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Bis(μ-3-nitrobenzene-1,2-dicarboxylato)-κ(4) O (1),O (2):O (1),O (1′);κ(4) O (1),O (1′):O (1),O (2)-bis[triaqua(6-carboxy-2-nitrobenzoato-κ(2) O (1),O (6))neodymium(III)] dihydrate
The title complex, [Nd(2)(C(8)H(3)NO(6))(2)(C(8)H(4)NO(6))(2)(H(2)O)(6)]·2H(2)O, consists of dimeric units related by an inversion center. The Nd(III) atom is nine-coordinated by three O atoms from water molecules and six from carboxylate atoms. The 1,2-dicarboxylate acid molecules are in a single...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515129/ https://www.ncbi.nlm.nih.gov/pubmed/23284356 http://dx.doi.org/10.1107/S1600536812042754 |
Sumario: | The title complex, [Nd(2)(C(8)H(3)NO(6))(2)(C(8)H(4)NO(6))(2)(H(2)O)(6)]·2H(2)O, consists of dimeric units related by an inversion center. The Nd(III) atom is nine-coordinated by three O atoms from water molecules and six from carboxylate atoms. The 1,2-dicarboxylate acid molecules are in a single and double deprotonation stage and exhibit two coordination modes, viz. μ(2)-(κ(4), O (1): O (2): O (2): O (3)) and μ(1)-(κ(2), O (2): O (3)), which are responsible for the dimeric structure framework. The dimeric structure is then assembled into a three-dimensional supramolecular framework via O—H⋯O hydrogen bonds. |
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