Tetra­aqua­bis­[2-(pyridin-4-yl-κN)pyrimidine-5-carboxyl­ato]zinc

In the title complex, [Zn(C(10)H(6)N(3)O(2))(2)(H(2)O)(4)], the Zn(II) ion lies on an inversion center and is coordinated in a slightly distorted octa­hedral geometry by two N atoms from two 2-(pyridin-4-yl)pyrimidine-5-carboxyl­ate ligands and four water mol­ecules. In the symmetry-unique part of t...

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Detalles Bibliográficos
Autores principales: Sen, Rupam, Mal, Dasarath, Brandao, Paula, Lin, Zhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515163/
https://www.ncbi.nlm.nih.gov/pubmed/23284390
http://dx.doi.org/10.1107/S160053681204411X
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author Sen, Rupam
Mal, Dasarath
Brandao, Paula
Lin, Zhi
author_facet Sen, Rupam
Mal, Dasarath
Brandao, Paula
Lin, Zhi
author_sort Sen, Rupam
collection PubMed
description In the title complex, [Zn(C(10)H(6)N(3)O(2))(2)(H(2)O)(4)], the Zn(II) ion lies on an inversion center and is coordinated in a slightly distorted octa­hedral geometry by two N atoms from two 2-(pyridin-4-yl)pyrimidine-5-carboxyl­ate ligands and four water mol­ecules. In the symmetry-unique part of the mol­ecule, the pyridine and pyrimidine rings form a dihedral angle of 7.0 (1)°. In the crystal, the coordinating water mol­ecules act as donor groups and carboxyl­ate O atoms act as acceptors in O—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-35151632013-01-02 Tetra­aqua­bis­[2-(pyridin-4-yl-κN)pyrimidine-5-carboxyl­ato]zinc Sen, Rupam Mal, Dasarath Brandao, Paula Lin, Zhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(10)H(6)N(3)O(2))(2)(H(2)O)(4)], the Zn(II) ion lies on an inversion center and is coordinated in a slightly distorted octa­hedral geometry by two N atoms from two 2-(pyridin-4-yl)pyrimidine-5-carboxyl­ate ligands and four water mol­ecules. In the symmetry-unique part of the mol­ecule, the pyridine and pyrimidine rings form a dihedral angle of 7.0 (1)°. In the crystal, the coordinating water mol­ecules act as donor groups and carboxyl­ate O atoms act as acceptors in O—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515163/ /pubmed/23284390 http://dx.doi.org/10.1107/S160053681204411X Text en © Sen et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sen, Rupam
Mal, Dasarath
Brandao, Paula
Lin, Zhi
Tetra­aqua­bis­[2-(pyridin-4-yl-κN)pyrimidine-5-carboxyl­ato]zinc
title Tetra­aqua­bis­[2-(pyridin-4-yl-κN)pyrimidine-5-carboxyl­ato]zinc
title_full Tetra­aqua­bis­[2-(pyridin-4-yl-κN)pyrimidine-5-carboxyl­ato]zinc
title_fullStr Tetra­aqua­bis­[2-(pyridin-4-yl-κN)pyrimidine-5-carboxyl­ato]zinc
title_full_unstemmed Tetra­aqua­bis­[2-(pyridin-4-yl-κN)pyrimidine-5-carboxyl­ato]zinc
title_short Tetra­aqua­bis­[2-(pyridin-4-yl-κN)pyrimidine-5-carboxyl­ato]zinc
title_sort tetra­aqua­bis­[2-(pyridin-4-yl-κn)pyrimidine-5-carboxyl­ato]zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515163/
https://www.ncbi.nlm.nih.gov/pubmed/23284390
http://dx.doi.org/10.1107/S160053681204411X
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AT maldasarath tetraaquabis2pyridin4ylknpyrimidine5carboxylatozinc
AT brandaopaula tetraaquabis2pyridin4ylknpyrimidine5carboxylatozinc
AT linzhi tetraaquabis2pyridin4ylknpyrimidine5carboxylatozinc

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