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trans-Iodido(pyrazinyl-κC (2))bis(triphenylphosphane-κP)palladium(II)
There are two independent molecules with similar configurations in the asymmetric unit of the title complex, [Pd(C(4)H(3)N(2))I(C(18)H(15)P)(2)]. In each molecule, the geometry around the Pd atom is distorted square-planar, with the Pd atom displaced by 0.0549 (12) and 0.0734 (13) Å from the least...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515155/ https://www.ncbi.nlm.nih.gov/pubmed/23284382 http://dx.doi.org/10.1107/S1600536812043589 |
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author | Tu, Yao-Jen Wang, Hsiao-Fen Lee, Gene-Hsiang Yih, Kuang-Hway Tang, Xiao-Yan |
author_facet | Tu, Yao-Jen Wang, Hsiao-Fen Lee, Gene-Hsiang Yih, Kuang-Hway Tang, Xiao-Yan |
author_sort | Tu, Yao-Jen |
collection | PubMed |
description | There are two independent molecules with similar configurations in the asymmetric unit of the title complex, [Pd(C(4)H(3)N(2))I(C(18)H(15)P)(2)]. In each molecule, the geometry around the Pd atom is distorted square-planar, with the Pd atom displaced by 0.0549 (12) and 0.0734 (13) Å from the least-squares plane of the I—P—P—C atoms. The PPh(3) ligands are in trans positions, with P—Pd—P angles of 173.12 (4) and 170.29 (4)°, while the pyrazinyl ligands and I atoms, also trans to each other, form C—Pd—I angles of 179.38 (12) and 178.44 (12)°. In the crystal, C—H⋯π interactions occur, resulting in a three-dimensional supramolecular architecture. |
format | Online Article Text |
id | pubmed-3515155 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151552013-01-02 trans-Iodido(pyrazinyl-κC (2))bis(triphenylphosphane-κP)palladium(II) Tu, Yao-Jen Wang, Hsiao-Fen Lee, Gene-Hsiang Yih, Kuang-Hway Tang, Xiao-Yan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers There are two independent molecules with similar configurations in the asymmetric unit of the title complex, [Pd(C(4)H(3)N(2))I(C(18)H(15)P)(2)]. In each molecule, the geometry around the Pd atom is distorted square-planar, with the Pd atom displaced by 0.0549 (12) and 0.0734 (13) Å from the least-squares plane of the I—P—P—C atoms. The PPh(3) ligands are in trans positions, with P—Pd—P angles of 173.12 (4) and 170.29 (4)°, while the pyrazinyl ligands and I atoms, also trans to each other, form C—Pd—I angles of 179.38 (12) and 178.44 (12)°. In the crystal, C—H⋯π interactions occur, resulting in a three-dimensional supramolecular architecture. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515155/ /pubmed/23284382 http://dx.doi.org/10.1107/S1600536812043589 Text en © Tu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tu, Yao-Jen Wang, Hsiao-Fen Lee, Gene-Hsiang Yih, Kuang-Hway Tang, Xiao-Yan trans-Iodido(pyrazinyl-κC (2))bis(triphenylphosphane-κP)palladium(II) |
title |
trans-Iodido(pyrazinyl-κC
(2))bis(triphenylphosphane-κP)palladium(II) |
title_full |
trans-Iodido(pyrazinyl-κC
(2))bis(triphenylphosphane-κP)palladium(II) |
title_fullStr |
trans-Iodido(pyrazinyl-κC
(2))bis(triphenylphosphane-κP)palladium(II) |
title_full_unstemmed |
trans-Iodido(pyrazinyl-κC
(2))bis(triphenylphosphane-κP)palladium(II) |
title_short |
trans-Iodido(pyrazinyl-κC
(2))bis(triphenylphosphane-κP)palladium(II) |
title_sort | trans-iodido(pyrazinyl-κc
(2))bis(triphenylphosphane-κp)palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515155/ https://www.ncbi.nlm.nih.gov/pubmed/23284382 http://dx.doi.org/10.1107/S1600536812043589 |
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