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catena-Poly[[[diaquacopper(II)]-μ-quinoline-2,3-dicarboxylato-κ(3) N,O (2):O (3)] monohydrate]
In the title compound, {[Cu(C(11)H(5)NO(4))(H(2)O)(2)]·H(2)O}(n), the Cu(II) ion is five-coordinated by two O atoms and one N atom of two symmetry-related quinoline-2,3-dicarboxylate ligands, and two water molecules. The water molecules occupy basal and apical positions of the square-pyramidal co...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515140/ https://www.ncbi.nlm.nih.gov/pubmed/23284367 http://dx.doi.org/10.1107/S1600536812043206 |
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author | Xia, Qiao-Hua Guo, Zhong-Fu Liu, Li Wang, Zhi-kun Li, Bing |
author_facet | Xia, Qiao-Hua Guo, Zhong-Fu Liu, Li Wang, Zhi-kun Li, Bing |
author_sort | Xia, Qiao-Hua |
collection | PubMed |
description | In the title compound, {[Cu(C(11)H(5)NO(4))(H(2)O)(2)]·H(2)O}(n), the Cu(II) ion is five-coordinated by two O atoms and one N atom of two symmetry-related quinoline-2,3-dicarboxylate ligands, and two water molecules. The water molecules occupy basal and apical positions of the square-pyramidal coordination polyhedron. Each quinoline-2,3-dicarboxylate dianion bridges two adjacent Cu(II) ions, forming a polymeric chain along [010]. The chains are further connected via O—H⋯O hydrogen-bonding interactions and quinoline ring π–π interactions [centroid–centroid distance = 3.725 (4) Å], generating a three-dimensional structure. Lattice water molecules participate in the crystal structure via O—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3515140 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151402013-01-02 catena-Poly[[[diaquacopper(II)]-μ-quinoline-2,3-dicarboxylato-κ(3) N,O (2):O (3)] monohydrate] Xia, Qiao-Hua Guo, Zhong-Fu Liu, Li Wang, Zhi-kun Li, Bing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(C(11)H(5)NO(4))(H(2)O)(2)]·H(2)O}(n), the Cu(II) ion is five-coordinated by two O atoms and one N atom of two symmetry-related quinoline-2,3-dicarboxylate ligands, and two water molecules. The water molecules occupy basal and apical positions of the square-pyramidal coordination polyhedron. Each quinoline-2,3-dicarboxylate dianion bridges two adjacent Cu(II) ions, forming a polymeric chain along [010]. The chains are further connected via O—H⋯O hydrogen-bonding interactions and quinoline ring π–π interactions [centroid–centroid distance = 3.725 (4) Å], generating a three-dimensional structure. Lattice water molecules participate in the crystal structure via O—H⋯O hydrogen bonds. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515140/ /pubmed/23284367 http://dx.doi.org/10.1107/S1600536812043206 Text en © Xia et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xia, Qiao-Hua Guo, Zhong-Fu Liu, Li Wang, Zhi-kun Li, Bing catena-Poly[[[diaquacopper(II)]-μ-quinoline-2,3-dicarboxylato-κ(3) N,O (2):O (3)] monohydrate] |
title |
catena-Poly[[[diaquacopper(II)]-μ-quinoline-2,3-dicarboxylato-κ(3)
N,O
(2):O
(3)] monohydrate] |
title_full |
catena-Poly[[[diaquacopper(II)]-μ-quinoline-2,3-dicarboxylato-κ(3)
N,O
(2):O
(3)] monohydrate] |
title_fullStr |
catena-Poly[[[diaquacopper(II)]-μ-quinoline-2,3-dicarboxylato-κ(3)
N,O
(2):O
(3)] monohydrate] |
title_full_unstemmed |
catena-Poly[[[diaquacopper(II)]-μ-quinoline-2,3-dicarboxylato-κ(3)
N,O
(2):O
(3)] monohydrate] |
title_short |
catena-Poly[[[diaquacopper(II)]-μ-quinoline-2,3-dicarboxylato-κ(3)
N,O
(2):O
(3)] monohydrate] |
title_sort | catena-poly[[[diaquacopper(ii)]-μ-quinoline-2,3-dicarboxylato-κ(3)
n,o
(2):o
(3)] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515140/ https://www.ncbi.nlm.nih.gov/pubmed/23284367 http://dx.doi.org/10.1107/S1600536812043206 |
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