Cargando…
Pyridinium cis-diaquabis(oxalato-κ(2) O,O′)chromate(III)
The title compound, (C(5)H(6)N)[Cr(C(2)O(4))(2)(H(2)O)(2)], contains one protonated pyridine molecule and one [Cr(C(2)O(4))(2)(H(2)O)(2)](−) complex anion in the asymmetric unit. The Cr(III) in the complex anion is coordinated in a distorted octahedral environment by two O atoms from two cis water...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515167/ https://www.ncbi.nlm.nih.gov/pubmed/23284394 http://dx.doi.org/10.1107/S1600536812044303 |
Sumario: | The title compound, (C(5)H(6)N)[Cr(C(2)O(4))(2)(H(2)O)(2)], contains one protonated pyridine molecule and one [Cr(C(2)O(4))(2)(H(2)O)(2)](−) complex anion in the asymmetric unit. The Cr(III) in the complex anion is coordinated in a distorted octahedral environment by two O atoms from two cis water molecules and four O atoms from two chelating oxalate dianions. The crystal packing is stabilized by intermolecular N—H⋯O(oxalate) and O—H⋯O(oxalate) hydrogen bonds and by π–π stacking interactions (centroid–centroid distance = 3.602 Å) between pyridine rings, thereby building up a three-dimensional network. |
---|