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Bis(diisopropylammonium) hexachloridostannate(IV)
The title compound, (C(6)H(16)N)(2)[SnCl(6)], crystallizes with one diisopropylammonium cation lying on a general position and the hexachloridostannate(IV) anion about a centre of inversion. The [SnCl(6)](2−) anion undergoes a slight distortion from octahedral symmetry as the result of the format...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515144/ https://www.ncbi.nlm.nih.gov/pubmed/23284371 http://dx.doi.org/10.1107/S1600536812043371 |
| Sumario: | The title compound, (C(6)H(16)N)(2)[SnCl(6)], crystallizes with one diisopropylammonium cation lying on a general position and the hexachloridostannate(IV) anion about a centre of inversion. The [SnCl(6)](2−) anion undergoes a slight distortion from octahedral symmetry as the result of the formation of four unforked charge-supported N—H⋯Cl hydrogen bonds. The hydrogen bonds between the cations and anions form layers perpendicular to [101]. These layers are built by 24-membered rings which can be classified with an R (8) (8)(24) graph-set descriptor. According to this hydrogen-bonding motif, the title compound is isostructural with (C(6)H(16)N)(2)[IrCl(6)]. |
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