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Poly[[diaqua­bis­{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2) O:N (4′)}zinc] dimethyl­formamide tetra­solvate]

In the title compound, {[Zn(C(24)H(15)N(2)O(4))(2)(H(2)O)(2)]·4C(3)H(7)NO}(n), the Zn(II) ion is located on an inversion center and is six-coordinated by two N atoms from two ligands, two carboxylate O atoms from two other symmetry-related ligands and two O atoms from two water mol­ecules, furnishin...

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Detalles Bibliográficos
Autores principales: Ge, Xin, Song, Shuyan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515151/
https://www.ncbi.nlm.nih.gov/pubmed/23284378
http://dx.doi.org/10.1107/S1600536812043838
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author Ge, Xin
Song, Shuyan
author_facet Ge, Xin
Song, Shuyan
author_sort Ge, Xin
collection PubMed
description In the title compound, {[Zn(C(24)H(15)N(2)O(4))(2)(H(2)O)(2)]·4C(3)H(7)NO}(n), the Zn(II) ion is located on an inversion center and is six-coordinated by two N atoms from two ligands, two carboxylate O atoms from two other symmetry-related ligands and two O atoms from two water mol­ecules, furnishing a slightly distorted octa­hedral geometry. The Zn(II) atoms are connected by the bridging ligands into a layer parallel to (101). O—H⋯O hydrogen bonds link the layers and the dimethyl­formamide solvent mol­ecules. π–π inter­actions between the pyridine and benzene rings [centroid–centroid distances = 3.7428 (17) and 3.7619 (17) Å] and intra­layer O—H⋯O hydrogen bonds are also present.
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spelling pubmed-35151512013-01-02 Poly[[diaqua­bis­{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2) O:N (4′)}zinc] dimethyl­formamide tetra­solvate] Ge, Xin Song, Shuyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(24)H(15)N(2)O(4))(2)(H(2)O)(2)]·4C(3)H(7)NO}(n), the Zn(II) ion is located on an inversion center and is six-coordinated by two N atoms from two ligands, two carboxylate O atoms from two other symmetry-related ligands and two O atoms from two water mol­ecules, furnishing a slightly distorted octa­hedral geometry. The Zn(II) atoms are connected by the bridging ligands into a layer parallel to (101). O—H⋯O hydrogen bonds link the layers and the dimethyl­formamide solvent mol­ecules. π–π inter­actions between the pyridine and benzene rings [centroid–centroid distances = 3.7428 (17) and 3.7619 (17) Å] and intra­layer O—H⋯O hydrogen bonds are also present. International Union of Crystallography 2012-10-27 /pmc/articles/PMC3515151/ /pubmed/23284378 http://dx.doi.org/10.1107/S1600536812043838 Text en © Ge and Song 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ge, Xin
Song, Shuyan
Poly[[diaqua­bis­{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2) O:N (4′)}zinc] dimethyl­formamide tetra­solvate]
title Poly[[diaqua­bis­{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2) O:N (4′)}zinc] dimethyl­formamide tetra­solvate]
title_full Poly[[diaqua­bis­{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2) O:N (4′)}zinc] dimethyl­formamide tetra­solvate]
title_fullStr Poly[[diaqua­bis­{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2) O:N (4′)}zinc] dimethyl­formamide tetra­solvate]
title_full_unstemmed Poly[[diaqua­bis­{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2) O:N (4′)}zinc] dimethyl­formamide tetra­solvate]
title_short Poly[[diaqua­bis­{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2) O:N (4′)}zinc] dimethyl­formamide tetra­solvate]
title_sort poly[[diaqua­bis­{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ(2) o:n (4′)}zinc] dimethyl­formamide tetra­solvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515151/
https://www.ncbi.nlm.nih.gov/pubmed/23284378
http://dx.doi.org/10.1107/S1600536812043838
work_keys_str_mv AT gexin polydiaquabism464carboxyphenyl44bipyridin2ylbenzoatok2on4zincdimethylformamidetetrasolvate
AT songshuyan polydiaquabism464carboxyphenyl44bipyridin2ylbenzoatok2on4zincdimethylformamidetetrasolvate