Cargando…
Bis{2,4-dibromo-6-[(E)-(4-fluorobenzyl)iminomethyl]phenolato-κ(2) N,O}cobalt(II)
The complete molecule of the title complex, [Co(C(14)H(9)Br(2)FNO)(2)], is generated by crystallographic twofold symmetry, with the Co(II) atom lying on the rotation axis. The coordination of the metal atom by the two N,O-bidentate ligands results in a squashed CoN(2)O(2) tetrahedron. The six-memb...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515158/ https://www.ncbi.nlm.nih.gov/pubmed/23284385 http://dx.doi.org/10.1107/S1600536812043929 |
| _version_ | 1782252123885404160 |
|---|---|
| author | Yu, Hong Chen, Zhu-Jun Jin, Yue-Bao Chang, Yong-Kang Lei, Ke-Wei |
| author_facet | Yu, Hong Chen, Zhu-Jun Jin, Yue-Bao Chang, Yong-Kang Lei, Ke-Wei |
| author_sort | Yu, Hong |
| collection | PubMed |
| description | The complete molecule of the title complex, [Co(C(14)H(9)Br(2)FNO)(2)], is generated by crystallographic twofold symmetry, with the Co(II) atom lying on the rotation axis. The coordination of the metal atom by the two N,O-bidentate ligands results in a squashed CoN(2)O(2) tetrahedron. The six-membered chelate ring is an envelope, with the metal atom as the flap. The dihedral angle between the planes of the aromatic rings within each ligand is 84.1 (6)°. |
| format | Online Article Text |
| id | pubmed-3515158 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35151582013-01-02 Bis{2,4-dibromo-6-[(E)-(4-fluorobenzyl)iminomethyl]phenolato-κ(2) N,O}cobalt(II) Yu, Hong Chen, Zhu-Jun Jin, Yue-Bao Chang, Yong-Kang Lei, Ke-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete molecule of the title complex, [Co(C(14)H(9)Br(2)FNO)(2)], is generated by crystallographic twofold symmetry, with the Co(II) atom lying on the rotation axis. The coordination of the metal atom by the two N,O-bidentate ligands results in a squashed CoN(2)O(2) tetrahedron. The six-membered chelate ring is an envelope, with the metal atom as the flap. The dihedral angle between the planes of the aromatic rings within each ligand is 84.1 (6)°. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515158/ /pubmed/23284385 http://dx.doi.org/10.1107/S1600536812043929 Text en © Yu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Yu, Hong Chen, Zhu-Jun Jin, Yue-Bao Chang, Yong-Kang Lei, Ke-Wei Bis{2,4-dibromo-6-[(E)-(4-fluorobenzyl)iminomethyl]phenolato-κ(2) N,O}cobalt(II) |
| title | Bis{2,4-dibromo-6-[(E)-(4-fluorobenzyl)iminomethyl]phenolato-κ(2)
N,O}cobalt(II) |
| title_full | Bis{2,4-dibromo-6-[(E)-(4-fluorobenzyl)iminomethyl]phenolato-κ(2)
N,O}cobalt(II) |
| title_fullStr | Bis{2,4-dibromo-6-[(E)-(4-fluorobenzyl)iminomethyl]phenolato-κ(2)
N,O}cobalt(II) |
| title_full_unstemmed | Bis{2,4-dibromo-6-[(E)-(4-fluorobenzyl)iminomethyl]phenolato-κ(2)
N,O}cobalt(II) |
| title_short | Bis{2,4-dibromo-6-[(E)-(4-fluorobenzyl)iminomethyl]phenolato-κ(2)
N,O}cobalt(II) |
| title_sort | bis{2,4-dibromo-6-[(e)-(4-fluorobenzyl)iminomethyl]phenolato-κ(2)
n,o}cobalt(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515158/ https://www.ncbi.nlm.nih.gov/pubmed/23284385 http://dx.doi.org/10.1107/S1600536812043929 |
| work_keys_str_mv | AT yuhong bis24dibromo6e4fluorobenzyliminomethylphenolatok2nocobaltii AT chenzhujun bis24dibromo6e4fluorobenzyliminomethylphenolatok2nocobaltii AT jinyuebao bis24dibromo6e4fluorobenzyliminomethylphenolatok2nocobaltii AT changyongkang bis24dibromo6e4fluorobenzyliminomethylphenolatok2nocobaltii AT leikewei bis24dibromo6e4fluorobenzyliminomethylphenolatok2nocobaltii |