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Tetra­aqua­bis­(6-chloro­pyridine-3-carboxyl­ato-κO)nickel(II) tetra­hydrate

In the title compound, [Ni(C(6)H(3)ClNO(2))(2)(H(2)O)(4)]·4H(2)O, the Ni(II) ion is located on an inversion centre and is octa­hedrally coordinated by four O atoms from four water mol­ecules in the equatorial plane and two O atoms of two 6-chloro-3-carboxyl­ate ligands in axial positions. There are...

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Autores principales: Xia, Qiao-Hua, Guo, Zhong-Fu, Liu, Li, Lv, Jian-Quan, Li, Bing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515138/
https://www.ncbi.nlm.nih.gov/pubmed/23284365
http://dx.doi.org/10.1107/S160053681204322X
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author Xia, Qiao-Hua
Guo, Zhong-Fu
Liu, Li
Lv, Jian-Quan
Li, Bing
author_facet Xia, Qiao-Hua
Guo, Zhong-Fu
Liu, Li
Lv, Jian-Quan
Li, Bing
author_sort Xia, Qiao-Hua
collection PubMed
description In the title compound, [Ni(C(6)H(3)ClNO(2))(2)(H(2)O)(4)]·4H(2)O, the Ni(II) ion is located on an inversion centre and is octa­hedrally coordinated by four O atoms from four water mol­ecules in the equatorial plane and two O atoms of two 6-chloro-3-carboxyl­ate ligands in axial positions. There are also four lattice water molecules present. The organic ligands are bound to the Ni(II) ion in a monodentate manner through a carboxyl­ate O atom. There is one strong intra­molecular O—H⋯O hydrogen bond and six inter­molecular O—H⋯O and O—H⋯N hydrogen-bonding inter­actions in the packing, resulting in a complex three-dimensional network structure.
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spelling pubmed-35151382013-01-02 Tetra­aqua­bis­(6-chloro­pyridine-3-carboxyl­ato-κO)nickel(II) tetra­hydrate Xia, Qiao-Hua Guo, Zhong-Fu Liu, Li Lv, Jian-Quan Li, Bing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(6)H(3)ClNO(2))(2)(H(2)O)(4)]·4H(2)O, the Ni(II) ion is located on an inversion centre and is octa­hedrally coordinated by four O atoms from four water mol­ecules in the equatorial plane and two O atoms of two 6-chloro-3-carboxyl­ate ligands in axial positions. There are also four lattice water molecules present. The organic ligands are bound to the Ni(II) ion in a monodentate manner through a carboxyl­ate O atom. There is one strong intra­molecular O—H⋯O hydrogen bond and six inter­molecular O—H⋯O and O—H⋯N hydrogen-bonding inter­actions in the packing, resulting in a complex three-dimensional network structure. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515138/ /pubmed/23284365 http://dx.doi.org/10.1107/S160053681204322X Text en © Xia et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xia, Qiao-Hua
Guo, Zhong-Fu
Liu, Li
Lv, Jian-Quan
Li, Bing
Tetra­aqua­bis­(6-chloro­pyridine-3-carboxyl­ato-κO)nickel(II) tetra­hydrate
title Tetra­aqua­bis­(6-chloro­pyridine-3-carboxyl­ato-κO)nickel(II) tetra­hydrate
title_full Tetra­aqua­bis­(6-chloro­pyridine-3-carboxyl­ato-κO)nickel(II) tetra­hydrate
title_fullStr Tetra­aqua­bis­(6-chloro­pyridine-3-carboxyl­ato-κO)nickel(II) tetra­hydrate
title_full_unstemmed Tetra­aqua­bis­(6-chloro­pyridine-3-carboxyl­ato-κO)nickel(II) tetra­hydrate
title_short Tetra­aqua­bis­(6-chloro­pyridine-3-carboxyl­ato-κO)nickel(II) tetra­hydrate
title_sort tetra­aqua­bis­(6-chloro­pyridine-3-carboxyl­ato-κo)nickel(ii) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515138/
https://www.ncbi.nlm.nih.gov/pubmed/23284365
http://dx.doi.org/10.1107/S160053681204322X
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