(Acetyl­acetonato-κ(2) O,O′)dichlorido­bis(methano­lato-κO)niobium(V)

In the title compound, [Nb(CH(3)O)(2)(C(5)H(7)O(2))Cl(2)], a slightly distorted octa­hedral coordination geometry is observed around the Nb(V) atom with Nb—O distances in the range of 1.8254 (16)–2.0892 (16) Å and Nb—Cl distances of 2.3997 (14) and 2.4023 (12) Å. The O—Nb—O angles vary between 81.36...

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Detalles Bibliográficos
Autores principales: Herbst, Leandra, Visser, Hendrik G., Roodt, Andreas, Pretorius, Carla
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515137/
https://www.ncbi.nlm.nih.gov/pubmed/23284364
http://dx.doi.org/10.1107/S1600536812042638
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author Herbst, Leandra
Visser, Hendrik G.
Roodt, Andreas
Pretorius, Carla
author_facet Herbst, Leandra
Visser, Hendrik G.
Roodt, Andreas
Pretorius, Carla
author_sort Herbst, Leandra
collection PubMed
description In the title compound, [Nb(CH(3)O)(2)(C(5)H(7)O(2))Cl(2)], a slightly distorted octa­hedral coordination geometry is observed around the Nb(V) atom with Nb—O distances in the range of 1.8254 (16)–2.0892 (16) Å and Nb—Cl distances of 2.3997 (14) and 2.4023 (12) Å. The O—Nb—O angles vary between 81.36 (7) and 172.65 (7) °, while the trans Cl—Nb—Cl angle is 167.34 (2)°. There are no hydrogen bonds observed.
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spelling pubmed-35151372013-01-02 (Acetyl­acetonato-κ(2) O,O′)dichlorido­bis(methano­lato-κO)niobium(V) Herbst, Leandra Visser, Hendrik G. Roodt, Andreas Pretorius, Carla Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Nb(CH(3)O)(2)(C(5)H(7)O(2))Cl(2)], a slightly distorted octa­hedral coordination geometry is observed around the Nb(V) atom with Nb—O distances in the range of 1.8254 (16)–2.0892 (16) Å and Nb—Cl distances of 2.3997 (14) and 2.4023 (12) Å. The O—Nb—O angles vary between 81.36 (7) and 172.65 (7) °, while the trans Cl—Nb—Cl angle is 167.34 (2)°. There are no hydrogen bonds observed. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515137/ /pubmed/23284364 http://dx.doi.org/10.1107/S1600536812042638 Text en © Herbst et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Herbst, Leandra
Visser, Hendrik G.
Roodt, Andreas
Pretorius, Carla
(Acetyl­acetonato-κ(2) O,O′)dichlorido­bis(methano­lato-κO)niobium(V)
title (Acetyl­acetonato-κ(2) O,O′)dichlorido­bis(methano­lato-κO)niobium(V)
title_full (Acetyl­acetonato-κ(2) O,O′)dichlorido­bis(methano­lato-κO)niobium(V)
title_fullStr (Acetyl­acetonato-κ(2) O,O′)dichlorido­bis(methano­lato-κO)niobium(V)
title_full_unstemmed (Acetyl­acetonato-κ(2) O,O′)dichlorido­bis(methano­lato-κO)niobium(V)
title_short (Acetyl­acetonato-κ(2) O,O′)dichlorido­bis(methano­lato-κO)niobium(V)
title_sort (acetyl­acetonato-κ(2) o,o′)dichlorido­bis(methano­lato-κo)niobium(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515137/
https://www.ncbi.nlm.nih.gov/pubmed/23284364
http://dx.doi.org/10.1107/S1600536812042638
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AT pretoriuscarla acetylacetonatok2oodichloridobismethanolatokoniobiumv

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