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Bis(acetato-κ(2) O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)­zinc

The mol­ecular structure of the title compound, [Zn(CH(3)COO)(2)(C(12)H(12)N(2))], consists of isolated mol­ecules bis­ected by a twofold rotation axis which goes through the Zn(II) cation and halves the organic base through the central C—C bond. The Zn(II) ion is coordinated by two N atoms from one...

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Autores principales: Harvey, Miguel A., Suarez, Sebastian A., Ibañez, Andres, Doctorovich, Fabio, Baggio, Ricardo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515128/
https://www.ncbi.nlm.nih.gov/pubmed/23284355
http://dx.doi.org/10.1107/S1600536812042699
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author Harvey, Miguel A.
Suarez, Sebastian A.
Ibañez, Andres
Doctorovich, Fabio
Baggio, Ricardo
author_facet Harvey, Miguel A.
Suarez, Sebastian A.
Ibañez, Andres
Doctorovich, Fabio
Baggio, Ricardo
author_sort Harvey, Miguel A.
collection PubMed
description The mol­ecular structure of the title compound, [Zn(CH(3)COO)(2)(C(12)H(12)N(2))], consists of isolated mol­ecules bis­ected by a twofold rotation axis which goes through the Zn(II) cation and halves the organic base through the central C—C bond. The Zn(II) ion is coordinated by two N atoms from one mol­ecule of the aromatic base and four O atoms from two bidentate, symmetry-related acetate anions, which coordinate asym­metrically [Zn—O distances of 2.058 (2) and 2.362 (3) Å], while the two Zn—N bond distances are equal as imposed by symmetry [2.079 (2) Å]. The crystal structure is supported by a number of weak C—H⋯O inter­actions and C—H⋯π contacts, with no π–π inter­actions present, mainly hindered by the substituent methyl groups and the relative mol­ecular orientation. The result is a three-dimensional structure in which each mol­ecule is linked to eight different neighbors.
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spelling pubmed-35151282013-01-02 Bis(acetato-κ(2) O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)­zinc Harvey, Miguel A. Suarez, Sebastian A. Ibañez, Andres Doctorovich, Fabio Baggio, Ricardo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecular structure of the title compound, [Zn(CH(3)COO)(2)(C(12)H(12)N(2))], consists of isolated mol­ecules bis­ected by a twofold rotation axis which goes through the Zn(II) cation and halves the organic base through the central C—C bond. The Zn(II) ion is coordinated by two N atoms from one mol­ecule of the aromatic base and four O atoms from two bidentate, symmetry-related acetate anions, which coordinate asym­metrically [Zn—O distances of 2.058 (2) and 2.362 (3) Å], while the two Zn—N bond distances are equal as imposed by symmetry [2.079 (2) Å]. The crystal structure is supported by a number of weak C—H⋯O inter­actions and C—H⋯π contacts, with no π–π inter­actions present, mainly hindered by the substituent methyl groups and the relative mol­ecular orientation. The result is a three-dimensional structure in which each mol­ecule is linked to eight different neighbors. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515128/ /pubmed/23284355 http://dx.doi.org/10.1107/S1600536812042699 Text en © Harvey et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Harvey, Miguel A.
Suarez, Sebastian A.
Ibañez, Andres
Doctorovich, Fabio
Baggio, Ricardo
Bis(acetato-κ(2) O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)­zinc
title Bis(acetato-κ(2) O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)­zinc
title_full Bis(acetato-κ(2) O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)­zinc
title_fullStr Bis(acetato-κ(2) O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)­zinc
title_full_unstemmed Bis(acetato-κ(2) O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)­zinc
title_short Bis(acetato-κ(2) O,O′)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)­zinc
title_sort bis(acetato-κ(2) o,o′)(4,4′-dimethyl-2,2′-bipyridine-κ(2) n,n′)­zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515128/
https://www.ncbi.nlm.nih.gov/pubmed/23284355
http://dx.doi.org/10.1107/S1600536812042699
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