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Iodido[1-(propan-2-yl­idene)thio­semi­carbazide-κS]bis­(triphenyl­phosphane-κP)copper(I)

In the mononuclear title complex, [CuI(C(4)H(9)N(3)S)(C(18)H(15)P)(2)], the Cu(I) ion displays a distorted tetra­hedral coordination geometry involving two P atoms of two triphenyl­phosphane mol­ecules, one S atom of a 1-(propan-2-yl­idene)thio­semicarbazide mol­ecule and one iodide ion. In the crys...

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Detalles Bibliográficos
Autores principales: Wattanakanjana, Yupa, Pakawatchai, Chaveng, Saithong, Saowanit, Piboonphon, Prapaporn, Nimthong, Ruthairat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515154/
https://www.ncbi.nlm.nih.gov/pubmed/23284381
http://dx.doi.org/10.1107/S1600536812044066
Descripción
Sumario:In the mononuclear title complex, [CuI(C(4)H(9)N(3)S)(C(18)H(15)P)(2)], the Cu(I) ion displays a distorted tetra­hedral coordination geometry involving two P atoms of two triphenyl­phosphane mol­ecules, one S atom of a 1-(propan-2-yl­idene)thio­semicarbazide mol­ecule and one iodide ion. In the crystal, C—H⋯π inter­actions [C—H⋯centroid distances = 3.443 (3) and 3.788 (3) Å] and N—H⋯S hydrogen bonds form layers parallel to (100). An intra­molecular N—H⋯I hydrogen bond is also observed.