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μ-(2,2′-Bipyrimidine)-bis­[dichlorido­palladium(II)] dimethyl­formamide monosolvate

In the title compound, [Pd(2)Cl(4)(C(8)H(6)N(4))]·C(3)H(7)NO, the two Pd(2+) cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2′-bipyrimidine ligand. Two terminal chloride anions are also bonded to each of the Pd(2+) cations. The dinuclear complex and t...

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Detalles Bibliográficos
Autores principales: Young, Cyril, Roodt, Andreas, Bezuidenhoudt, Barend C. B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515126/
https://www.ncbi.nlm.nih.gov/pubmed/23284353
http://dx.doi.org/10.1107/S1600536812040779
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author Young, Cyril
Roodt, Andreas
Bezuidenhoudt, Barend C. B.
author_facet Young, Cyril
Roodt, Andreas
Bezuidenhoudt, Barend C. B.
author_sort Young, Cyril
collection PubMed
description In the title compound, [Pd(2)Cl(4)(C(8)H(6)N(4))]·C(3)H(7)NO, the two Pd(2+) cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2′-bipyrimidine ligand. Two terminal chloride anions are also bonded to each of the Pd(2+) cations. The dinuclear complex and the dimethylformamide solvate molecule lie on the inter­section of a twofold rotation axis and a mirror plane, with disorder present in the solvate mol­ecule. There is a slight distortion from the square-planar metal geometry, as indicated by the bite angles of 81.77 (13)° and 91.63 (5)°. The C and O atoms of the solvent mol­ecule are disordered over two sets of sites of equal occupancy.
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spelling pubmed-35151262013-01-02 μ-(2,2′-Bipyrimidine)-bis­[dichlorido­palladium(II)] dimethyl­formamide monosolvate Young, Cyril Roodt, Andreas Bezuidenhoudt, Barend C. B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(2)Cl(4)(C(8)H(6)N(4))]·C(3)H(7)NO, the two Pd(2+) cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2′-bipyrimidine ligand. Two terminal chloride anions are also bonded to each of the Pd(2+) cations. The dinuclear complex and the dimethylformamide solvate molecule lie on the inter­section of a twofold rotation axis and a mirror plane, with disorder present in the solvate mol­ecule. There is a slight distortion from the square-planar metal geometry, as indicated by the bite angles of 81.77 (13)° and 91.63 (5)°. The C and O atoms of the solvent mol­ecule are disordered over two sets of sites of equal occupancy. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515126/ /pubmed/23284353 http://dx.doi.org/10.1107/S1600536812040779 Text en © Young et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Young, Cyril
Roodt, Andreas
Bezuidenhoudt, Barend C. B.
μ-(2,2′-Bipyrimidine)-bis­[dichlorido­palladium(II)] dimethyl­formamide monosolvate
title μ-(2,2′-Bipyrimidine)-bis­[dichlorido­palladium(II)] dimethyl­formamide monosolvate
title_full μ-(2,2′-Bipyrimidine)-bis­[dichlorido­palladium(II)] dimethyl­formamide monosolvate
title_fullStr μ-(2,2′-Bipyrimidine)-bis­[dichlorido­palladium(II)] dimethyl­formamide monosolvate
title_full_unstemmed μ-(2,2′-Bipyrimidine)-bis­[dichlorido­palladium(II)] dimethyl­formamide monosolvate
title_short μ-(2,2′-Bipyrimidine)-bis­[dichlorido­palladium(II)] dimethyl­formamide monosolvate
title_sort μ-(2,2′-bipyrimidine)-bis­[dichlorido­palladium(ii)] dimethyl­formamide monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515126/
https://www.ncbi.nlm.nih.gov/pubmed/23284353
http://dx.doi.org/10.1107/S1600536812040779
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