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cis-(2,2′-Bipyridine-κ(2) N,N′)bis(isonicotinamide-κN (1))palladium(II) bis(hexafluoridophosphate)
In the title salt, [Pd(C(10)H(8)N(2))(C(6)H(6)NO)(2)](PF(6))(2), the Pd(II) atom is in a slightly distorted square-planar coordination environment by N atoms derived from two 4-pyridinecarboxamide ligands, in a cis disposition, and a chelating 2,2′-bipyridine molecule. The monodentate ligands are...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515136/ https://www.ncbi.nlm.nih.gov/pubmed/23284363 http://dx.doi.org/10.1107/S1600536812043036 |
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author | Adrian, Rafael A. Quintela, Brayan Powell, Douglas R. Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Adrian, Rafael A. Quintela, Brayan Powell, Douglas R. Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Adrian, Rafael A. |
collection | PubMed |
description | In the title salt, [Pd(C(10)H(8)N(2))(C(6)H(6)NO)(2)](PF(6))(2), the Pd(II) atom is in a slightly distorted square-planar coordination environment by N atoms derived from two 4-pyridinecarboxamide ligands, in a cis disposition, and a chelating 2,2′-bipyridine molecule. The monodentate ligands are nearly orthogonal to each other [dihedral angle = 85.7 (5)°] and to the PdN(4) plane [dihedral angles = 79.3 (3) and 78.7 (3)°]. The amide O atoms lie to opposite sides of the PdN(4) plane. The most notable feature of the crystal packing is a linear supramolecular chain orientated approximately along [310] and formed via 16-membered {⋯HNCO}(4) motifs. These are connected into a three-dimensional network by amide–H⋯O, F interactions. Both PF(6) (−) anions are disordered over two positions of equal occupancy in respect of the F atoms. |
format | Online Article Text |
id | pubmed-3515136 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151362013-01-02 cis-(2,2′-Bipyridine-κ(2) N,N′)bis(isonicotinamide-κN (1))palladium(II) bis(hexafluoridophosphate) Adrian, Rafael A. Quintela, Brayan Powell, Douglas R. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Pd(C(10)H(8)N(2))(C(6)H(6)NO)(2)](PF(6))(2), the Pd(II) atom is in a slightly distorted square-planar coordination environment by N atoms derived from two 4-pyridinecarboxamide ligands, in a cis disposition, and a chelating 2,2′-bipyridine molecule. The monodentate ligands are nearly orthogonal to each other [dihedral angle = 85.7 (5)°] and to the PdN(4) plane [dihedral angles = 79.3 (3) and 78.7 (3)°]. The amide O atoms lie to opposite sides of the PdN(4) plane. The most notable feature of the crystal packing is a linear supramolecular chain orientated approximately along [310] and formed via 16-membered {⋯HNCO}(4) motifs. These are connected into a three-dimensional network by amide–H⋯O, F interactions. Both PF(6) (−) anions are disordered over two positions of equal occupancy in respect of the F atoms. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515136/ /pubmed/23284363 http://dx.doi.org/10.1107/S1600536812043036 Text en © Adrian et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Adrian, Rafael A. Quintela, Brayan Powell, Douglas R. Ng, Seik Weng Tiekink, Edward R. T. cis-(2,2′-Bipyridine-κ(2) N,N′)bis(isonicotinamide-κN (1))palladium(II) bis(hexafluoridophosphate) |
title |
cis-(2,2′-Bipyridine-κ(2)
N,N′)bis(isonicotinamide-κN
(1))palladium(II) bis(hexafluoridophosphate) |
title_full |
cis-(2,2′-Bipyridine-κ(2)
N,N′)bis(isonicotinamide-κN
(1))palladium(II) bis(hexafluoridophosphate) |
title_fullStr |
cis-(2,2′-Bipyridine-κ(2)
N,N′)bis(isonicotinamide-κN
(1))palladium(II) bis(hexafluoridophosphate) |
title_full_unstemmed |
cis-(2,2′-Bipyridine-κ(2)
N,N′)bis(isonicotinamide-κN
(1))palladium(II) bis(hexafluoridophosphate) |
title_short |
cis-(2,2′-Bipyridine-κ(2)
N,N′)bis(isonicotinamide-κN
(1))palladium(II) bis(hexafluoridophosphate) |
title_sort | cis-(2,2′-bipyridine-κ(2)
n,n′)bis(isonicotinamide-κn
(1))palladium(ii) bis(hexafluoridophosphate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515136/ https://www.ncbi.nlm.nih.gov/pubmed/23284363 http://dx.doi.org/10.1107/S1600536812043036 |
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