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Poly[[diaquabis{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2) O:N (4′)}zinc] dimethylformamide tetrasolvate]
In the title compound, {[Zn(C(24)H(15)N(2)O(4))(2)(H(2)O)(2)]·4C(3)H(7)NO}(n), the Zn(II) ion is located on an inversion center and is six-coordinated by two N atoms from two ligands, two carboxylate O atoms from two other symmetry-related ligands and two O atoms from two water molecules, furnishin...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515151/ https://www.ncbi.nlm.nih.gov/pubmed/23284378 http://dx.doi.org/10.1107/S1600536812043838 |
Sumario: | In the title compound, {[Zn(C(24)H(15)N(2)O(4))(2)(H(2)O)(2)]·4C(3)H(7)NO}(n), the Zn(II) ion is located on an inversion center and is six-coordinated by two N atoms from two ligands, two carboxylate O atoms from two other symmetry-related ligands and two O atoms from two water molecules, furnishing a slightly distorted octahedral geometry. The Zn(II) atoms are connected by the bridging ligands into a layer parallel to (101). O—H⋯O hydrogen bonds link the layers and the dimethylformamide solvent molecules. π–π interactions between the pyridine and benzene rings [centroid–centroid distances = 3.7428 (17) and 3.7619 (17) Å] and intralayer O—H⋯O hydrogen bonds are also present. |
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