trans-Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN]bis(N,N-dimethyl­formamide-κO)cobalt(II)

The title complex, [Co(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)], lies across an inversion center. The Co(II) atom is coordinated in a slightly distorted octa­hedral geometry by four N atoms from two bidentate 4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidate (sulfadiazine) anions and two O atoms from tw...

Descripción completa

Detalles Bibliográficos
Autores principales: Guo, Jing Jing, Wang, Wei, Zhang, Yi Dong, Yang, Li, Zhang, Shu Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515142/
https://www.ncbi.nlm.nih.gov/pubmed/23284369
http://dx.doi.org/10.1107/S160053681204336X
_version_ 1782252120078024704
author Guo, Jing Jing
Wang, Wei
Zhang, Yi Dong
Yang, Li
Zhang, Shu Hua
author_facet Guo, Jing Jing
Wang, Wei
Zhang, Yi Dong
Yang, Li
Zhang, Shu Hua
author_sort Guo, Jing Jing
collection PubMed
description The title complex, [Co(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)], lies across an inversion center. The Co(II) atom is coordinated in a slightly distorted octa­hedral geometry by four N atoms from two bidentate 4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidate (sulfadiazine) anions and two O atoms from two dimethyl­formamide (DMF) ligands. The dihedral angle between the benzene and pyrimidine rings is 82.37 (13)°. A three-dimensional network is generated by N—H⋯O hydrogen bonds between the amino groups and of the sulfonamidate O atoms of neighbouring mol­ecules. The DMF ligand is disordered over two sets of sites in a 0.559 (4):0.441 (4) ratio.
format Online
Article
Text
id pubmed-3515142
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35151422013-01-02 trans-Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN]bis(N,N-dimethyl­formamide-κO)cobalt(II) Guo, Jing Jing Wang, Wei Zhang, Yi Dong Yang, Li Zhang, Shu Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Co(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)], lies across an inversion center. The Co(II) atom is coordinated in a slightly distorted octa­hedral geometry by four N atoms from two bidentate 4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidate (sulfadiazine) anions and two O atoms from two dimethyl­formamide (DMF) ligands. The dihedral angle between the benzene and pyrimidine rings is 82.37 (13)°. A three-dimensional network is generated by N—H⋯O hydrogen bonds between the amino groups and of the sulfonamidate O atoms of neighbouring mol­ecules. The DMF ligand is disordered over two sets of sites in a 0.559 (4):0.441 (4) ratio. International Union of Crystallography 2012-10-24 /pmc/articles/PMC3515142/ /pubmed/23284369 http://dx.doi.org/10.1107/S160053681204336X Text en © Guo et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Jing Jing
Wang, Wei
Zhang, Yi Dong
Yang, Li
Zhang, Shu Hua
trans-Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN]bis(N,N-dimethyl­formamide-κO)cobalt(II)
title trans-Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN]bis(N,N-dimethyl­formamide-κO)cobalt(II)
title_full trans-Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN]bis(N,N-dimethyl­formamide-κO)cobalt(II)
title_fullStr trans-Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN]bis(N,N-dimethyl­formamide-κO)cobalt(II)
title_full_unstemmed trans-Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN]bis(N,N-dimethyl­formamide-κO)cobalt(II)
title_short trans-Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene­sulfonamidato-κN]bis(N,N-dimethyl­formamide-κO)cobalt(II)
title_sort trans-bis[4-amino-n-(pyrimidin-2-yl-κn)benzene­sulfonamidato-κn]bis(n,n-dimethyl­formamide-κo)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515142/
https://www.ncbi.nlm.nih.gov/pubmed/23284369
http://dx.doi.org/10.1107/S160053681204336X
work_keys_str_mv AT guojingjing transbis4aminonpyrimidin2ylknbenzenesulfonamidatoknbisnndimethylformamidekocobaltii
AT wangwei transbis4aminonpyrimidin2ylknbenzenesulfonamidatoknbisnndimethylformamidekocobaltii
AT zhangyidong transbis4aminonpyrimidin2ylknbenzenesulfonamidatoknbisnndimethylformamidekocobaltii
AT yangli transbis4aminonpyrimidin2ylknbenzenesulfonamidatoknbisnndimethylformamidekocobaltii
AT zhangshuhua transbis4aminonpyrimidin2ylknbenzenesulfonamidatoknbisnndimethylformamidekocobaltii

Ejemplares similares