Cargando…

catena-Poly[[[diaqua­copper(II)]-μ-quinoline-2,3-dicarboxyl­ato-κ(3) N,O (2):O (3)] monohydrate]

In the title compound, {[Cu(C(11)H(5)NO(4))(H(2)O)(2)]·H(2)O}(n), the Cu(II) ion is five-coordinated by two O atoms and one N atom of two symmetry-related quinoline-2,3-dicarboxyl­ate ligands, and two water mol­ecules. The water mol­ecules occupy basal and apical positions of the square-pyramidal co...

Descripción completa

Detalles Bibliográficos
Autores principales: Xia, Qiao-Hua, Guo, Zhong-Fu, Liu, Li, Wang, Zhi-kun, Li, Bing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515140/
https://www.ncbi.nlm.nih.gov/pubmed/23284367
http://dx.doi.org/10.1107/S1600536812043206
_version_ 1782252119619796992
author Xia, Qiao-Hua
Guo, Zhong-Fu
Liu, Li
Wang, Zhi-kun
Li, Bing
author_facet Xia, Qiao-Hua
Guo, Zhong-Fu
Liu, Li
Wang, Zhi-kun
Li, Bing
author_sort Xia, Qiao-Hua
collection PubMed
description In the title compound, {[Cu(C(11)H(5)NO(4))(H(2)O)(2)]·H(2)O}(n), the Cu(II) ion is five-coordinated by two O atoms and one N atom of two symmetry-related quinoline-2,3-dicarboxyl­ate ligands, and two water mol­ecules. The water mol­ecules occupy basal and apical positions of the square-pyramidal coordination polyhedron. Each quinoline-2,3-dicarboxyl­ate dianion bridges two adjacent Cu(II) ions, forming a polymeric chain along [010]. The chains are further connected via O—H⋯O hydrogen-bonding inter­actions and quinoline ring π–π inter­actions [centroid–centroid distance = 3.725 (4) Å], generating a three-dimensional structure. Lattice water mol­ecules participate in the crystal structure via O—H⋯O hydrogen bonds.
format Online
Article
Text
id pubmed-3515140
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35151402013-01-02 catena-Poly[[[diaqua­copper(II)]-μ-quinoline-2,3-dicarboxyl­ato-κ(3) N,O (2):O (3)] monohydrate] Xia, Qiao-Hua Guo, Zhong-Fu Liu, Li Wang, Zhi-kun Li, Bing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(C(11)H(5)NO(4))(H(2)O)(2)]·H(2)O}(n), the Cu(II) ion is five-coordinated by two O atoms and one N atom of two symmetry-related quinoline-2,3-dicarboxyl­ate ligands, and two water mol­ecules. The water mol­ecules occupy basal and apical positions of the square-pyramidal coordination polyhedron. Each quinoline-2,3-dicarboxyl­ate dianion bridges two adjacent Cu(II) ions, forming a polymeric chain along [010]. The chains are further connected via O—H⋯O hydrogen-bonding inter­actions and quinoline ring π–π inter­actions [centroid–centroid distance = 3.725 (4) Å], generating a three-dimensional structure. Lattice water mol­ecules participate in the crystal structure via O—H⋯O hydrogen bonds. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515140/ /pubmed/23284367 http://dx.doi.org/10.1107/S1600536812043206 Text en © Xia et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xia, Qiao-Hua
Guo, Zhong-Fu
Liu, Li
Wang, Zhi-kun
Li, Bing
catena-Poly[[[diaqua­copper(II)]-μ-quinoline-2,3-dicarboxyl­ato-κ(3) N,O (2):O (3)] monohydrate]
title catena-Poly[[[diaqua­copper(II)]-μ-quinoline-2,3-dicarboxyl­ato-κ(3) N,O (2):O (3)] monohydrate]
title_full catena-Poly[[[diaqua­copper(II)]-μ-quinoline-2,3-dicarboxyl­ato-κ(3) N,O (2):O (3)] monohydrate]
title_fullStr catena-Poly[[[diaqua­copper(II)]-μ-quinoline-2,3-dicarboxyl­ato-κ(3) N,O (2):O (3)] monohydrate]
title_full_unstemmed catena-Poly[[[diaqua­copper(II)]-μ-quinoline-2,3-dicarboxyl­ato-κ(3) N,O (2):O (3)] monohydrate]
title_short catena-Poly[[[diaqua­copper(II)]-μ-quinoline-2,3-dicarboxyl­ato-κ(3) N,O (2):O (3)] monohydrate]
title_sort catena-poly[[[diaqua­copper(ii)]-μ-quinoline-2,3-dicarboxyl­ato-κ(3) n,o (2):o (3)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515140/
https://www.ncbi.nlm.nih.gov/pubmed/23284367
http://dx.doi.org/10.1107/S1600536812043206
work_keys_str_mv AT xiaqiaohua catenapolydiaquacopperiimquinoline23dicarboxylatok3no2o3monohydrate
AT guozhongfu catenapolydiaquacopperiimquinoline23dicarboxylatok3no2o3monohydrate
AT liuli catenapolydiaquacopperiimquinoline23dicarboxylatok3no2o3monohydrate
AT wangzhikun catenapolydiaquacopperiimquinoline23dicarboxylatok3no2o3monohydrate
AT libing catenapolydiaquacopperiimquinoline23dicarboxylatok3no2o3monohydrate