Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) acetonitrile monosolvate

In the title compound, [CoBr(2)(C(14)H(12)N(2))]·CH(3)CN, the Co(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a chelating 2,9-dimethyl-1,10-phenanthroline ligand and two terminal Br atoms. In the crystal, π–π contacts between the pyridine and benzene rings [c...

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Autores principales: Shirvan, Sadif A., Aghajeri, Manouchehr, Haydari Dezfuli, Sara, Khazali, Fereydoon, Borsalani, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515147/
https://www.ncbi.nlm.nih.gov/pubmed/23284374
http://dx.doi.org/10.1107/S160053681204367X
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author Shirvan, Sadif A.
Aghajeri, Manouchehr
Haydari Dezfuli, Sara
Khazali, Fereydoon
Borsalani, Ali
author_facet Shirvan, Sadif A.
Aghajeri, Manouchehr
Haydari Dezfuli, Sara
Khazali, Fereydoon
Borsalani, Ali
author_sort Shirvan, Sadif A.
collection PubMed
description In the title compound, [CoBr(2)(C(14)H(12)N(2))]·CH(3)CN, the Co(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a chelating 2,9-dimethyl-1,10-phenanthroline ligand and two terminal Br atoms. In the crystal, π–π contacts between the pyridine and benzene rings [centroid–centroid distances = 3.828 (5), 3.782 (5), 3.880 (5) and 3.646 (5) Å] stabilize the structure.
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spelling pubmed-35151472013-01-02 Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) acetonitrile monosolvate Shirvan, Sadif A. Aghajeri, Manouchehr Haydari Dezfuli, Sara Khazali, Fereydoon Borsalani, Ali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoBr(2)(C(14)H(12)N(2))]·CH(3)CN, the Co(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a chelating 2,9-dimethyl-1,10-phenanthroline ligand and two terminal Br atoms. In the crystal, π–π contacts between the pyridine and benzene rings [centroid–centroid distances = 3.828 (5), 3.782 (5), 3.880 (5) and 3.646 (5) Å] stabilize the structure. International Union of Crystallography 2012-10-27 /pmc/articles/PMC3515147/ /pubmed/23284374 http://dx.doi.org/10.1107/S160053681204367X Text en © Shirvan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shirvan, Sadif A.
Aghajeri, Manouchehr
Haydari Dezfuli, Sara
Khazali, Fereydoon
Borsalani, Ali
Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) acetonitrile monosolvate
title Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) acetonitrile monosolvate
title_full Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) acetonitrile monosolvate
title_fullStr Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) acetonitrile monosolvate
title_full_unstemmed Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) acetonitrile monosolvate
title_short Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)cobalt(II) acetonitrile monosolvate
title_sort dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) n,n′)cobalt(ii) acetonitrile monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515147/
https://www.ncbi.nlm.nih.gov/pubmed/23284374
http://dx.doi.org/10.1107/S160053681204367X
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