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Poly[[hexa­aqua­(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetra­carboxyl­ato-κ(6) O (4):N,O (6),O (6′),N′:O (4′))dinickel(II)] dihydrate]

In the title complex, {[Ni(2)(C(14)H(4)N(2)O(8))(H(2)O)(6)]·2H(2)O}(n), the two Ni(II) atoms are located in different special positions (one on a twofold rotation axis and the second on a centre of symmetry) and have different distorted octa­hedral environments (one by two N atoms from a bipyridine...

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Detalles Bibliográficos
Autores principales: Li, Jie, Lei, Ke-Wei, Xia, Dong-Guo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515156/
https://www.ncbi.nlm.nih.gov/pubmed/23284383
http://dx.doi.org/10.1107/S1600536812043942
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author Li, Jie
Lei, Ke-Wei
Xia, Dong-Guo
author_facet Li, Jie
Lei, Ke-Wei
Xia, Dong-Guo
author_sort Li, Jie
collection PubMed
description In the title complex, {[Ni(2)(C(14)H(4)N(2)O(8))(H(2)O)(6)]·2H(2)O}(n), the two Ni(II) atoms are located in different special positions (one on a twofold rotation axis and the second on a centre of symmetry) and have different distorted octa­hedral environments (one by two N atoms from a bipyridine unit, two O atoms from two water mol­ecules and two O atoms from two carboxyl­ate groups, and the second by four O atoms from four water mol­ecules and two O atoms from two carboxyl­ate groups). Thus, the environments of the Ni(II) atoms may be denoted as NiN(2)O(4) and NiO(6). In the crystal, there exists an extensive network of classical O—H⋯O hydrogen bonds.
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spelling pubmed-35151562013-01-02 Poly[[hexa­aqua­(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetra­carboxyl­ato-κ(6) O (4):N,O (6),O (6′),N′:O (4′))dinickel(II)] dihydrate] Li, Jie Lei, Ke-Wei Xia, Dong-Guo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Ni(2)(C(14)H(4)N(2)O(8))(H(2)O)(6)]·2H(2)O}(n), the two Ni(II) atoms are located in different special positions (one on a twofold rotation axis and the second on a centre of symmetry) and have different distorted octa­hedral environments (one by two N atoms from a bipyridine unit, two O atoms from two water mol­ecules and two O atoms from two carboxyl­ate groups, and the second by four O atoms from four water mol­ecules and two O atoms from two carboxyl­ate groups). Thus, the environments of the Ni(II) atoms may be denoted as NiN(2)O(4) and NiO(6). In the crystal, there exists an extensive network of classical O—H⋯O hydrogen bonds. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515156/ /pubmed/23284383 http://dx.doi.org/10.1107/S1600536812043942 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Jie
Lei, Ke-Wei
Xia, Dong-Guo
Poly[[hexa­aqua­(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetra­carboxyl­ato-κ(6) O (4):N,O (6),O (6′),N′:O (4′))dinickel(II)] dihydrate]
title Poly[[hexa­aqua­(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetra­carboxyl­ato-κ(6) O (4):N,O (6),O (6′),N′:O (4′))dinickel(II)] dihydrate]
title_full Poly[[hexa­aqua­(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetra­carboxyl­ato-κ(6) O (4):N,O (6),O (6′),N′:O (4′))dinickel(II)] dihydrate]
title_fullStr Poly[[hexa­aqua­(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetra­carboxyl­ato-κ(6) O (4):N,O (6),O (6′),N′:O (4′))dinickel(II)] dihydrate]
title_full_unstemmed Poly[[hexa­aqua­(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetra­carboxyl­ato-κ(6) O (4):N,O (6),O (6′),N′:O (4′))dinickel(II)] dihydrate]
title_short Poly[[hexa­aqua­(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetra­carboxyl­ato-κ(6) O (4):N,O (6),O (6′),N′:O (4′))dinickel(II)] dihydrate]
title_sort poly[[hexa­aqua­(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetra­carboxyl­ato-κ(6) o (4):n,o (6),o (6′),n′:o (4′))dinickel(ii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515156/
https://www.ncbi.nlm.nih.gov/pubmed/23284383
http://dx.doi.org/10.1107/S1600536812043942
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