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Poly[[diaquabis{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2) O:N (4′)}zinc] dimethylformamide tetrasolvate]
In the title compound, {[Zn(C(24)H(15)N(2)O(4))(2)(H(2)O)(2)]·4C(3)H(7)NO}(n), the Zn(II) ion is located on an inversion center and is six-coordinated by two N atoms from two ligands, two carboxylate O atoms from two other symmetry-related ligands and two O atoms from two water molecules, furnishin...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515151/ https://www.ncbi.nlm.nih.gov/pubmed/23284378 http://dx.doi.org/10.1107/S1600536812043838 |
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author | Ge, Xin Song, Shuyan |
author_facet | Ge, Xin Song, Shuyan |
author_sort | Ge, Xin |
collection | PubMed |
description | In the title compound, {[Zn(C(24)H(15)N(2)O(4))(2)(H(2)O)(2)]·4C(3)H(7)NO}(n), the Zn(II) ion is located on an inversion center and is six-coordinated by two N atoms from two ligands, two carboxylate O atoms from two other symmetry-related ligands and two O atoms from two water molecules, furnishing a slightly distorted octahedral geometry. The Zn(II) atoms are connected by the bridging ligands into a layer parallel to (101). O—H⋯O hydrogen bonds link the layers and the dimethylformamide solvent molecules. π–π interactions between the pyridine and benzene rings [centroid–centroid distances = 3.7428 (17) and 3.7619 (17) Å] and intralayer O—H⋯O hydrogen bonds are also present. |
format | Online Article Text |
id | pubmed-3515151 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151512013-01-02 Poly[[diaquabis{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2) O:N (4′)}zinc] dimethylformamide tetrasolvate] Ge, Xin Song, Shuyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(24)H(15)N(2)O(4))(2)(H(2)O)(2)]·4C(3)H(7)NO}(n), the Zn(II) ion is located on an inversion center and is six-coordinated by two N atoms from two ligands, two carboxylate O atoms from two other symmetry-related ligands and two O atoms from two water molecules, furnishing a slightly distorted octahedral geometry. The Zn(II) atoms are connected by the bridging ligands into a layer parallel to (101). O—H⋯O hydrogen bonds link the layers and the dimethylformamide solvent molecules. π–π interactions between the pyridine and benzene rings [centroid–centroid distances = 3.7428 (17) and 3.7619 (17) Å] and intralayer O—H⋯O hydrogen bonds are also present. International Union of Crystallography 2012-10-27 /pmc/articles/PMC3515151/ /pubmed/23284378 http://dx.doi.org/10.1107/S1600536812043838 Text en © Ge and Song 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ge, Xin Song, Shuyan Poly[[diaquabis{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2) O:N (4′)}zinc] dimethylformamide tetrasolvate] |
title | Poly[[diaquabis{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2)
O:N
(4′)}zinc] dimethylformamide tetrasolvate] |
title_full | Poly[[diaquabis{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2)
O:N
(4′)}zinc] dimethylformamide tetrasolvate] |
title_fullStr | Poly[[diaquabis{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2)
O:N
(4′)}zinc] dimethylformamide tetrasolvate] |
title_full_unstemmed | Poly[[diaquabis{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2)
O:N
(4′)}zinc] dimethylformamide tetrasolvate] |
title_short | Poly[[diaquabis{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2)
O:N
(4′)}zinc] dimethylformamide tetrasolvate] |
title_sort | poly[[diaquabis{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2)
o:n
(4′)}zinc] dimethylformamide tetrasolvate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515151/ https://www.ncbi.nlm.nih.gov/pubmed/23284378 http://dx.doi.org/10.1107/S1600536812043838 |
work_keys_str_mv | AT gexin polydiaquabism464carboxyphenyl44bipyridin2ylbenzoatok2on4zincdimethylformamidetetrasolvate AT songshuyan polydiaquabism464carboxyphenyl44bipyridin2ylbenzoatok2on4zincdimethylformamidetetrasolvate |