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catena-Poly[[[diaqua­copper(II)]-μ-quinoline-2,3-dicarboxyl­ato-κ(3) N,O (2):O (3)] monohydrate]

In the title compound, {[Cu(C(11)H(5)NO(4))(H(2)O)(2)]·H(2)O}(n), the Cu(II) ion is five-coordinated by two O atoms and one N atom of two symmetry-related quinoline-2,3-dicarboxyl­ate ligands, and two water mol­ecules. The water mol­ecules occupy basal and apical positions of the square-pyramidal co...

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Detalles Bibliográficos
Autores principales: Xia, Qiao-Hua, Guo, Zhong-Fu, Liu, Li, Wang, Zhi-kun, Li, Bing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515140/
https://www.ncbi.nlm.nih.gov/pubmed/23284367
http://dx.doi.org/10.1107/S1600536812043206
Descripción
Sumario:In the title compound, {[Cu(C(11)H(5)NO(4))(H(2)O)(2)]·H(2)O}(n), the Cu(II) ion is five-coordinated by two O atoms and one N atom of two symmetry-related quinoline-2,3-dicarboxyl­ate ligands, and two water mol­ecules. The water mol­ecules occupy basal and apical positions of the square-pyramidal coordination polyhedron. Each quinoline-2,3-dicarboxyl­ate dianion bridges two adjacent Cu(II) ions, forming a polymeric chain along [010]. The chains are further connected via O—H⋯O hydrogen-bonding inter­actions and quinoline ring π–π inter­actions [centroid–centroid distance = 3.725 (4) Å], generating a three-dimensional structure. Lattice water mol­ecules participate in the crystal structure via O—H⋯O hydrogen bonds.