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cis-(2,2′-Bipyridine-κ(2) N,N′)bis­(isonicotinamide-κN (1))palladium(II) bis­(hexa­fluoridophosphate)

In the title salt, [Pd(C(10)H(8)N(2))(C(6)H(6)NO)(2)](PF(6))(2), the Pd(II) atom is in a slightly distorted square-planar coordination environment by N atoms derived from two 4-pyridine­carboxamide ligands, in a cis disposition, and a chelating 2,2′-bipyridine mol­ecule. The monodentate ligands are...

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Autores principales: Adrian, Rafael A., Quintela, Brayan, Powell, Douglas R., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515136/
https://www.ncbi.nlm.nih.gov/pubmed/23284363
http://dx.doi.org/10.1107/S1600536812043036
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author Adrian, Rafael A.
Quintela, Brayan
Powell, Douglas R.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Adrian, Rafael A.
Quintela, Brayan
Powell, Douglas R.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Adrian, Rafael A.
collection PubMed
description In the title salt, [Pd(C(10)H(8)N(2))(C(6)H(6)NO)(2)](PF(6))(2), the Pd(II) atom is in a slightly distorted square-planar coordination environment by N atoms derived from two 4-pyridine­carboxamide ligands, in a cis disposition, and a chelating 2,2′-bipyridine mol­ecule. The monodentate ligands are nearly orthogonal to each other [dihedral angle = 85.7 (5)°] and to the PdN(4) plane [dihedral angles = 79.3 (3) and 78.7 (3)°]. The amide O atoms lie to opposite sides of the PdN(4) plane. The most notable feature of the crystal packing is a linear supra­molecular chain orientated approximately along [310] and formed via 16-membered {⋯HNCO}(4) motifs. These are connected into a three-dimensional network by amide–H⋯O, F inter­actions. Both PF(6) (−) anions are disordered over two positions of equal occupancy in respect of the F atoms.
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spelling pubmed-35151362013-01-02 cis-(2,2′-Bipyridine-κ(2) N,N′)bis­(isonicotinamide-κN (1))palladium(II) bis­(hexa­fluoridophosphate) Adrian, Rafael A. Quintela, Brayan Powell, Douglas R. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Pd(C(10)H(8)N(2))(C(6)H(6)NO)(2)](PF(6))(2), the Pd(II) atom is in a slightly distorted square-planar coordination environment by N atoms derived from two 4-pyridine­carboxamide ligands, in a cis disposition, and a chelating 2,2′-bipyridine mol­ecule. The monodentate ligands are nearly orthogonal to each other [dihedral angle = 85.7 (5)°] and to the PdN(4) plane [dihedral angles = 79.3 (3) and 78.7 (3)°]. The amide O atoms lie to opposite sides of the PdN(4) plane. The most notable feature of the crystal packing is a linear supra­molecular chain orientated approximately along [310] and formed via 16-membered {⋯HNCO}(4) motifs. These are connected into a three-dimensional network by amide–H⋯O, F inter­actions. Both PF(6) (−) anions are disordered over two positions of equal occupancy in respect of the F atoms. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515136/ /pubmed/23284363 http://dx.doi.org/10.1107/S1600536812043036 Text en © Adrian et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Adrian, Rafael A.
Quintela, Brayan
Powell, Douglas R.
Ng, Seik Weng
Tiekink, Edward R. T.
cis-(2,2′-Bipyridine-κ(2) N,N′)bis­(isonicotinamide-κN (1))palladium(II) bis­(hexa­fluoridophosphate)
title cis-(2,2′-Bipyridine-κ(2) N,N′)bis­(isonicotinamide-κN (1))palladium(II) bis­(hexa­fluoridophosphate)
title_full cis-(2,2′-Bipyridine-κ(2) N,N′)bis­(isonicotinamide-κN (1))palladium(II) bis­(hexa­fluoridophosphate)
title_fullStr cis-(2,2′-Bipyridine-κ(2) N,N′)bis­(isonicotinamide-κN (1))palladium(II) bis­(hexa­fluoridophosphate)
title_full_unstemmed cis-(2,2′-Bipyridine-κ(2) N,N′)bis­(isonicotinamide-κN (1))palladium(II) bis­(hexa­fluoridophosphate)
title_short cis-(2,2′-Bipyridine-κ(2) N,N′)bis­(isonicotinamide-κN (1))palladium(II) bis­(hexa­fluoridophosphate)
title_sort cis-(2,2′-bipyridine-κ(2) n,n′)bis­(isonicotinamide-κn (1))palladium(ii) bis­(hexa­fluoridophosphate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515136/
https://www.ncbi.nlm.nih.gov/pubmed/23284363
http://dx.doi.org/10.1107/S1600536812043036
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