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Tetraaquabis(6-chloropyridine-3-carboxylato-κO)nickel(II) tetrahydrate
In the title compound, [Ni(C(6)H(3)ClNO(2))(2)(H(2)O)(4)]·4H(2)O, the Ni(II) ion is located on an inversion centre and is octahedrally coordinated by four O atoms from four water molecules in the equatorial plane and two O atoms of two 6-chloro-3-carboxylate ligands in axial positions. There are...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515138/ https://www.ncbi.nlm.nih.gov/pubmed/23284365 http://dx.doi.org/10.1107/S160053681204322X |
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author | Xia, Qiao-Hua Guo, Zhong-Fu Liu, Li Lv, Jian-Quan Li, Bing |
author_facet | Xia, Qiao-Hua Guo, Zhong-Fu Liu, Li Lv, Jian-Quan Li, Bing |
author_sort | Xia, Qiao-Hua |
collection | PubMed |
description | In the title compound, [Ni(C(6)H(3)ClNO(2))(2)(H(2)O)(4)]·4H(2)O, the Ni(II) ion is located on an inversion centre and is octahedrally coordinated by four O atoms from four water molecules in the equatorial plane and two O atoms of two 6-chloro-3-carboxylate ligands in axial positions. There are also four lattice water molecules present. The organic ligands are bound to the Ni(II) ion in a monodentate manner through a carboxylate O atom. There is one strong intramolecular O—H⋯O hydrogen bond and six intermolecular O—H⋯O and O—H⋯N hydrogen-bonding interactions in the packing, resulting in a complex three-dimensional network structure. |
format | Online Article Text |
id | pubmed-3515138 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151382013-01-02 Tetraaquabis(6-chloropyridine-3-carboxylato-κO)nickel(II) tetrahydrate Xia, Qiao-Hua Guo, Zhong-Fu Liu, Li Lv, Jian-Quan Li, Bing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(6)H(3)ClNO(2))(2)(H(2)O)(4)]·4H(2)O, the Ni(II) ion is located on an inversion centre and is octahedrally coordinated by four O atoms from four water molecules in the equatorial plane and two O atoms of two 6-chloro-3-carboxylate ligands in axial positions. There are also four lattice water molecules present. The organic ligands are bound to the Ni(II) ion in a monodentate manner through a carboxylate O atom. There is one strong intramolecular O—H⋯O hydrogen bond and six intermolecular O—H⋯O and O—H⋯N hydrogen-bonding interactions in the packing, resulting in a complex three-dimensional network structure. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515138/ /pubmed/23284365 http://dx.doi.org/10.1107/S160053681204322X Text en © Xia et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xia, Qiao-Hua Guo, Zhong-Fu Liu, Li Lv, Jian-Quan Li, Bing Tetraaquabis(6-chloropyridine-3-carboxylato-κO)nickel(II) tetrahydrate |
title | Tetraaquabis(6-chloropyridine-3-carboxylato-κO)nickel(II) tetrahydrate |
title_full | Tetraaquabis(6-chloropyridine-3-carboxylato-κO)nickel(II) tetrahydrate |
title_fullStr | Tetraaquabis(6-chloropyridine-3-carboxylato-κO)nickel(II) tetrahydrate |
title_full_unstemmed | Tetraaquabis(6-chloropyridine-3-carboxylato-κO)nickel(II) tetrahydrate |
title_short | Tetraaquabis(6-chloropyridine-3-carboxylato-κO)nickel(II) tetrahydrate |
title_sort | tetraaquabis(6-chloropyridine-3-carboxylato-κo)nickel(ii) tetrahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515138/ https://www.ncbi.nlm.nih.gov/pubmed/23284365 http://dx.doi.org/10.1107/S160053681204322X |
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