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Bis(μ-3-nitrobenzene-1,2-dicarboxylato)-κ(4) O (1),O (2):O (1),O (1′);κ(4) O (1),O (1′):O (1),O (2)-bis[triaqua(6-carboxy-2-nitrobenzoato-κ(2) O (1),O (6))neodymium(III)] dihydrate
The title complex, [Nd(2)(C(8)H(3)NO(6))(2)(C(8)H(4)NO(6))(2)(H(2)O)(6)]·2H(2)O, consists of dimeric units related by an inversion center. The Nd(III) atom is nine-coordinated by three O atoms from water molecules and six from carboxylate atoms. The 1,2-dicarboxylate acid molecules are in a single...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515129/ https://www.ncbi.nlm.nih.gov/pubmed/23284356 http://dx.doi.org/10.1107/S1600536812042754 |
| _version_ | 1782252117028765696 |
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| author | Chang, Yin-cheng Pei, Zhi-chao Shuai, Qi |
| author_facet | Chang, Yin-cheng Pei, Zhi-chao Shuai, Qi |
| author_sort | Chang, Yin-cheng |
| collection | PubMed |
| description | The title complex, [Nd(2)(C(8)H(3)NO(6))(2)(C(8)H(4)NO(6))(2)(H(2)O)(6)]·2H(2)O, consists of dimeric units related by an inversion center. The Nd(III) atom is nine-coordinated by three O atoms from water molecules and six from carboxylate atoms. The 1,2-dicarboxylate acid molecules are in a single and double deprotonation stage and exhibit two coordination modes, viz. μ(2)-(κ(4), O (1): O (2): O (2): O (3)) and μ(1)-(κ(2), O (2): O (3)), which are responsible for the dimeric structure framework. The dimeric structure is then assembled into a three-dimensional supramolecular framework via O—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3515129 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35151292013-01-02 Bis(μ-3-nitrobenzene-1,2-dicarboxylato)-κ(4) O (1),O (2):O (1),O (1′);κ(4) O (1),O (1′):O (1),O (2)-bis[triaqua(6-carboxy-2-nitrobenzoato-κ(2) O (1),O (6))neodymium(III)] dihydrate Chang, Yin-cheng Pei, Zhi-chao Shuai, Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Nd(2)(C(8)H(3)NO(6))(2)(C(8)H(4)NO(6))(2)(H(2)O)(6)]·2H(2)O, consists of dimeric units related by an inversion center. The Nd(III) atom is nine-coordinated by three O atoms from water molecules and six from carboxylate atoms. The 1,2-dicarboxylate acid molecules are in a single and double deprotonation stage and exhibit two coordination modes, viz. μ(2)-(κ(4), O (1): O (2): O (2): O (3)) and μ(1)-(κ(2), O (2): O (3)), which are responsible for the dimeric structure framework. The dimeric structure is then assembled into a three-dimensional supramolecular framework via O—H⋯O hydrogen bonds. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515129/ /pubmed/23284356 http://dx.doi.org/10.1107/S1600536812042754 Text en © Chang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chang, Yin-cheng Pei, Zhi-chao Shuai, Qi Bis(μ-3-nitrobenzene-1,2-dicarboxylato)-κ(4) O (1),O (2):O (1),O (1′);κ(4) O (1),O (1′):O (1),O (2)-bis[triaqua(6-carboxy-2-nitrobenzoato-κ(2) O (1),O (6))neodymium(III)] dihydrate |
| title | Bis(μ-3-nitrobenzene-1,2-dicarboxylato)-κ(4)
O
(1),O
(2):O
(1),O
(1′);κ(4)
O
(1),O
(1′):O
(1),O
(2)-bis[triaqua(6-carboxy-2-nitrobenzoato-κ(2)
O
(1),O
(6))neodymium(III)] dihydrate |
| title_full | Bis(μ-3-nitrobenzene-1,2-dicarboxylato)-κ(4)
O
(1),O
(2):O
(1),O
(1′);κ(4)
O
(1),O
(1′):O
(1),O
(2)-bis[triaqua(6-carboxy-2-nitrobenzoato-κ(2)
O
(1),O
(6))neodymium(III)] dihydrate |
| title_fullStr | Bis(μ-3-nitrobenzene-1,2-dicarboxylato)-κ(4)
O
(1),O
(2):O
(1),O
(1′);κ(4)
O
(1),O
(1′):O
(1),O
(2)-bis[triaqua(6-carboxy-2-nitrobenzoato-κ(2)
O
(1),O
(6))neodymium(III)] dihydrate |
| title_full_unstemmed | Bis(μ-3-nitrobenzene-1,2-dicarboxylato)-κ(4)
O
(1),O
(2):O
(1),O
(1′);κ(4)
O
(1),O
(1′):O
(1),O
(2)-bis[triaqua(6-carboxy-2-nitrobenzoato-κ(2)
O
(1),O
(6))neodymium(III)] dihydrate |
| title_short | Bis(μ-3-nitrobenzene-1,2-dicarboxylato)-κ(4)
O
(1),O
(2):O
(1),O
(1′);κ(4)
O
(1),O
(1′):O
(1),O
(2)-bis[triaqua(6-carboxy-2-nitrobenzoato-κ(2)
O
(1),O
(6))neodymium(III)] dihydrate |
| title_sort | bis(μ-3-nitrobenzene-1,2-dicarboxylato)-κ(4)
o
(1),o
(2):o
(1),o
(1′);κ(4)
o
(1),o
(1′):o
(1),o
(2)-bis[triaqua(6-carboxy-2-nitrobenzoato-κ(2)
o
(1),o
(6))neodymium(iii)] dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515129/ https://www.ncbi.nlm.nih.gov/pubmed/23284356 http://dx.doi.org/10.1107/S1600536812042754 |
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