Bis(2,2′:6′,2′′-terpyridine)­ruthenium(II) bis­(perchlorate) hemihydrate

The asymmetric unit of the title compound, [Ru(C(15)H(11)N(3))(2)](ClO(4))(2)·0.5H(2)O, contains one ruthenium–terpiridine complex cation, two perchlorate anions and one half-mol­ecule of water. Face-to-face and face-to-edge π-stacking inter­actions between terpyridine units [centroid–centroid dista...

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Detalles Bibliográficos
Autores principales: Kozlowska, Mariana, Rodziewicz, Pawel, Brus, Diana Malgorzata, Breczko, Joanna, Brzezinski, Krzysztof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515152/
https://www.ncbi.nlm.nih.gov/pubmed/23284379
http://dx.doi.org/10.1107/S1600536812043917
Descripción
Sumario:The asymmetric unit of the title compound, [Ru(C(15)H(11)N(3))(2)](ClO(4))(2)·0.5H(2)O, contains one ruthenium–terpiridine complex cation, two perchlorate anions and one half-mol­ecule of water. Face-to-face and face-to-edge π-stacking inter­actions between terpyridine units [centroid–centroid distances = 3.793 (2) and 3.801 (2)  Å] stabilize the crystal lattice The partially occupied water mol­ecule inter­acts with two perchlorate ions via O—H⋯O hydrogen bonds. In the crystal lattice, the complex cations, perchlorate ion-water pairs and the second perchlorate anions are arranged into columns along b direction.

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