Bis(diisopropyl­ammonium) hexa­chlorido­stannate(IV)

The title compound, (C(6)H(16)N)(2)[SnCl(6)], crystallizes with one diisopropyl­ammonium cation lying on a general position and the hexa­chloridostannate(IV) anion about a centre of inversion. The [SnCl(6)](2−) anion undergoes a slight distortion from octa­hedral symmetry as the result of the format...

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Detalles Bibliográficos
Autores principales: Reiss, Guido J., Helmbrecht, Cora
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515144/
https://www.ncbi.nlm.nih.gov/pubmed/23284371
http://dx.doi.org/10.1107/S1600536812043371
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author Reiss, Guido J.
Helmbrecht, Cora
author_facet Reiss, Guido J.
Helmbrecht, Cora
author_sort Reiss, Guido J.
collection PubMed
description The title compound, (C(6)H(16)N)(2)[SnCl(6)], crystallizes with one diisopropyl­ammonium cation lying on a general position and the hexa­chloridostannate(IV) anion about a centre of inversion. The [SnCl(6)](2−) anion undergoes a slight distortion from octa­hedral symmetry as the result of the formation of four unforked charge-supported N—H⋯Cl hydrogen bonds. The hydrogen bonds between the cations and anions form layers perpendicular to [101]. These layers are built by 24-membered rings which can be classified with an R (8) (8)(24) graph-set descriptor. According to this hydrogen-bonding motif, the title compound is isostructural with (C(6)H(16)N)(2)[IrCl(6)].
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spelling pubmed-35151442013-01-02 Bis(diisopropyl­ammonium) hexa­chlorido­stannate(IV) Reiss, Guido J. Helmbrecht, Cora Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(6)H(16)N)(2)[SnCl(6)], crystallizes with one diisopropyl­ammonium cation lying on a general position and the hexa­chloridostannate(IV) anion about a centre of inversion. The [SnCl(6)](2−) anion undergoes a slight distortion from octa­hedral symmetry as the result of the formation of four unforked charge-supported N—H⋯Cl hydrogen bonds. The hydrogen bonds between the cations and anions form layers perpendicular to [101]. These layers are built by 24-membered rings which can be classified with an R (8) (8)(24) graph-set descriptor. According to this hydrogen-bonding motif, the title compound is isostructural with (C(6)H(16)N)(2)[IrCl(6)]. International Union of Crystallography 2012-10-24 /pmc/articles/PMC3515144/ /pubmed/23284371 http://dx.doi.org/10.1107/S1600536812043371 Text en © Reiss and Helmbrecht 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Reiss, Guido J.
Helmbrecht, Cora
Bis(diisopropyl­ammonium) hexa­chlorido­stannate(IV)
title Bis(diisopropyl­ammonium) hexa­chlorido­stannate(IV)
title_full Bis(diisopropyl­ammonium) hexa­chlorido­stannate(IV)
title_fullStr Bis(diisopropyl­ammonium) hexa­chlorido­stannate(IV)
title_full_unstemmed Bis(diisopropyl­ammonium) hexa­chlorido­stannate(IV)
title_short Bis(diisopropyl­ammonium) hexa­chlorido­stannate(IV)
title_sort bis(diisopropyl­ammonium) hexa­chlorido­stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515144/
https://www.ncbi.nlm.nih.gov/pubmed/23284371
http://dx.doi.org/10.1107/S1600536812043371
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