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Poly[[hexaaqua(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetracarboxylato-κ(6) O (4):N,O (6),O (6′),N′:O (4′))dinickel(II)] dihydrate]
In the title complex, {[Ni(2)(C(14)H(4)N(2)O(8))(H(2)O)(6)]·2H(2)O}(n), the two Ni(II) atoms are located in different special positions (one on a twofold rotation axis and the second on a centre of symmetry) and have different distorted octahedral environments (one by two N atoms from a bipyridine...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515156/ https://www.ncbi.nlm.nih.gov/pubmed/23284383 http://dx.doi.org/10.1107/S1600536812043942 |
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author | Li, Jie Lei, Ke-Wei Xia, Dong-Guo |
author_facet | Li, Jie Lei, Ke-Wei Xia, Dong-Guo |
author_sort | Li, Jie |
collection | PubMed |
description | In the title complex, {[Ni(2)(C(14)H(4)N(2)O(8))(H(2)O)(6)]·2H(2)O}(n), the two Ni(II) atoms are located in different special positions (one on a twofold rotation axis and the second on a centre of symmetry) and have different distorted octahedral environments (one by two N atoms from a bipyridine unit, two O atoms from two water molecules and two O atoms from two carboxylate groups, and the second by four O atoms from four water molecules and two O atoms from two carboxylate groups). Thus, the environments of the Ni(II) atoms may be denoted as NiN(2)O(4) and NiO(6). In the crystal, there exists an extensive network of classical O—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3515156 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151562013-01-02 Poly[[hexaaqua(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetracarboxylato-κ(6) O (4):N,O (6),O (6′),N′:O (4′))dinickel(II)] dihydrate] Li, Jie Lei, Ke-Wei Xia, Dong-Guo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Ni(2)(C(14)H(4)N(2)O(8))(H(2)O)(6)]·2H(2)O}(n), the two Ni(II) atoms are located in different special positions (one on a twofold rotation axis and the second on a centre of symmetry) and have different distorted octahedral environments (one by two N atoms from a bipyridine unit, two O atoms from two water molecules and two O atoms from two carboxylate groups, and the second by four O atoms from four water molecules and two O atoms from two carboxylate groups). Thus, the environments of the Ni(II) atoms may be denoted as NiN(2)O(4) and NiO(6). In the crystal, there exists an extensive network of classical O—H⋯O hydrogen bonds. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515156/ /pubmed/23284383 http://dx.doi.org/10.1107/S1600536812043942 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Jie Lei, Ke-Wei Xia, Dong-Guo Poly[[hexaaqua(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetracarboxylato-κ(6) O (4):N,O (6),O (6′),N′:O (4′))dinickel(II)] dihydrate] |
title | Poly[[hexaaqua(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetracarboxylato-κ(6)
O
(4):N,O
(6),O
(6′),N′:O
(4′))dinickel(II)] dihydrate] |
title_full | Poly[[hexaaqua(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetracarboxylato-κ(6)
O
(4):N,O
(6),O
(6′),N′:O
(4′))dinickel(II)] dihydrate] |
title_fullStr | Poly[[hexaaqua(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetracarboxylato-κ(6)
O
(4):N,O
(6),O
(6′),N′:O
(4′))dinickel(II)] dihydrate] |
title_full_unstemmed | Poly[[hexaaqua(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetracarboxylato-κ(6)
O
(4):N,O
(6),O
(6′),N′:O
(4′))dinickel(II)] dihydrate] |
title_short | Poly[[hexaaqua(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetracarboxylato-κ(6)
O
(4):N,O
(6),O
(6′),N′:O
(4′))dinickel(II)] dihydrate] |
title_sort | poly[[hexaaqua(μ(3)-2,2′-bipyridine-4,4′,6,6′-tetracarboxylato-κ(6)
o
(4):n,o
(6),o
(6′),n′:o
(4′))dinickel(ii)] dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515156/ https://www.ncbi.nlm.nih.gov/pubmed/23284383 http://dx.doi.org/10.1107/S1600536812043942 |
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