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Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ(6) O,N,N′,O′:O,O′;2:3κ(6) O,O′:O,N,N′,O′-tricopper(II)

The title compound, [Cu(3)(C(19)H(18)Cl(2)N(2)O(2))(2)(CH(3)CO(2))(2)], is a linear homo-trinuclear Cu(II) complex. The central Cu(II) atom is located on a centre of inversion and has a distorted octa­hedral coordination environment formed by six O atoms from two tetra­dentate Schiff base ligands an...

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Detalles Bibliográficos
Autores principales: Kubono, Koji, Tani, Keita, Yokoi, Kunihiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515164/
https://www.ncbi.nlm.nih.gov/pubmed/23284391
http://dx.doi.org/10.1107/S1600536812044315
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author Kubono, Koji
Tani, Keita
Yokoi, Kunihiko
author_facet Kubono, Koji
Tani, Keita
Yokoi, Kunihiko
author_sort Kubono, Koji
collection PubMed
description The title compound, [Cu(3)(C(19)H(18)Cl(2)N(2)O(2))(2)(CH(3)CO(2))(2)], is a linear homo-trinuclear Cu(II) complex. The central Cu(II) atom is located on a centre of inversion and has a distorted octa­hedral coordination environment formed by six O atoms from two tetra­dentate Schiff base ligands and two bridging acetate ligands. The coordination geometry of the terminal Cu(II) atom is square-pyramidal with a tetra­dentate ligand in the basal plane. The apical site is occupied by one O atom from an acetate ligand. The acetate-bridged Cu⋯Cu distance is 3.0910 (5) Å. An intra­molecular C—H⋯O hydrogen bond forms an S(6) ring motif. The crystal of the trinuclear complex is stabilized by C—H⋯O hydrogen bonds.
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spelling pubmed-35151642013-01-02 Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ(6) O,N,N′,O′:O,O′;2:3κ(6) O,O′:O,N,N′,O′-tricopper(II) Kubono, Koji Tani, Keita Yokoi, Kunihiko Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(3)(C(19)H(18)Cl(2)N(2)O(2))(2)(CH(3)CO(2))(2)], is a linear homo-trinuclear Cu(II) complex. The central Cu(II) atom is located on a centre of inversion and has a distorted octa­hedral coordination environment formed by six O atoms from two tetra­dentate Schiff base ligands and two bridging acetate ligands. The coordination geometry of the terminal Cu(II) atom is square-pyramidal with a tetra­dentate ligand in the basal plane. The apical site is occupied by one O atom from an acetate ligand. The acetate-bridged Cu⋯Cu distance is 3.0910 (5) Å. An intra­molecular C—H⋯O hydrogen bond forms an S(6) ring motif. The crystal of the trinuclear complex is stabilized by C—H⋯O hydrogen bonds. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515164/ /pubmed/23284391 http://dx.doi.org/10.1107/S1600536812044315 Text en © Kubono et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kubono, Koji
Tani, Keita
Yokoi, Kunihiko
Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ(6) O,N,N′,O′:O,O′;2:3κ(6) O,O′:O,N,N′,O′-tricopper(II)
title Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ(6) O,N,N′,O′:O,O′;2:3κ(6) O,O′:O,N,N′,O′-tricopper(II)
title_full Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ(6) O,N,N′,O′:O,O′;2:3κ(6) O,O′:O,N,N′,O′-tricopper(II)
title_fullStr Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ(6) O,N,N′,O′:O,O′;2:3κ(6) O,O′:O,N,N′,O′-tricopper(II)
title_full_unstemmed Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ(6) O,N,N′,O′:O,O′;2:3κ(6) O,O′:O,N,N′,O′-tricopper(II)
title_short Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis­{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ(6) O,N,N′,O′:O,O′;2:3κ(6) O,O′:O,N,N′,O′-tricopper(II)
title_sort di-μ(2)-acetato-1:2κ(2) o:o′;2:3κ(2) o:o′-bis­{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}-1:2κ(6) o,n,n′,o′:o,o′;2:3κ(6) o,o′:o,n,n′,o′-tricopper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515164/
https://www.ncbi.nlm.nih.gov/pubmed/23284391
http://dx.doi.org/10.1107/S1600536812044315
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