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1-Dodecyl-1H-benzo[d]imidazol-2(3H)-one
In the title compound, C(19)H(30)N(2)O, the fused ring system is essentially planar, the maximum deviation from the mean plane being 0.013 (2) Å for the N atom bearing the dodecyl chain. The 1-dodecyl group is almost perpendicular to the 1H-benzo[d]imidazol-2(3H)-one plane as indicated by the dihedr...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515176/ https://www.ncbi.nlm.nih.gov/pubmed/23284403 http://dx.doi.org/10.1107/S1600536812041189 |
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author | Belaziz, Dounia Kandri Rodi, Youssef Ouazzani Chahdi, Fouad Essassi, El Mokhtar Saadi, Mohamed El Ammari, Lahcen |
author_facet | Belaziz, Dounia Kandri Rodi, Youssef Ouazzani Chahdi, Fouad Essassi, El Mokhtar Saadi, Mohamed El Ammari, Lahcen |
author_sort | Belaziz, Dounia |
collection | PubMed |
description | In the title compound, C(19)H(30)N(2)O, the fused ring system is essentially planar, the maximum deviation from the mean plane being 0.013 (2) Å for the N atom bearing the dodecyl chain. The 1-dodecyl group is almost perpendicular to the 1H-benzo[d]imidazol-2(3H)-one plane as indicated by the dihedral angle of 82.9 (2)°between planes through the fused ring system and the first three C atoms of the chain. The C—C—C—C torsion angles (about ±179°) of the dodecyl group indicate an antiperiplanar conformation. In the crystal, inversion dimers are formed by pairs of N—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3515176 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151762013-01-02 1-Dodecyl-1H-benzo[d]imidazol-2(3H)-one Belaziz, Dounia Kandri Rodi, Youssef Ouazzani Chahdi, Fouad Essassi, El Mokhtar Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(30)N(2)O, the fused ring system is essentially planar, the maximum deviation from the mean plane being 0.013 (2) Å for the N atom bearing the dodecyl chain. The 1-dodecyl group is almost perpendicular to the 1H-benzo[d]imidazol-2(3H)-one plane as indicated by the dihedral angle of 82.9 (2)°between planes through the fused ring system and the first three C atoms of the chain. The C—C—C—C torsion angles (about ±179°) of the dodecyl group indicate an antiperiplanar conformation. In the crystal, inversion dimers are formed by pairs of N—H⋯O hydrogen bonds. International Union of Crystallography 2012-10-06 /pmc/articles/PMC3515176/ /pubmed/23284403 http://dx.doi.org/10.1107/S1600536812041189 Text en © Belaziz et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Belaziz, Dounia Kandri Rodi, Youssef Ouazzani Chahdi, Fouad Essassi, El Mokhtar Saadi, Mohamed El Ammari, Lahcen 1-Dodecyl-1H-benzo[d]imidazol-2(3H)-one |
title | 1-Dodecyl-1H-benzo[d]imidazol-2(3H)-one |
title_full | 1-Dodecyl-1H-benzo[d]imidazol-2(3H)-one |
title_fullStr | 1-Dodecyl-1H-benzo[d]imidazol-2(3H)-one |
title_full_unstemmed | 1-Dodecyl-1H-benzo[d]imidazol-2(3H)-one |
title_short | 1-Dodecyl-1H-benzo[d]imidazol-2(3H)-one |
title_sort | 1-dodecyl-1h-benzo[d]imidazol-2(3h)-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515176/ https://www.ncbi.nlm.nih.gov/pubmed/23284403 http://dx.doi.org/10.1107/S1600536812041189 |
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