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catena-Poly[[[aqua(2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2) O (2):O (5)] dihydrate]
In the crystal structure of the title compound, {[Cu(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite chain parallel to [110] is formed by the linking of Cu(H(2)O)(2,2′-bipyridine) units through a furan-2,5-dicarboxylate bridge. The Cu(II) atom shows a square-pyramidal geometry, with on...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515153/ https://www.ncbi.nlm.nih.gov/pubmed/23284380 http://dx.doi.org/10.1107/S1600536812043632 |
| _version_ | 1782252122701561856 |
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| author | Li, Ya-Feng Xu, Yue Qin, Xiao-Lin Yuan, Yong-Peng Gao, Wen-Yuan |
| author_facet | Li, Ya-Feng Xu, Yue Qin, Xiao-Lin Yuan, Yong-Peng Gao, Wen-Yuan |
| author_sort | Li, Ya-Feng |
| collection | PubMed |
| description | In the crystal structure of the title compound, {[Cu(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite chain parallel to [110] is formed by the linking of Cu(H(2)O)(2,2′-bipyridine) units through a furan-2,5-dicarboxylate bridge. The Cu(II) atom shows a square-pyramidal geometry, with one furan-2,5-dicarboxylate O atom in the apical position. The dihedral angle between the planes of the furan ring and the bipyridine molecule is 83.88 (7)°. O(water)—H⋯O hydrogen bonds connect adjacent chains, generating a layer motif parallel to (001). |
| format | Online Article Text |
| id | pubmed-3515153 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35151532013-01-02 catena-Poly[[[aqua(2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2) O (2):O (5)] dihydrate] Li, Ya-Feng Xu, Yue Qin, Xiao-Lin Yuan, Yong-Peng Gao, Wen-Yuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, {[Cu(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite chain parallel to [110] is formed by the linking of Cu(H(2)O)(2,2′-bipyridine) units through a furan-2,5-dicarboxylate bridge. The Cu(II) atom shows a square-pyramidal geometry, with one furan-2,5-dicarboxylate O atom in the apical position. The dihedral angle between the planes of the furan ring and the bipyridine molecule is 83.88 (7)°. O(water)—H⋯O hydrogen bonds connect adjacent chains, generating a layer motif parallel to (001). International Union of Crystallography 2012-10-27 /pmc/articles/PMC3515153/ /pubmed/23284380 http://dx.doi.org/10.1107/S1600536812043632 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Ya-Feng Xu, Yue Qin, Xiao-Lin Yuan, Yong-Peng Gao, Wen-Yuan catena-Poly[[[aqua(2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2) O (2):O (5)] dihydrate] |
| title |
catena-Poly[[[aqua(2,2′-bipyridine-κ(2)
N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2)
O
(2):O
(5)] dihydrate] |
| title_full |
catena-Poly[[[aqua(2,2′-bipyridine-κ(2)
N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2)
O
(2):O
(5)] dihydrate] |
| title_fullStr |
catena-Poly[[[aqua(2,2′-bipyridine-κ(2)
N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2)
O
(2):O
(5)] dihydrate] |
| title_full_unstemmed |
catena-Poly[[[aqua(2,2′-bipyridine-κ(2)
N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2)
O
(2):O
(5)] dihydrate] |
| title_short |
catena-Poly[[[aqua(2,2′-bipyridine-κ(2)
N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2)
O
(2):O
(5)] dihydrate] |
| title_sort | catena-poly[[[aqua(2,2′-bipyridine-κ(2)
n,n′)copper(ii)]-μ-furan-2,5-dicarboxylato-κ(2)
o
(2):o
(5)] dihydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515153/ https://www.ncbi.nlm.nih.gov/pubmed/23284380 http://dx.doi.org/10.1107/S1600536812043632 |
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