Iodido[1-(propan-2-yl­idene)thio­semi­carbazide-κS]bis­(triphenyl­phosphane-κP)copper(I)

In the mononuclear title complex, [CuI(C(4)H(9)N(3)S)(C(18)H(15)P)(2)], the Cu(I) ion displays a distorted tetra­hedral coordination geometry involving two P atoms of two triphenyl­phosphane mol­ecules, one S atom of a 1-(propan-2-yl­idene)thio­semicarbazide mol­ecule and one iodide ion. In the crys...

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Autores principales: Wattanakanjana, Yupa, Pakawatchai, Chaveng, Saithong, Saowanit, Piboonphon, Prapaporn, Nimthong, Ruthairat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515154/
https://www.ncbi.nlm.nih.gov/pubmed/23284381
http://dx.doi.org/10.1107/S1600536812044066
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author Wattanakanjana, Yupa
Pakawatchai, Chaveng
Saithong, Saowanit
Piboonphon, Prapaporn
Nimthong, Ruthairat
author_facet Wattanakanjana, Yupa
Pakawatchai, Chaveng
Saithong, Saowanit
Piboonphon, Prapaporn
Nimthong, Ruthairat
author_sort Wattanakanjana, Yupa
collection PubMed
description In the mononuclear title complex, [CuI(C(4)H(9)N(3)S)(C(18)H(15)P)(2)], the Cu(I) ion displays a distorted tetra­hedral coordination geometry involving two P atoms of two triphenyl­phosphane mol­ecules, one S atom of a 1-(propan-2-yl­idene)thio­semicarbazide mol­ecule and one iodide ion. In the crystal, C—H⋯π inter­actions [C—H⋯centroid distances = 3.443 (3) and 3.788 (3) Å] and N—H⋯S hydrogen bonds form layers parallel to (100). An intra­molecular N—H⋯I hydrogen bond is also observed.
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spelling pubmed-35151542013-01-02 Iodido[1-(propan-2-yl­idene)thio­semi­carbazide-κS]bis­(triphenyl­phosphane-κP)copper(I) Wattanakanjana, Yupa Pakawatchai, Chaveng Saithong, Saowanit Piboonphon, Prapaporn Nimthong, Ruthairat Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [CuI(C(4)H(9)N(3)S)(C(18)H(15)P)(2)], the Cu(I) ion displays a distorted tetra­hedral coordination geometry involving two P atoms of two triphenyl­phosphane mol­ecules, one S atom of a 1-(propan-2-yl­idene)thio­semicarbazide mol­ecule and one iodide ion. In the crystal, C—H⋯π inter­actions [C—H⋯centroid distances = 3.443 (3) and 3.788 (3) Å] and N—H⋯S hydrogen bonds form layers parallel to (100). An intra­molecular N—H⋯I hydrogen bond is also observed. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515154/ /pubmed/23284381 http://dx.doi.org/10.1107/S1600536812044066 Text en © Wattanakanjana et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wattanakanjana, Yupa
Pakawatchai, Chaveng
Saithong, Saowanit
Piboonphon, Prapaporn
Nimthong, Ruthairat
Iodido[1-(propan-2-yl­idene)thio­semi­carbazide-κS]bis­(triphenyl­phosphane-κP)copper(I)
title Iodido[1-(propan-2-yl­idene)thio­semi­carbazide-κS]bis­(triphenyl­phosphane-κP)copper(I)
title_full Iodido[1-(propan-2-yl­idene)thio­semi­carbazide-κS]bis­(triphenyl­phosphane-κP)copper(I)
title_fullStr Iodido[1-(propan-2-yl­idene)thio­semi­carbazide-κS]bis­(triphenyl­phosphane-κP)copper(I)
title_full_unstemmed Iodido[1-(propan-2-yl­idene)thio­semi­carbazide-κS]bis­(triphenyl­phosphane-κP)copper(I)
title_short Iodido[1-(propan-2-yl­idene)thio­semi­carbazide-κS]bis­(triphenyl­phosphane-κP)copper(I)
title_sort iodido[1-(propan-2-yl­idene)thio­semi­carbazide-κs]bis­(triphenyl­phosphane-κp)copper(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515154/
https://www.ncbi.nlm.nih.gov/pubmed/23284381
http://dx.doi.org/10.1107/S1600536812044066
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