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Bis(acetato-κ(2) O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc
The molecular structure of the title compound, [Zn(CH(3)COO)(2)(C(12)H(12)N(2))], consists of isolated molecules bisected by a twofold rotation axis which goes through the Zn(II) cation and halves the organic base through the central C—C bond. The Zn(II) ion is coordinated by two N atoms from one...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515128/ https://www.ncbi.nlm.nih.gov/pubmed/23284355 http://dx.doi.org/10.1107/S1600536812042699 |
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author | Harvey, Miguel A. Suarez, Sebastian A. Ibañez, Andres Doctorovich, Fabio Baggio, Ricardo |
author_facet | Harvey, Miguel A. Suarez, Sebastian A. Ibañez, Andres Doctorovich, Fabio Baggio, Ricardo |
author_sort | Harvey, Miguel A. |
collection | PubMed |
description | The molecular structure of the title compound, [Zn(CH(3)COO)(2)(C(12)H(12)N(2))], consists of isolated molecules bisected by a twofold rotation axis which goes through the Zn(II) cation and halves the organic base through the central C—C bond. The Zn(II) ion is coordinated by two N atoms from one molecule of the aromatic base and four O atoms from two bidentate, symmetry-related acetate anions, which coordinate asymmetrically [Zn—O distances of 2.058 (2) and 2.362 (3) Å], while the two Zn—N bond distances are equal as imposed by symmetry [2.079 (2) Å]. The crystal structure is supported by a number of weak C—H⋯O interactions and C—H⋯π contacts, with no π–π interactions present, mainly hindered by the substituent methyl groups and the relative molecular orientation. The result is a three-dimensional structure in which each molecule is linked to eight different neighbors. |
format | Online Article Text |
id | pubmed-3515128 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151282013-01-02 Bis(acetato-κ(2) O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc Harvey, Miguel A. Suarez, Sebastian A. Ibañez, Andres Doctorovich, Fabio Baggio, Ricardo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecular structure of the title compound, [Zn(CH(3)COO)(2)(C(12)H(12)N(2))], consists of isolated molecules bisected by a twofold rotation axis which goes through the Zn(II) cation and halves the organic base through the central C—C bond. The Zn(II) ion is coordinated by two N atoms from one molecule of the aromatic base and four O atoms from two bidentate, symmetry-related acetate anions, which coordinate asymmetrically [Zn—O distances of 2.058 (2) and 2.362 (3) Å], while the two Zn—N bond distances are equal as imposed by symmetry [2.079 (2) Å]. The crystal structure is supported by a number of weak C—H⋯O interactions and C—H⋯π contacts, with no π–π interactions present, mainly hindered by the substituent methyl groups and the relative molecular orientation. The result is a three-dimensional structure in which each molecule is linked to eight different neighbors. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515128/ /pubmed/23284355 http://dx.doi.org/10.1107/S1600536812042699 Text en © Harvey et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Harvey, Miguel A. Suarez, Sebastian A. Ibañez, Andres Doctorovich, Fabio Baggio, Ricardo Bis(acetato-κ(2) O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc |
title | Bis(acetato-κ(2)
O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc |
title_full | Bis(acetato-κ(2)
O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc |
title_fullStr | Bis(acetato-κ(2)
O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc |
title_full_unstemmed | Bis(acetato-κ(2)
O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc |
title_short | Bis(acetato-κ(2)
O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc |
title_sort | bis(acetato-κ(2)
o,o′)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)zinc |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515128/ https://www.ncbi.nlm.nih.gov/pubmed/23284355 http://dx.doi.org/10.1107/S1600536812042699 |
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