3′-Ferrocenylcarbon­yl-1′-methyl-4′-phenyl­spiro­[indeno­[2,3-b]quinoxaline-11,2′-pyrrolidine]

In the title compound, [Fe(C(5)H(5))(C(31)H(24)N(3)O)], the pyrrolidine ring makes a dihedral angle of 86.3 (3)° with the mean plane [r.m.s deviation = 0.074 (2) Å] of the indeno-quinoxaline ring system. The central pyrrolidine ring adopts a twist conformation and the two cyclopentadienyl rings adop...

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Autores principales: Vijayakumar, B., Gavaskar, D., Srinivasan, T., Raghunathan, R., Velmurugan, D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515131/
https://www.ncbi.nlm.nih.gov/pubmed/23284358
http://dx.doi.org/10.1107/S1600536812042468
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author Vijayakumar, B.
Gavaskar, D.
Srinivasan, T.
Raghunathan, R.
Velmurugan, D.
author_facet Vijayakumar, B.
Gavaskar, D.
Srinivasan, T.
Raghunathan, R.
Velmurugan, D.
author_sort Vijayakumar, B.
collection PubMed
description In the title compound, [Fe(C(5)H(5))(C(31)H(24)N(3)O)], the pyrrolidine ring makes a dihedral angle of 86.3 (3)° with the mean plane [r.m.s deviation = 0.074 (2) Å] of the indeno-quinoxaline ring system. The central pyrrolidine ring adopts a twist conformation and the two cyclopentadienyl rings adopt an eclipsed conformation. In the crystal, mol­ecules are linked by weak C—H⋯N and C—H⋯π inter­actions, propagating along the c and a axes, respectively.
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spelling pubmed-35151312013-01-02 3′-Ferrocenylcarbon­yl-1′-methyl-4′-phenyl­spiro­[indeno­[2,3-b]quinoxaline-11,2′-pyrrolidine] Vijayakumar, B. Gavaskar, D. Srinivasan, T. Raghunathan, R. Velmurugan, D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(31)H(24)N(3)O)], the pyrrolidine ring makes a dihedral angle of 86.3 (3)° with the mean plane [r.m.s deviation = 0.074 (2) Å] of the indeno-quinoxaline ring system. The central pyrrolidine ring adopts a twist conformation and the two cyclopentadienyl rings adopt an eclipsed conformation. In the crystal, mol­ecules are linked by weak C—H⋯N and C—H⋯π inter­actions, propagating along the c and a axes, respectively. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515131/ /pubmed/23284358 http://dx.doi.org/10.1107/S1600536812042468 Text en © Vijayakumar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Vijayakumar, B.
Gavaskar, D.
Srinivasan, T.
Raghunathan, R.
Velmurugan, D.
3′-Ferrocenylcarbon­yl-1′-methyl-4′-phenyl­spiro­[indeno­[2,3-b]quinoxaline-11,2′-pyrrolidine]
title 3′-Ferrocenylcarbon­yl-1′-methyl-4′-phenyl­spiro­[indeno­[2,3-b]quinoxaline-11,2′-pyrrolidine]
title_full 3′-Ferrocenylcarbon­yl-1′-methyl-4′-phenyl­spiro­[indeno­[2,3-b]quinoxaline-11,2′-pyrrolidine]
title_fullStr 3′-Ferrocenylcarbon­yl-1′-methyl-4′-phenyl­spiro­[indeno­[2,3-b]quinoxaline-11,2′-pyrrolidine]
title_full_unstemmed 3′-Ferrocenylcarbon­yl-1′-methyl-4′-phenyl­spiro­[indeno­[2,3-b]quinoxaline-11,2′-pyrrolidine]
title_short 3′-Ferrocenylcarbon­yl-1′-methyl-4′-phenyl­spiro­[indeno­[2,3-b]quinoxaline-11,2′-pyrrolidine]
title_sort 3′-ferrocenylcarbon­yl-1′-methyl-4′-phenyl­spiro­[indeno­[2,3-b]quinoxaline-11,2′-pyrrolidine]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515131/
https://www.ncbi.nlm.nih.gov/pubmed/23284358
http://dx.doi.org/10.1107/S1600536812042468
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