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Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ(6) O,N,N′,O′:O,O′;2:3κ(6) O,O′:O,N,N′,O′-tricopper(II)
The title compound, [Cu(3)(C(19)H(18)Cl(2)N(2)O(2))(2)(CH(3)CO(2))(2)], is a linear homo-trinuclear Cu(II) complex. The central Cu(II) atom is located on a centre of inversion and has a distorted octahedral coordination environment formed by six O atoms from two tetradentate Schiff base ligands an...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515164/ https://www.ncbi.nlm.nih.gov/pubmed/23284391 http://dx.doi.org/10.1107/S1600536812044315 |
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author | Kubono, Koji Tani, Keita Yokoi, Kunihiko |
author_facet | Kubono, Koji Tani, Keita Yokoi, Kunihiko |
author_sort | Kubono, Koji |
collection | PubMed |
description | The title compound, [Cu(3)(C(19)H(18)Cl(2)N(2)O(2))(2)(CH(3)CO(2))(2)], is a linear homo-trinuclear Cu(II) complex. The central Cu(II) atom is located on a centre of inversion and has a distorted octahedral coordination environment formed by six O atoms from two tetradentate Schiff base ligands and two bridging acetate ligands. The coordination geometry of the terminal Cu(II) atom is square-pyramidal with a tetradentate ligand in the basal plane. The apical site is occupied by one O atom from an acetate ligand. The acetate-bridged Cu⋯Cu distance is 3.0910 (5) Å. An intramolecular C—H⋯O hydrogen bond forms an S(6) ring motif. The crystal of the trinuclear complex is stabilized by C—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3515164 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151642013-01-02 Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ(6) O,N,N′,O′:O,O′;2:3κ(6) O,O′:O,N,N′,O′-tricopper(II) Kubono, Koji Tani, Keita Yokoi, Kunihiko Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(3)(C(19)H(18)Cl(2)N(2)O(2))(2)(CH(3)CO(2))(2)], is a linear homo-trinuclear Cu(II) complex. The central Cu(II) atom is located on a centre of inversion and has a distorted octahedral coordination environment formed by six O atoms from two tetradentate Schiff base ligands and two bridging acetate ligands. The coordination geometry of the terminal Cu(II) atom is square-pyramidal with a tetradentate ligand in the basal plane. The apical site is occupied by one O atom from an acetate ligand. The acetate-bridged Cu⋯Cu distance is 3.0910 (5) Å. An intramolecular C—H⋯O hydrogen bond forms an S(6) ring motif. The crystal of the trinuclear complex is stabilized by C—H⋯O hydrogen bonds. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515164/ /pubmed/23284391 http://dx.doi.org/10.1107/S1600536812044315 Text en © Kubono et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kubono, Koji Tani, Keita Yokoi, Kunihiko Di-μ(2)-acetato-1:2κ(2) O:O′;2:3κ(2) O:O′-bis{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ(6) O,N,N′,O′:O,O′;2:3κ(6) O,O′:O,N,N′,O′-tricopper(II) |
title | Di-μ(2)-acetato-1:2κ(2)
O:O′;2:3κ(2)
O:O′-bis{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ(6)
O,N,N′,O′:O,O′;2:3κ(6)
O,O′:O,N,N′,O′-tricopper(II) |
title_full | Di-μ(2)-acetato-1:2κ(2)
O:O′;2:3κ(2)
O:O′-bis{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ(6)
O,N,N′,O′:O,O′;2:3κ(6)
O,O′:O,N,N′,O′-tricopper(II) |
title_fullStr | Di-μ(2)-acetato-1:2κ(2)
O:O′;2:3κ(2)
O:O′-bis{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ(6)
O,N,N′,O′:O,O′;2:3κ(6)
O,O′:O,N,N′,O′-tricopper(II) |
title_full_unstemmed | Di-μ(2)-acetato-1:2κ(2)
O:O′;2:3κ(2)
O:O′-bis{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ(6)
O,N,N′,O′:O,O′;2:3κ(6)
O,O′:O,N,N′,O′-tricopper(II) |
title_short | Di-μ(2)-acetato-1:2κ(2)
O:O′;2:3κ(2)
O:O′-bis{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ(6)
O,N,N′,O′:O,O′;2:3κ(6)
O,O′:O,N,N′,O′-tricopper(II) |
title_sort | di-μ(2)-acetato-1:2κ(2)
o:o′;2:3κ(2)
o:o′-bis{μ(2)-4,4′-dichloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}-1:2κ(6)
o,n,n′,o′:o,o′;2:3κ(6)
o,o′:o,n,n′,o′-tricopper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515164/ https://www.ncbi.nlm.nih.gov/pubmed/23284391 http://dx.doi.org/10.1107/S1600536812044315 |
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