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3-(Ammoniomethyl)pyridinium dibromide
In the title salt, C(6)H(10)N(2) (2+)·2Br(−), the non-H atoms of the 3-methylpyridinium unit of the cation are almost coplanar (r.m.s. deviation = 0.0052 Å). In the crystal, the dications and Br anions are linked by a combination of six hydrogen bonds, viz. one N(py)—H⋯Br, two C—H⋯Br and three H(2)...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515173/ https://www.ncbi.nlm.nih.gov/pubmed/23284400 http://dx.doi.org/10.1107/S1600536812040937 |
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author | Ali, Basem F. Al-Far, Rawhi Haddad, Salim F. |
author_facet | Ali, Basem F. Al-Far, Rawhi Haddad, Salim F. |
author_sort | Ali, Basem F. |
collection | PubMed |
description | In the title salt, C(6)H(10)N(2) (2+)·2Br(−), the non-H atoms of the 3-methylpyridinium unit of the cation are almost coplanar (r.m.s. deviation = 0.0052 Å). In the crystal, the dications and Br anions are linked by a combination of six hydrogen bonds, viz. one N(py)—H⋯Br, two C—H⋯Br and three H(2)N–H⋯Br, into supramolecular layers, parallel to the bc plane, composed of alternating R(2)(4)(10) and R(2)(4)(8) loops. Weak π–π interactions between cationic rings with centroid–centroid distances of 3.891 (2) Å are also observed. |
format | Online Article Text |
id | pubmed-3515173 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151732013-01-02 3-(Ammoniomethyl)pyridinium dibromide Ali, Basem F. Al-Far, Rawhi Haddad, Salim F. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(6)H(10)N(2) (2+)·2Br(−), the non-H atoms of the 3-methylpyridinium unit of the cation are almost coplanar (r.m.s. deviation = 0.0052 Å). In the crystal, the dications and Br anions are linked by a combination of six hydrogen bonds, viz. one N(py)—H⋯Br, two C—H⋯Br and three H(2)N–H⋯Br, into supramolecular layers, parallel to the bc plane, composed of alternating R(2)(4)(10) and R(2)(4)(8) loops. Weak π–π interactions between cationic rings with centroid–centroid distances of 3.891 (2) Å are also observed. International Union of Crystallography 2012-10-03 /pmc/articles/PMC3515173/ /pubmed/23284400 http://dx.doi.org/10.1107/S1600536812040937 Text en © Ali et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ali, Basem F. Al-Far, Rawhi Haddad, Salim F. 3-(Ammoniomethyl)pyridinium dibromide |
title | 3-(Ammoniomethyl)pyridinium dibromide |
title_full | 3-(Ammoniomethyl)pyridinium dibromide |
title_fullStr | 3-(Ammoniomethyl)pyridinium dibromide |
title_full_unstemmed | 3-(Ammoniomethyl)pyridinium dibromide |
title_short | 3-(Ammoniomethyl)pyridinium dibromide |
title_sort | 3-(ammoniomethyl)pyridinium dibromide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515173/ https://www.ncbi.nlm.nih.gov/pubmed/23284400 http://dx.doi.org/10.1107/S1600536812040937 |
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