A triclinic polymorph of catena-poly[[bis­(N,N-dimethyl­formamide-κO)cobalt(II)]-di-μ-1,5-dicyanamido-κ(4) N (1):N (5)]

The title compound, [Co(C(2)N(3))(2)(C(3)H(7)NO)(2)](n), is a triclinic polymorph of the previously reported monoclinic structure [Tong et al. (2003 ▶). Acta Cryst. E59, m405–m407]. The Co(II) ion lies on an inversion centre and adopts an almost regular octa­hedral N(4)O(2) coordination geometry. Ad...

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Detalles Bibliográficos
Autor principal: Meng, S. C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515145/
https://www.ncbi.nlm.nih.gov/pubmed/23284372
http://dx.doi.org/10.1107/S1600536812043310
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author Meng, S. C.
author_facet Meng, S. C.
author_sort Meng, S. C.
collection PubMed
description The title compound, [Co(C(2)N(3))(2)(C(3)H(7)NO)(2)](n), is a triclinic polymorph of the previously reported monoclinic structure [Tong et al. (2003 ▶). Acta Cryst. E59, m405–m407]. The Co(II) ion lies on an inversion centre and adopts an almost regular octa­hedral N(4)O(2) coordination geometry. Adjacent Co(II) atoms are connected by two bridging dicyanamide ligands, resulting in the formation of neutral chains parallel to the b axis. The title complex is isotypic with the Mn(II) analogue but not with the Ni(II) analogue.
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spelling pubmed-35151452013-01-02 A triclinic polymorph of catena-poly[[bis­(N,N-dimethyl­formamide-κO)cobalt(II)]-di-μ-1,5-dicyanamido-κ(4) N (1):N (5)] Meng, S. C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(2)N(3))(2)(C(3)H(7)NO)(2)](n), is a triclinic polymorph of the previously reported monoclinic structure [Tong et al. (2003 ▶). Acta Cryst. E59, m405–m407]. The Co(II) ion lies on an inversion centre and adopts an almost regular octa­hedral N(4)O(2) coordination geometry. Adjacent Co(II) atoms are connected by two bridging dicyanamide ligands, resulting in the formation of neutral chains parallel to the b axis. The title complex is isotypic with the Mn(II) analogue but not with the Ni(II) analogue. International Union of Crystallography 2012-10-24 /pmc/articles/PMC3515145/ /pubmed/23284372 http://dx.doi.org/10.1107/S1600536812043310 Text en © S. C. Meng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meng, S. C.
A triclinic polymorph of catena-poly[[bis­(N,N-dimethyl­formamide-κO)cobalt(II)]-di-μ-1,5-dicyanamido-κ(4) N (1):N (5)]
title A triclinic polymorph of catena-poly[[bis­(N,N-dimethyl­formamide-κO)cobalt(II)]-di-μ-1,5-dicyanamido-κ(4) N (1):N (5)]
title_full A triclinic polymorph of catena-poly[[bis­(N,N-dimethyl­formamide-κO)cobalt(II)]-di-μ-1,5-dicyanamido-κ(4) N (1):N (5)]
title_fullStr A triclinic polymorph of catena-poly[[bis­(N,N-dimethyl­formamide-κO)cobalt(II)]-di-μ-1,5-dicyanamido-κ(4) N (1):N (5)]
title_full_unstemmed A triclinic polymorph of catena-poly[[bis­(N,N-dimethyl­formamide-κO)cobalt(II)]-di-μ-1,5-dicyanamido-κ(4) N (1):N (5)]
title_short A triclinic polymorph of catena-poly[[bis­(N,N-dimethyl­formamide-κO)cobalt(II)]-di-μ-1,5-dicyanamido-κ(4) N (1):N (5)]
title_sort triclinic polymorph of catena-poly[[bis­(n,n-dimethyl­formamide-κo)cobalt(ii)]-di-μ-1,5-dicyanamido-κ(4) n (1):n (5)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515145/
https://www.ncbi.nlm.nih.gov/pubmed/23284372
http://dx.doi.org/10.1107/S1600536812043310
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AT mengsc triclinicpolymorphofcatenapolybisnndimethylformamidekocobaltiidim15dicyanamidok4n1n5

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