126/ https://www.ncbi.nlm.nih.gov/pubmed/23284353 http://dx.doi.org/10.1107/S1600536812040779 |
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author | Young, Cyril Roodt, Andreas Bezuidenhoudt, Barend C. B. |
author_facet | Young, Cyril Roodt, Andreas Bezuidenhoudt, Barend C. B. |
author_sort | Young, Cyril |
collection | PubMed |
description | In the title compound, [Pd(2)Cl(4)(C(8)H(6)N(4))]·C(3)H(7)NO, the two Pd(2+) cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2′-bipyrimidine ligand. Two terminal chloride anions are also bonded to each of the Pd(2+) cations. The dinuclear complex and the dimethylformamide solvate molecule lie on the intersection of a twofold rotation axis and a mirror plane, with disorder present in the solvate molecule. There is a slight distortion from the square-planar metal geometry, as indicated by the bite angles of 81.77 (13)° and 91.63 (5)°. The C and O atoms of the solvent molecule are disordered over two sets of sites of equal occupancy. |
format | Online Article Text |
id | pubmed-3515126 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151262013-01-02 μ-(2,2′-Bipyrimidine)-bis[dichloridopalladium(II)] dimethylformamide monosolvate Young, Cyril Roodt, Andreas Bezuidenhoudt, Barend C. B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(2)Cl(4)(C(8)H(6)N(4))]·C(3)H(7)NO, the two Pd(2+) cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2′-bipyrimidine ligand. Two terminal chloride anions are also bonded to each of the Pd(2+) cations. The dinuclear complex and the dimethylformamide solvate molecule lie on the intersection of a twofold rotation axis and a mirror plane, with disorder present in the solvate molecule. There is a slight distortion from the square-planar metal geometry, as indicated by the bite angles of 81.77 (13)° and 91.63 (5)°. The C and O atoms of the solvent molecule are disordered over two sets of sites of equal occupancy. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515126/ /pubmed/23284353 http://dx.doi.org/10.1107/S1600536812040779 Text en © Young et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Young, Cyril Roodt, Andreas Bezuidenhoudt, Barend C. B. μ-(2,2′-Bipyrimidine)-bis[dichloridopalladium(II)] dimethylformamide monosolvate |
title | μ-(2,2′-Bipyrimidine)-bis[dichloridopalladium(II)] dimethylformamide monosolvate |
title_full | μ-(2,2′-Bipyrimidine)-bis[dichloridopalladium(II)] dimethylformamide monosolvate |
title_fullStr | μ-(2,2′-Bipyrimidine)-bis[dichloridopalladium(II)] dimethylformamide monosolvate |
title_full_unstemmed | μ-(2,2′-Bipyrimidine)-bis[dichloridopalladium(II)] dimethylformamide monosolvate |
title_short | μ-(2,2′-Bipyrimidine)-bis[dichloridopalladium(II)] dimethylformamide monosolvate |
title_sort | μ-(2,2′-bipyrimidine)-bis[dichloridopalladium(ii)] dimethylformamide monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515126/ https://www.ncbi.nlm.nih.gov/pubmed/23284353 http://dx.doi.org/10.1107/S1600536812040779 |
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