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trans-Iodido(pyrazinyl-κC (2))bis­(triphenyl­phosphane-κP)palladium(II)

There are two independent mol­ecules with similar configurations in the asymmetric unit of the title complex, [Pd(C(4)H(3)N(2))I(C(18)H(15)P)(2)]. In each mol­ecule, the geometry around the Pd atom is distorted square-planar, with the Pd atom displaced by 0.0549 (12) and 0.0734 (13) Å from the least...

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Autores principales: Tu, Yao-Jen, Wang, Hsiao-Fen, Lee, Gene-Hsiang, Yih, Kuang-Hway, Tang, Xiao-Yan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515155/
https://www.ncbi.nlm.nih.gov/pubmed/23284382
http://dx.doi.org/10.1107/S1600536812043589
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author Tu, Yao-Jen
Wang, Hsiao-Fen
Lee, Gene-Hsiang
Yih, Kuang-Hway
Tang, Xiao-Yan
author_facet Tu, Yao-Jen
Wang, Hsiao-Fen
Lee, Gene-Hsiang
Yih, Kuang-Hway
Tang, Xiao-Yan
author_sort Tu, Yao-Jen
collection PubMed
description There are two independent mol­ecules with similar configurations in the asymmetric unit of the title complex, [Pd(C(4)H(3)N(2))I(C(18)H(15)P)(2)]. In each mol­ecule, the geometry around the Pd atom is distorted square-planar, with the Pd atom displaced by 0.0549 (12) and 0.0734 (13) Å from the least-squares plane of the I—P—P—C atoms. The PPh(3) ligands are in trans positions, with P—Pd—P angles of 173.12 (4) and 170.29 (4)°, while the pyrazinyl ligands and I atoms, also trans to each other, form C—Pd—I angles of 179.38 (12) and 178.44 (12)°. In the crystal, C—H⋯π inter­actions occur, resulting in a three-dimensional supramolecular architecture.
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spelling pubmed-35151552013-01-02 trans-Iodido(pyrazinyl-κC (2))bis­(triphenyl­phosphane-κP)palladium(II) Tu, Yao-Jen Wang, Hsiao-Fen Lee, Gene-Hsiang Yih, Kuang-Hway Tang, Xiao-Yan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers There are two independent mol­ecules with similar configurations in the asymmetric unit of the title complex, [Pd(C(4)H(3)N(2))I(C(18)H(15)P)(2)]. In each mol­ecule, the geometry around the Pd atom is distorted square-planar, with the Pd atom displaced by 0.0549 (12) and 0.0734 (13) Å from the least-squares plane of the I—P—P—C atoms. The PPh(3) ligands are in trans positions, with P—Pd—P angles of 173.12 (4) and 170.29 (4)°, while the pyrazinyl ligands and I atoms, also trans to each other, form C—Pd—I angles of 179.38 (12) and 178.44 (12)°. In the crystal, C—H⋯π inter­actions occur, resulting in a three-dimensional supramolecular architecture. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515155/ /pubmed/23284382 http://dx.doi.org/10.1107/S1600536812043589 Text en © Tu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tu, Yao-Jen
Wang, Hsiao-Fen
Lee, Gene-Hsiang
Yih, Kuang-Hway
Tang, Xiao-Yan
trans-Iodido(pyrazinyl-κC (2))bis­(triphenyl­phosphane-κP)palladium(II)
title trans-Iodido(pyrazinyl-κC (2))bis­(triphenyl­phosphane-κP)palladium(II)
title_full trans-Iodido(pyrazinyl-κC (2))bis­(triphenyl­phosphane-κP)palladium(II)
title_fullStr trans-Iodido(pyrazinyl-κC (2))bis­(triphenyl­phosphane-κP)palladium(II)
title_full_unstemmed trans-Iodido(pyrazinyl-κC (2))bis­(triphenyl­phosphane-κP)palladium(II)
title_short trans-Iodido(pyrazinyl-κC (2))bis­(triphenyl­phosphane-κP)palladium(II)
title_sort trans-iodido(pyrazinyl-κc (2))bis­(triphenyl­phosphane-κp)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515155/
https://www.ncbi.nlm.nih.gov/pubmed/23284382
http://dx.doi.org/10.1107/S1600536812043589
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