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(Nitrato-κO)tris[tris(4-fluorophenyl)phosphane-κP]copper(I)
In the title complex, [Cu(NO(3))(C(18)H(12)F(3)P)(3)], the ligating atoms define a distorted tetrahedon with the three tris(4-fluorophenyl)phosphane ligands in the basal positions and the nitrate ligand in the axial position. The intramolecular π–π interaction [centroid–centroid distance = 3.61...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515141/ https://www.ncbi.nlm.nih.gov/pubmed/23284368 http://dx.doi.org/10.1107/S1600536812043346 |
Sumario: | In the title complex, [Cu(NO(3))(C(18)H(12)F(3)P)(3)], the ligating atoms define a distorted tetrahedon with the three tris(4-fluorophenyl)phosphane ligands in the basal positions and the nitrate ligand in the axial position. The intramolecular π–π interaction [centroid–centroid distance = 3.6113 (11) Å] between two of the 4-fluorophenyl groups is complemented by both C—H⋯F and C—H⋯O interactions with distances in the range 2.51–2.60 Å, resulting in a tight head-to-tail packing. |
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