(Nitrato-κO)tris­[tris­(4-fluoro­phen­yl)phosphane-κP]copper(I)

In the title complex, [Cu(NO(3))(C(18)H(12)F(3)P)(3)], the ligating atoms define a distorted tetrahedon with the three tris­(4-fluoro­phen­yl)phosphane ligands in the basal positions and the nitrate ligand in the axial position. The intra­molecular π–π inter­action [centroid–centroid distance = 3.61...

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Detalles Bibliográficos
Autores principales: Hill, Tania N., Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515141/
https://www.ncbi.nlm.nih.gov/pubmed/23284368
http://dx.doi.org/10.1107/S1600536812043346
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author Hill, Tania N.
Roodt, Andreas
author_facet Hill, Tania N.
Roodt, Andreas
author_sort Hill, Tania N.
collection PubMed
description In the title complex, [Cu(NO(3))(C(18)H(12)F(3)P)(3)], the ligating atoms define a distorted tetrahedon with the three tris­(4-fluoro­phen­yl)phosphane ligands in the basal positions and the nitrate ligand in the axial position. The intra­molecular π–π inter­action [centroid–centroid distance = 3.6113 (11) Å] between two of the 4-fluoro­phenyl groups is complemented by both C—H⋯F and C—H⋯O inter­actions with distances in the range 2.51–2.60 Å, resulting in a tight head-to-tail packing.
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spelling pubmed-35151412013-01-02 (Nitrato-κO)tris­[tris­(4-fluoro­phen­yl)phosphane-κP]copper(I) Hill, Tania N. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(NO(3))(C(18)H(12)F(3)P)(3)], the ligating atoms define a distorted tetrahedon with the three tris­(4-fluoro­phen­yl)phosphane ligands in the basal positions and the nitrate ligand in the axial position. The intra­molecular π–π inter­action [centroid–centroid distance = 3.6113 (11) Å] between two of the 4-fluoro­phenyl groups is complemented by both C—H⋯F and C—H⋯O inter­actions with distances in the range 2.51–2.60 Å, resulting in a tight head-to-tail packing. International Union of Crystallography 2012-10-24 /pmc/articles/PMC3515141/ /pubmed/23284368 http://dx.doi.org/10.1107/S1600536812043346 Text en © Hill and Roodt 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hill, Tania N.
Roodt, Andreas
(Nitrato-κO)tris­[tris­(4-fluoro­phen­yl)phosphane-κP]copper(I)
title (Nitrato-κO)tris­[tris­(4-fluoro­phen­yl)phosphane-κP]copper(I)
title_full (Nitrato-κO)tris­[tris­(4-fluoro­phen­yl)phosphane-κP]copper(I)
title_fullStr (Nitrato-κO)tris­[tris­(4-fluoro­phen­yl)phosphane-κP]copper(I)
title_full_unstemmed (Nitrato-κO)tris­[tris­(4-fluoro­phen­yl)phosphane-κP]copper(I)
title_short (Nitrato-κO)tris­[tris­(4-fluoro­phen­yl)phosphane-κP]copper(I)
title_sort (nitrato-κo)tris­[tris­(4-fluoro­phen­yl)phosphane-κp]copper(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515141/
https://www.ncbi.nlm.nih.gov/pubmed/23284368
http://dx.doi.org/10.1107/S1600536812043346
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