Cargando…
Iodido[1-(propan-2-ylidene)thiosemicarbazide-κS]bis(triphenylphosphane-κP)copper(I)
In the mononuclear title complex, [CuI(C(4)H(9)N(3)S)(C(18)H(15)P)(2)], the Cu(I) ion displays a distorted tetrahedral coordination geometry involving two P atoms of two triphenylphosphane molecules, one S atom of a 1-(propan-2-ylidene)thiosemicarbazide molecule and one iodide ion. In the crys...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515154/ https://www.ncbi.nlm.nih.gov/pubmed/23284381 http://dx.doi.org/10.1107/S1600536812044066 |
Sumario: | In the mononuclear title complex, [CuI(C(4)H(9)N(3)S)(C(18)H(15)P)(2)], the Cu(I) ion displays a distorted tetrahedral coordination geometry involving two P atoms of two triphenylphosphane molecules, one S atom of a 1-(propan-2-ylidene)thiosemicarbazide molecule and one iodide ion. In the crystal, C—H⋯π interactions [C—H⋯centroid distances = 3.443 (3) and 3.788 (3) Å] and N—H⋯S hydrogen bonds form layers parallel to (100). An intramolecular N—H⋯I hydrogen bond is also observed. |
---|