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Poly[(μ(3)-hydrogenphosphato)(4H-1,2,4-triazole-κN (1))zinc]

The asymmetric unit of the title compound, [Zn(HPO(4))(C(2)H(3)N(3))](n), contains one Zn(2+) cation, one (HPO(4))(2−) anion and a 1,2,4 triazole ligand. The Zn(2+) cation is coordinated in a quite regular tetra­hedral geometry by O atoms from three phosphate groups and a tertiary N atom from the tr...

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Detalles Bibliográficos
Autores principales: Aitenneite, Hafid, El Bouari, Abdeslam, Sebti, Said, Saadi, Mohamed, El Ammari, Lahcen, Adil, Karim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515161/
https://www.ncbi.nlm.nih.gov/pubmed/23284388
http://dx.doi.org/10.1107/S1600536812044182
Descripción
Sumario:The asymmetric unit of the title compound, [Zn(HPO(4))(C(2)H(3)N(3))](n), contains one Zn(2+) cation, one (HPO(4))(2−) anion and a 1,2,4 triazole ligand. The Zn(2+) cation is coordinated in a quite regular tetra­hedral geometry by O atoms from three phosphate groups and a tertiary N atom from the triazole ring. Each phosphate anion is connected to three Zn(II) cations, leading to a series of corrugated organic–inorganic layers parallel to the ac plane. The overall structure involves stacking of complex hybrid organic–inorganic layers along the b axis. Cohesion in the crystal is ensured by an infinite three-dimensional network of N—H⋯O and O—H⋯O hydrogen bonds between the phosphate groups and the triazole ligands.