Bis(2,2′:6′,2′′-terpyridine)­ruthenium(II) bis­(perchlorate) hemihydrate

The asymmetric unit of the title compound, [Ru(C(15)H(11)N(3))(2)](ClO(4))(2)·0.5H(2)O, contains one ruthenium–terpiridine complex cation, two perchlorate anions and one half-mol­ecule of water. Face-to-face and face-to-edge π-stacking inter­actions between terpyridine units [centroid–centroid dista...

Descripción completa

Detalles Bibliográficos
Autores principales: Kozlowska, Mariana, Rodziewicz, Pawel, Brus, Diana Malgorzata, Breczko, Joanna, Brzezinski, Krzysztof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515152/
https://www.ncbi.nlm.nih.gov/pubmed/23284379
http://dx.doi.org/10.1107/S1600536812043917
_version_ 1782252122462486528
author Kozlowska, Mariana
Rodziewicz, Pawel
Brus, Diana Malgorzata
Breczko, Joanna
Brzezinski, Krzysztof
author_facet Kozlowska, Mariana
Rodziewicz, Pawel
Brus, Diana Malgorzata
Breczko, Joanna
Brzezinski, Krzysztof
author_sort Kozlowska, Mariana
collection PubMed
description The asymmetric unit of the title compound, [Ru(C(15)H(11)N(3))(2)](ClO(4))(2)·0.5H(2)O, contains one ruthenium–terpiridine complex cation, two perchlorate anions and one half-mol­ecule of water. Face-to-face and face-to-edge π-stacking inter­actions between terpyridine units [centroid–centroid distances = 3.793 (2) and 3.801 (2)  Å] stabilize the crystal lattice The partially occupied water mol­ecule inter­acts with two perchlorate ions via O—H⋯O hydrogen bonds. In the crystal lattice, the complex cations, perchlorate ion-water pairs and the second perchlorate anions are arranged into columns along b direction.
format Online
Article
Text
id pubmed-3515152
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35151522013-01-02 Bis(2,2′:6′,2′′-terpyridine)­ruthenium(II) bis­(perchlorate) hemihydrate Kozlowska, Mariana Rodziewicz, Pawel Brus, Diana Malgorzata Breczko, Joanna Brzezinski, Krzysztof Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ru(C(15)H(11)N(3))(2)](ClO(4))(2)·0.5H(2)O, contains one ruthenium–terpiridine complex cation, two perchlorate anions and one half-mol­ecule of water. Face-to-face and face-to-edge π-stacking inter­actions between terpyridine units [centroid–centroid distances = 3.793 (2) and 3.801 (2)  Å] stabilize the crystal lattice The partially occupied water mol­ecule inter­acts with two perchlorate ions via O—H⋯O hydrogen bonds. In the crystal lattice, the complex cations, perchlorate ion-water pairs and the second perchlorate anions are arranged into columns along b direction. International Union of Crystallography 2012-10-27 /pmc/articles/PMC3515152/ /pubmed/23284379 http://dx.doi.org/10.1107/S1600536812043917 Text en © Kozlowska et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kozlowska, Mariana
Rodziewicz, Pawel
Brus, Diana Malgorzata
Breczko, Joanna
Brzezinski, Krzysztof
Bis(2,2′:6′,2′′-terpyridine)­ruthenium(II) bis­(perchlorate) hemihydrate
title Bis(2,2′:6′,2′′-terpyridine)­ruthenium(II) bis­(perchlorate) hemihydrate
title_full Bis(2,2′:6′,2′′-terpyridine)­ruthenium(II) bis­(perchlorate) hemihydrate
title_fullStr Bis(2,2′:6′,2′′-terpyridine)­ruthenium(II) bis­(perchlorate) hemihydrate
title_full_unstemmed Bis(2,2′:6′,2′′-terpyridine)­ruthenium(II) bis­(perchlorate) hemihydrate
title_short Bis(2,2′:6′,2′′-terpyridine)­ruthenium(II) bis­(perchlorate) hemihydrate
title_sort bis(2,2′:6′,2′′-terpyridine)­ruthenium(ii) bis­(perchlorate) hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515152/
https://www.ncbi.nlm.nih.gov/pubmed/23284379
http://dx.doi.org/10.1107/S1600536812043917
work_keys_str_mv AT kozlowskamariana bis2262terpyridinerutheniumiibisperchloratehemihydrate
AT rodziewiczpawel bis2262terpyridinerutheniumiibisperchloratehemihydrate
AT brusdianamalgorzata bis2262terpyridinerutheniumiibisperchloratehemihydrate
AT breczkojoanna bis2262terpyridinerutheniumiibisperchloratehemihydrate
AT brzezinskikrzysztof bis2262terpyridinerutheniumiibisperchloratehemihydrate

Ejemplares similares