6-Benzyl-2-methyl-1,3-bis­(penta­fluoro­phen­yl)-1,3,6,2-triaza­alumocane

In the title compound, [Al(CH(3))(C(23)H(15)F(10)N(3))], the Al(III) atom is coordinated in a distorted tetra­hedral geometry by three N atoms from the tridentate amine and by one C atom of the methyl substituent. Further, there is a short intra­molecular Al⋯F contact [2.5717 (11) Å], leading to an...

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Autores principales: Kireenko, Marina M., Zaitsev, Kirill V., Churakov, Andrei V., Zaitseva, Galina S., Karlov, Sergey S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515133/
https://www.ncbi.nlm.nih.gov/pubmed/23284360
http://dx.doi.org/10.1107/S1600536812042560
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author Kireenko, Marina M.
Zaitsev, Kirill V.
Churakov, Andrei V.
Zaitseva, Galina S.
Karlov, Sergey S.
author_facet Kireenko, Marina M.
Zaitsev, Kirill V.
Churakov, Andrei V.
Zaitseva, Galina S.
Karlov, Sergey S.
author_sort Kireenko, Marina M.
collection PubMed
description In the title compound, [Al(CH(3))(C(23)H(15)F(10)N(3))], the Al(III) atom is coordinated in a distorted tetra­hedral geometry by three N atoms from the tridentate amine and by one C atom of the methyl substituent. Further, there is a short intra­molecular Al⋯F contact [2.5717 (11) Å], leading to an overall distorted trigonal–bipyramidal coordination environment around Al(III).
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spelling pubmed-35151332013-01-02 6-Benzyl-2-methyl-1,3-bis­(penta­fluoro­phen­yl)-1,3,6,2-triaza­alumocane Kireenko, Marina M. Zaitsev, Kirill V. Churakov, Andrei V. Zaitseva, Galina S. Karlov, Sergey S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Al(CH(3))(C(23)H(15)F(10)N(3))], the Al(III) atom is coordinated in a distorted tetra­hedral geometry by three N atoms from the tridentate amine and by one C atom of the methyl substituent. Further, there is a short intra­molecular Al⋯F contact [2.5717 (11) Å], leading to an overall distorted trigonal–bipyramidal coordination environment around Al(III). International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515133/ /pubmed/23284360 http://dx.doi.org/10.1107/S1600536812042560 Text en © Kireenko et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kireenko, Marina M.
Zaitsev, Kirill V.
Churakov, Andrei V.
Zaitseva, Galina S.
Karlov, Sergey S.
6-Benzyl-2-methyl-1,3-bis­(penta­fluoro­phen­yl)-1,3,6,2-triaza­alumocane
title 6-Benzyl-2-methyl-1,3-bis­(penta­fluoro­phen­yl)-1,3,6,2-triaza­alumocane
title_full 6-Benzyl-2-methyl-1,3-bis­(penta­fluoro­phen­yl)-1,3,6,2-triaza­alumocane
title_fullStr 6-Benzyl-2-methyl-1,3-bis­(penta­fluoro­phen­yl)-1,3,6,2-triaza­alumocane
title_full_unstemmed 6-Benzyl-2-methyl-1,3-bis­(penta­fluoro­phen­yl)-1,3,6,2-triaza­alumocane
title_short 6-Benzyl-2-methyl-1,3-bis­(penta­fluoro­phen­yl)-1,3,6,2-triaza­alumocane
title_sort 6-benzyl-2-methyl-1,3-bis­(penta­fluoro­phen­yl)-1,3,6,2-triaza­alumocane
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515133/
https://www.ncbi.nlm.nih.gov/pubmed/23284360
http://dx.doi.org/10.1107/S1600536812042560
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