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Triaqua­(cyclo­hex-4-ene-1,2-dicarboxyl­ato-κO (1))(1,10-phenanthroline-κ(2) N,N′)cobalt(II)

In the title compound, [Co(C(8)H(8)O(4))(C(12)H(8)N(2))(H(2)O)(3)], the Co(II) atom is coordinated by two N atoms from a bidentate 1,10-phenanthroline ligand, one O atom from a monodentate 4-cyclo­hexene-1,2-dicarboxyl­ate ligand and three water O atoms in a distorted octa­hedral geometry. The monon...

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Detalles Bibliográficos
Autores principales: Li, Hai-Ye, Wang, Cheng, Huang, Fu-Ping, Jiang, Yi-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515127/
https://www.ncbi.nlm.nih.gov/pubmed/23284354
http://dx.doi.org/10.1107/S160053681204024X
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author Li, Hai-Ye
Wang, Cheng
Huang, Fu-Ping
Jiang, Yi-Min
author_facet Li, Hai-Ye
Wang, Cheng
Huang, Fu-Ping
Jiang, Yi-Min
author_sort Li, Hai-Ye
collection PubMed
description In the title compound, [Co(C(8)H(8)O(4))(C(12)H(8)N(2))(H(2)O)(3)], the Co(II) atom is coordinated by two N atoms from a bidentate 1,10-phenanthroline ligand, one O atom from a monodentate 4-cyclo­hexene-1,2-dicarboxyl­ate ligand and three water O atoms in a distorted octa­hedral geometry. The mononuclear mol­ecules are engaged in extensive intra- and inter­molecular O—H⋯O hydrogen-bonding inter­actions and π–π stacking inter­actions [centroid–centroid distance = 3.784 (3) Å], forming a three-dimensional supra­molecular network.
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spelling pubmed-35151272013-01-02 Triaqua­(cyclo­hex-4-ene-1,2-dicarboxyl­ato-κO (1))(1,10-phenanthroline-κ(2) N,N′)cobalt(II) Li, Hai-Ye Wang, Cheng Huang, Fu-Ping Jiang, Yi-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(8)H(8)O(4))(C(12)H(8)N(2))(H(2)O)(3)], the Co(II) atom is coordinated by two N atoms from a bidentate 1,10-phenanthroline ligand, one O atom from a monodentate 4-cyclo­hexene-1,2-dicarboxyl­ate ligand and three water O atoms in a distorted octa­hedral geometry. The mononuclear mol­ecules are engaged in extensive intra- and inter­molecular O—H⋯O hydrogen-bonding inter­actions and π–π stacking inter­actions [centroid–centroid distance = 3.784 (3) Å], forming a three-dimensional supra­molecular network. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515127/ /pubmed/23284354 http://dx.doi.org/10.1107/S160053681204024X Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Hai-Ye
Wang, Cheng
Huang, Fu-Ping
Jiang, Yi-Min
Triaqua­(cyclo­hex-4-ene-1,2-dicarboxyl­ato-κO (1))(1,10-phenanthroline-κ(2) N,N′)cobalt(II)
title Triaqua­(cyclo­hex-4-ene-1,2-dicarboxyl­ato-κO (1))(1,10-phenanthroline-κ(2) N,N′)cobalt(II)
title_full Triaqua­(cyclo­hex-4-ene-1,2-dicarboxyl­ato-κO (1))(1,10-phenanthroline-κ(2) N,N′)cobalt(II)
title_fullStr Triaqua­(cyclo­hex-4-ene-1,2-dicarboxyl­ato-κO (1))(1,10-phenanthroline-κ(2) N,N′)cobalt(II)
title_full_unstemmed Triaqua­(cyclo­hex-4-ene-1,2-dicarboxyl­ato-κO (1))(1,10-phenanthroline-κ(2) N,N′)cobalt(II)
title_short Triaqua­(cyclo­hex-4-ene-1,2-dicarboxyl­ato-κO (1))(1,10-phenanthroline-κ(2) N,N′)cobalt(II)
title_sort triaqua­(cyclo­hex-4-ene-1,2-dicarboxyl­ato-κo (1))(1,10-phenanthroline-κ(2) n,n′)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515127/
https://www.ncbi.nlm.nih.gov/pubmed/23284354
http://dx.doi.org/10.1107/S160053681204024X
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