catena-Poly[[[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-furan-2,5-di­carboxyl­ato-κ(2) O (2):O (5)] dihydrate]

In the crystal structure of the title compound, {[Cu(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite chain parallel to [110] is formed by the linking of Cu(H(2)O)(2,2′-bipyridine) units through a furan-2,5-dicarboxyl­ate bridge. The Cu(II) atom shows a square-pyramidal geometry, with on...

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Detalles Bibliográficos
Autores principales: Li, Ya-Feng, Xu, Yue, Qin, Xiao-Lin, Yuan, Yong-Peng, Gao, Wen-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515153/
https://www.ncbi.nlm.nih.gov/pubmed/23284380
http://dx.doi.org/10.1107/S1600536812043632
Descripción
Sumario:In the crystal structure of the title compound, {[Cu(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite chain parallel to [110] is formed by the linking of Cu(H(2)O)(2,2′-bipyridine) units through a furan-2,5-dicarboxyl­ate bridge. The Cu(II) atom shows a square-pyramidal geometry, with one furan-2,5-dicarboxyl­ate O atom in the apical position. The dihedral angle between the planes of the furan ring and the bipyridine mol­ecule is 83.88 (7)°. O(water)—H⋯O hydrogen bonds connect adjacent chains, generating a layer motif parallel to (001).

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