Bis{2,4-dibromo-6-[(E)-(4-fluoro­benz­yl)imino­meth­yl]phenolato-κ(2) N,O}zinc

In the title Schiff base complex, [Zn(C(14)H(9)Br(2)FNO)(2)], the Zn(II) atom is located on a twofold rotation axis and is coordinated by two O and two N atoms from two symmetry-related bidentate Schiff base ligands in a compressed tetrahedral geometry. The bond lengths and bond angles are within no...

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Detalles Bibliográficos
Autores principales: Zhang, Dingjun, Yu, Hong, Jin, Yue-Bao, Lei, Ke-Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515159/
https://www.ncbi.nlm.nih.gov/pubmed/23284386
http://dx.doi.org/10.1107/S1600536812043930
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author Zhang, Dingjun
Yu, Hong
Jin, Yue-Bao
Lei, Ke-Wei
author_facet Zhang, Dingjun
Yu, Hong
Jin, Yue-Bao
Lei, Ke-Wei
author_sort Zhang, Dingjun
collection PubMed
description In the title Schiff base complex, [Zn(C(14)H(9)Br(2)FNO)(2)], the Zn(II) atom is located on a twofold rotation axis and is coordinated by two O and two N atoms from two symmetry-related bidentate Schiff base ligands in a compressed tetrahedral geometry. The bond lengths and bond angles are within normal ranges. The dihedral angle between the least-squares planes of the aromatic rings within each ligand is 82.76 (17)°.
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spelling pubmed-35151592013-01-02 Bis{2,4-dibromo-6-[(E)-(4-fluoro­benz­yl)imino­meth­yl]phenolato-κ(2) N,O}zinc Zhang, Dingjun Yu, Hong Jin, Yue-Bao Lei, Ke-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Schiff base complex, [Zn(C(14)H(9)Br(2)FNO)(2)], the Zn(II) atom is located on a twofold rotation axis and is coordinated by two O and two N atoms from two symmetry-related bidentate Schiff base ligands in a compressed tetrahedral geometry. The bond lengths and bond angles are within normal ranges. The dihedral angle between the least-squares planes of the aromatic rings within each ligand is 82.76 (17)°. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515159/ /pubmed/23284386 http://dx.doi.org/10.1107/S1600536812043930 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Dingjun
Yu, Hong
Jin, Yue-Bao
Lei, Ke-Wei
Bis{2,4-dibromo-6-[(E)-(4-fluoro­benz­yl)imino­meth­yl]phenolato-κ(2) N,O}zinc
title Bis{2,4-dibromo-6-[(E)-(4-fluoro­benz­yl)imino­meth­yl]phenolato-κ(2) N,O}zinc
title_full Bis{2,4-dibromo-6-[(E)-(4-fluoro­benz­yl)imino­meth­yl]phenolato-κ(2) N,O}zinc
title_fullStr Bis{2,4-dibromo-6-[(E)-(4-fluoro­benz­yl)imino­meth­yl]phenolato-κ(2) N,O}zinc
title_full_unstemmed Bis{2,4-dibromo-6-[(E)-(4-fluoro­benz­yl)imino­meth­yl]phenolato-κ(2) N,O}zinc
title_short Bis{2,4-dibromo-6-[(E)-(4-fluoro­benz­yl)imino­meth­yl]phenolato-κ(2) N,O}zinc
title_sort bis{2,4-dibromo-6-[(e)-(4-fluoro­benz­yl)imino­meth­yl]phenolato-κ(2) n,o}zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515159/
https://www.ncbi.nlm.nih.gov/pubmed/23284386
http://dx.doi.org/10.1107/S1600536812043930
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