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Hexakis(μ(3)-1-methylthiourea-κ(3) S:S:S)hexakis[iodidocopper(I)]
The title compound, [Cu(6)I(6)(C(2)H(6)N(2)S)(6)], was obtained from the reaction of copper(I) iodide with N-methylthiourea (Metu) in equimolar amounts in acetonitile. The complex consists of two six-membered trinuclear Cu(3)S(3)I(3) cores that combine through triply bridging Metu, forming a hexa...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515146/ https://www.ncbi.nlm.nih.gov/pubmed/23284373 http://dx.doi.org/10.1107/S1600536812043437 |
| _version_ | 1782252120996577280 |
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| author | Ahmad, Saeed Mufakkar, Muhammad Khan, Islam Ullah Fun, Hoong-Kun Waheed, Abdul |
| author_facet | Ahmad, Saeed Mufakkar, Muhammad Khan, Islam Ullah Fun, Hoong-Kun Waheed, Abdul |
| author_sort | Ahmad, Saeed |
| collection | PubMed |
| description | The title compound, [Cu(6)I(6)(C(2)H(6)N(2)S)(6)], was obtained from the reaction of copper(I) iodide with N-methylthiourea (Metu) in equimolar amounts in acetonitile. The complex consists of two six-membered trinuclear Cu(3)S(3)I(3) cores that combine through triply bridging Metu, forming a hexanuclear core which has -3 symmetry. The Cu(II) atom is coordinated by three S atoms of Metu and one iodide ion in a distorted tetrahedral geometry. The crystal structure is stabilized by N—H⋯I hydrogen bonds and cuprophilic interactions [Cu⋯Cu = 3.0264 (9) Å]. |
| format | Online Article Text |
| id | pubmed-3515146 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35151462013-01-02 Hexakis(μ(3)-1-methylthiourea-κ(3) S:S:S)hexakis[iodidocopper(I)] Ahmad, Saeed Mufakkar, Muhammad Khan, Islam Ullah Fun, Hoong-Kun Waheed, Abdul Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(6)I(6)(C(2)H(6)N(2)S)(6)], was obtained from the reaction of copper(I) iodide with N-methylthiourea (Metu) in equimolar amounts in acetonitile. The complex consists of two six-membered trinuclear Cu(3)S(3)I(3) cores that combine through triply bridging Metu, forming a hexanuclear core which has -3 symmetry. The Cu(II) atom is coordinated by three S atoms of Metu and one iodide ion in a distorted tetrahedral geometry. The crystal structure is stabilized by N—H⋯I hydrogen bonds and cuprophilic interactions [Cu⋯Cu = 3.0264 (9) Å]. International Union of Crystallography 2012-10-24 /pmc/articles/PMC3515146/ /pubmed/23284373 http://dx.doi.org/10.1107/S1600536812043437 Text en © Ahmad et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ahmad, Saeed Mufakkar, Muhammad Khan, Islam Ullah Fun, Hoong-Kun Waheed, Abdul Hexakis(μ(3)-1-methylthiourea-κ(3) S:S:S)hexakis[iodidocopper(I)] |
| title | Hexakis(μ(3)-1-methylthiourea-κ(3)
S:S:S)hexakis[iodidocopper(I)] |
| title_full | Hexakis(μ(3)-1-methylthiourea-κ(3)
S:S:S)hexakis[iodidocopper(I)] |
| title_fullStr | Hexakis(μ(3)-1-methylthiourea-κ(3)
S:S:S)hexakis[iodidocopper(I)] |
| title_full_unstemmed | Hexakis(μ(3)-1-methylthiourea-κ(3)
S:S:S)hexakis[iodidocopper(I)] |
| title_short | Hexakis(μ(3)-1-methylthiourea-κ(3)
S:S:S)hexakis[iodidocopper(I)] |
| title_sort | hexakis(μ(3)-1-methylthiourea-κ(3)
s:s:s)hexakis[iodidocopper(i)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515146/ https://www.ncbi.nlm.nih.gov/pubmed/23284373 http://dx.doi.org/10.1107/S1600536812043437 |
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