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Triaqua(cyclohex-4-ene-1,2-dicarboxylato-κO (1))(1,10-phenanthroline-κ(2) N,N′)cobalt(II)
In the title compound, [Co(C(8)H(8)O(4))(C(12)H(8)N(2))(H(2)O)(3)], the Co(II) atom is coordinated by two N atoms from a bidentate 1,10-phenanthroline ligand, one O atom from a monodentate 4-cyclohexene-1,2-dicarboxylate ligand and three water O atoms in a distorted octahedral geometry. The monon...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515127/ https://www.ncbi.nlm.nih.gov/pubmed/23284354 http://dx.doi.org/10.1107/S160053681204024X |
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author | Li, Hai-Ye Wang, Cheng Huang, Fu-Ping Jiang, Yi-Min |
author_facet | Li, Hai-Ye Wang, Cheng Huang, Fu-Ping Jiang, Yi-Min |
author_sort | Li, Hai-Ye |
collection | PubMed |
description | In the title compound, [Co(C(8)H(8)O(4))(C(12)H(8)N(2))(H(2)O)(3)], the Co(II) atom is coordinated by two N atoms from a bidentate 1,10-phenanthroline ligand, one O atom from a monodentate 4-cyclohexene-1,2-dicarboxylate ligand and three water O atoms in a distorted octahedral geometry. The mononuclear molecules are engaged in extensive intra- and intermolecular O—H⋯O hydrogen-bonding interactions and π–π stacking interactions [centroid–centroid distance = 3.784 (3) Å], forming a three-dimensional supramolecular network. |
format | Online Article Text |
id | pubmed-3515127 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151272013-01-02 Triaqua(cyclohex-4-ene-1,2-dicarboxylato-κO (1))(1,10-phenanthroline-κ(2) N,N′)cobalt(II) Li, Hai-Ye Wang, Cheng Huang, Fu-Ping Jiang, Yi-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(8)H(8)O(4))(C(12)H(8)N(2))(H(2)O)(3)], the Co(II) atom is coordinated by two N atoms from a bidentate 1,10-phenanthroline ligand, one O atom from a monodentate 4-cyclohexene-1,2-dicarboxylate ligand and three water O atoms in a distorted octahedral geometry. The mononuclear molecules are engaged in extensive intra- and intermolecular O—H⋯O hydrogen-bonding interactions and π–π stacking interactions [centroid–centroid distance = 3.784 (3) Å], forming a three-dimensional supramolecular network. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515127/ /pubmed/23284354 http://dx.doi.org/10.1107/S160053681204024X Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Hai-Ye Wang, Cheng Huang, Fu-Ping Jiang, Yi-Min Triaqua(cyclohex-4-ene-1,2-dicarboxylato-κO (1))(1,10-phenanthroline-κ(2) N,N′)cobalt(II) |
title | Triaqua(cyclohex-4-ene-1,2-dicarboxylato-κO
(1))(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) |
title_full | Triaqua(cyclohex-4-ene-1,2-dicarboxylato-κO
(1))(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) |
title_fullStr | Triaqua(cyclohex-4-ene-1,2-dicarboxylato-κO
(1))(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) |
title_full_unstemmed | Triaqua(cyclohex-4-ene-1,2-dicarboxylato-κO
(1))(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) |
title_short | Triaqua(cyclohex-4-ene-1,2-dicarboxylato-κO
(1))(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) |
title_sort | triaqua(cyclohex-4-ene-1,2-dicarboxylato-κo
(1))(1,10-phenanthroline-κ(2)
n,n′)cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515127/ https://www.ncbi.nlm.nih.gov/pubmed/23284354 http://dx.doi.org/10.1107/S160053681204024X |
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