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cis-(2,2′-Bipyridine-κ(2) N,N′)bis­(isonicotinamide-κN (1))palladium(II) bis­(hexa­fluoridophosphate)

In the title salt, [Pd(C(10)H(8)N(2))(C(6)H(6)NO)(2)](PF(6))(2), the Pd(II) atom is in a slightly distorted square-planar coordination environment by N atoms derived from two 4-pyridine­carboxamide ligands, in a cis disposition, and a chelating 2,2′-bipyridine mol­ecule. The monodentate ligands are...

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Detalles Bibliográficos
Autores principales: Adrian, Rafael A., Quintela, Brayan, Powell, Douglas R., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515136/
https://www.ncbi.nlm.nih.gov/pubmed/23284363
http://dx.doi.org/10.1107/S1600536812043036
Descripción
Sumario:In the title salt, [Pd(C(10)H(8)N(2))(C(6)H(6)NO)(2)](PF(6))(2), the Pd(II) atom is in a slightly distorted square-planar coordination environment by N atoms derived from two 4-pyridine­carboxamide ligands, in a cis disposition, and a chelating 2,2′-bipyridine mol­ecule. The monodentate ligands are nearly orthogonal to each other [dihedral angle = 85.7 (5)°] and to the PdN(4) plane [dihedral angles = 79.3 (3) and 78.7 (3)°]. The amide O atoms lie to opposite sides of the PdN(4) plane. The most notable feature of the crystal packing is a linear supra­molecular chain orientated approximately along [310] and formed via 16-membered {⋯HNCO}(4) motifs. These are connected into a three-dimensional network by amide–H⋯O, F inter­actions. Both PF(6) (−) anions are disordered over two positions of equal occupancy in respect of the F atoms.