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3-(Ammonio­meth­yl)pyridinium dibromide

In the title salt, C(6)H(10)N(2) (2+)·2Br(−), the non-H atoms of the 3-methyl­pyridinium unit of the cation are almost coplanar (r.m.s. deviation = 0.0052 Å). In the crystal, the dications and Br anions are linked by a combination of six hydrogen bonds, viz. one N(py)—H⋯Br, two C—H⋯Br and three H(2)...

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Detalles Bibliográficos
Autores principales: Ali, Basem F., Al-Far, Rawhi, Haddad, Salim F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515173/
https://www.ncbi.nlm.nih.gov/pubmed/23284400
http://dx.doi.org/10.1107/S1600536812040937
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author Ali, Basem F.
Al-Far, Rawhi
Haddad, Salim F.
author_facet Ali, Basem F.
Al-Far, Rawhi
Haddad, Salim F.
author_sort Ali, Basem F.
collection PubMed
description In the title salt, C(6)H(10)N(2) (2+)·2Br(−), the non-H atoms of the 3-methyl­pyridinium unit of the cation are almost coplanar (r.m.s. deviation = 0.0052 Å). In the crystal, the dications and Br anions are linked by a combination of six hydrogen bonds, viz. one N(py)—H⋯Br, two C—H⋯Br and three H(2)N–H⋯Br, into supra­molecular layers, parallel to the bc plane, composed of alternating R(2)(4)(10) and R(2)(4)(8) loops. Weak π–π inter­actions between cationic rings with centroid–centroid distances of 3.891 (2) Å are also observed.
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spelling pubmed-35151732013-01-02 3-(Ammonio­meth­yl)pyridinium dibromide Ali, Basem F. Al-Far, Rawhi Haddad, Salim F. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(6)H(10)N(2) (2+)·2Br(−), the non-H atoms of the 3-methyl­pyridinium unit of the cation are almost coplanar (r.m.s. deviation = 0.0052 Å). In the crystal, the dications and Br anions are linked by a combination of six hydrogen bonds, viz. one N(py)—H⋯Br, two C—H⋯Br and three H(2)N–H⋯Br, into supra­molecular layers, parallel to the bc plane, composed of alternating R(2)(4)(10) and R(2)(4)(8) loops. Weak π–π inter­actions between cationic rings with centroid–centroid distances of 3.891 (2) Å are also observed. International Union of Crystallography 2012-10-03 /pmc/articles/PMC3515173/ /pubmed/23284400 http://dx.doi.org/10.1107/S1600536812040937 Text en © Ali et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ali, Basem F.
Al-Far, Rawhi
Haddad, Salim F.
3-(Ammonio­meth­yl)pyridinium dibromide
title 3-(Ammonio­meth­yl)pyridinium dibromide
title_full 3-(Ammonio­meth­yl)pyridinium dibromide
title_fullStr 3-(Ammonio­meth­yl)pyridinium dibromide
title_full_unstemmed 3-(Ammonio­meth­yl)pyridinium dibromide
title_short 3-(Ammonio­meth­yl)pyridinium dibromide
title_sort 3-(ammonio­meth­yl)pyridinium dibromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515173/
https://www.ncbi.nlm.nih.gov/pubmed/23284400
http://dx.doi.org/10.1107/S1600536812040937
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