catena-Poly[zinc-μ(3)-{3,3′-[(1,7-dioxa-4,10-diaza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}]

The Zn(II) ion in the title compound, [Zn(C(24)H(28)N(2)O(6))](n), is located on a twofold rotation axis and is at the midpoint of a crown-4 moiety of 3,3′-[(1,7-dioxa-4,10-diaza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoate anion. It is octahedrally coordinated by two N atoms and two O atom...

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Detalles Bibliográficos
Autores principales: Ingram, C. W., Liao, L., Bacsa, J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515149/
https://www.ncbi.nlm.nih.gov/pubmed/23284376
http://dx.doi.org/10.1107/S1600536812043450
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author Ingram, C. W.
Liao, L.
Bacsa, J.
author_facet Ingram, C. W.
Liao, L.
Bacsa, J.
author_sort Ingram, C. W.
collection PubMed
description The Zn(II) ion in the title compound, [Zn(C(24)H(28)N(2)O(6))](n), is located on a twofold rotation axis and is at the midpoint of a crown-4 moiety of 3,3′-[(1,7-dioxa-4,10-diaza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoate anion. It is octahedrally coordinated by two N atoms and two O atoms of the crown moiety from one ligand and two carboxyl­ate O atoms from two bridging intra-chain ligands. Metallomacrocyclic rings are identified in the structure. The metallomacrocycle contains two Zn(II) ions and 14 atoms from the bridging ligands. Repetition of these units gives rise to an infinite zigzag chain along [101]. C—H⋯O hydrogen bonds occur.
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spelling pubmed-35151492013-01-02 catena-Poly[zinc-μ(3)-{3,3′-[(1,7-dioxa-4,10-diaza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}] Ingram, C. W. Liao, L. Bacsa, J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) ion in the title compound, [Zn(C(24)H(28)N(2)O(6))](n), is located on a twofold rotation axis and is at the midpoint of a crown-4 moiety of 3,3′-[(1,7-dioxa-4,10-diaza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoate anion. It is octahedrally coordinated by two N atoms and two O atoms of the crown moiety from one ligand and two carboxyl­ate O atoms from two bridging intra-chain ligands. Metallomacrocyclic rings are identified in the structure. The metallomacrocycle contains two Zn(II) ions and 14 atoms from the bridging ligands. Repetition of these units gives rise to an infinite zigzag chain along [101]. C—H⋯O hydrogen bonds occur. International Union of Crystallography 2012-10-27 /pmc/articles/PMC3515149/ /pubmed/23284376 http://dx.doi.org/10.1107/S1600536812043450 Text en © Ingram et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ingram, C. W.
Liao, L.
Bacsa, J.
catena-Poly[zinc-μ(3)-{3,3′-[(1,7-dioxa-4,10-diaza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}]
title catena-Poly[zinc-μ(3)-{3,3′-[(1,7-dioxa-4,10-diaza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}]
title_full catena-Poly[zinc-μ(3)-{3,3′-[(1,7-dioxa-4,10-diaza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}]
title_fullStr catena-Poly[zinc-μ(3)-{3,3′-[(1,7-dioxa-4,10-diaza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}]
title_full_unstemmed catena-Poly[zinc-μ(3)-{3,3′-[(1,7-dioxa-4,10-diaza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}]
title_short catena-Poly[zinc-μ(3)-{3,3′-[(1,7-dioxa-4,10-diaza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}]
title_sort catena-poly[zinc-μ(3)-{3,3′-[(1,7-dioxa-4,10-diaza­cyclo­dodecane-4,10-di­yl)bis­(methyl­ene)]dibenzoato}]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515149/
https://www.ncbi.nlm.nih.gov/pubmed/23284376
http://dx.doi.org/10.1107/S1600536812043450
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AT liaol catenapolyzincm33317dioxa410diazacyclododecane410diylbismethylenedibenzoato
AT bacsaj catenapolyzincm33317dioxa410diazacyclododecane410diylbismethylenedibenzoato

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